Product ID:ZIP FIXER OR TRAY FIXER
MSDS Date:10/23/1989
FSC:6750
NIIN:01-144-4232
MSDS Number: BKBND

HORIZONS INC - METALPHOTO DIVISION

18531 SOUTH MILES RD
CLEVELAND, OH 44128
US

Emergency Phone: 216-475-0555

Cage: NO048

HORIZONS INC - METALPHOTO DIVISION

CLEVELAND, OH 44128 US

Telephone: 216-475-0555

Cage: NO048

ACETIC ACID (SARA III)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 3%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM METABISULFITE

CAS: 7681-57-4

RTECS: UX8225000

Fraction By Weight: 2 - 4%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9192

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 39 - 53%

OTHER NON HAZARDOUS INGREDIENT(S)

Fraction By Weight: BALANCE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MATERIAL IS A CORROSIVE ACID SOLUTION
AND WILL CAUSE IRRITATION AND BURNS TO EYES, SKIN, RESPIRATORY
TRACT AND GASTROINTESTINAL TRACT. INGESTION WILL RESULT IN BURNS TO
THE MOUTH, THROAT, AND GASTROIN TESTINAL TRACT. CHRONIC: PROLONGED
EXPOSURE MAY LEAD TO DELAYED EFFECTS INCLUDING SCARRING AND
INFECTION OF LIVER/KIDNEY
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS LISTED IN THIS
FORMULATION IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:PROLONGED SKIN CONTACT MAY PRODUCE ACID BURNS
WITH ACCOMPANYING RASH.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND
RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH
WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN
IF BREATHI NG IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF VICTIM
IS NOT BREATHING. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM
LARGE AMOUNTS OF WATER TO DILUTE MATERIAL. GET MEDICAL ATTENTION.

Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL AS APPROPRIATE FOR SURROUNDINGS.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, ELIMINATE SOURCES
OF IGNITION, AND VENTILATE AREA AS REQUIRED. ABSORB SMALL SPILL
WITH INERT MATERIAL (SAW DUST, SAND, OIL DRY ETC.) PLACE WASTE IN
DOT APPROVED CONTAINER FO R DISPOSAL.
Neutralizing Agent:SODA ASH OR SODIUM BICARBONATE (SMALL SPILLS)

Handling and Storage Precautions:STORE IN A COOL (68-75F), DRY, WELL
VENTILATED AREA AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER
CLOSED WHEN NOT IN USE. PROTECT FROM PHYSICAL DAMAGE
Other Precautions:CORROSIVE MATERIAL - AVOID CONTACT WITH SKIN, EYES,
AND CLOTHING. AVOID BREATHING VAPORS.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND
NIOSH-RESPIRATOR SELECTION.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Protective Gloves:ACID RESISTANT IMPERMEABLE GLOVES
Eye Protection:FULL-FACED RESPIRATOR, IF NEEDED
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. IMPERMEABLE
BOOTS AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
CORROSIVE MATERIAL - AVOID CONTACT.

HCC:C3
Boiling Pt:B.P. Text:193
Vapor Density:<1 AIR=1
Spec Gravity:1.27
pH:<7
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:VERY SOLUBLE
Appearance and Odor:PALE YELLOW SOLUTION; VINEGAR ODOR

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS (REACTION MAY PRODUCE HYDROGEN SULFIDE FUMES)
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. DILUTED AND NEUTRALIZED
MATERIAL CAN PROBABLY BE FLUSHED TO WASTE WATER TREATMENT VIA A
SEWER. UNUSED WASTE MATERIAL WOULD BE A HAZARDOUS WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.