Product ID:875942-00W
MSDS Date:01/01/1986
FSC:9150
NIIN:00-875-4103
Kit Part:Y
MSDS Number: BKBYB

MILLER-STEPHENSON CHEMICAL CO INC.

GEORGE WASHINGTON HIGHWAY
DANBURY, CT 06810
US

Emergency Phone: 203-797-2212 OR 800-424-9300

Info Phone: 203-743-4447

Preparer: JANET STEPHENS

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 3.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 45.50%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DICHLORODIFLUOROMETHANE (SARA III)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 45.50%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPOR IS HEAVIER THAN AIR AND CAN
CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE. EXCESSIVE
INHALATION OF CONCENTRATED VAPOR MAY LEAD TO DIZZINESS
NARCOSIS,ANESTHESIA,CARDIAC IRREGULARITIES,UNCONSCIOU SNESS OR
DEATH. EXCESSIVE INHALATION OFPYROLYZED FUMES: FLU LIKE "POLYMER
FUME FEVER".
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:MILD SKIN IRRITANT. REPEATED SKIN CONTACT CAN
CAUSE DEFATTING OF THE SKIN. CONTACT WILL CAUSE IRRITATION.
ALTHOUGH THE ORAL TOXICITY IS LOW, INGESTION IS TO BE AVOIDED.
Medical Cond Aggravated by Exposure:SEE PRINCIPAL HEALTH HAZARDS;
INHALATION SECTION.

First Aid:MOVE PATIENT TO FRESH AIR. IF NECESSARY, GIVE ARTIFICAL
RESPIRATION OR OXYGEN. IF BREATHING IS DIFFICULT, CALL A PHYSICIAN.
DO NOT GIVE EPINEPHINE OF SIMILAR DRUGS AS SUCH DRUGS MAY INDUCE
VENTRICULA R ARRHYTHINA. NORMAL RECOVERY OCCURS WITH 1 2 DAYS. EYE
CONTACT IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN
CONTACTFLUSH WITH WATER. ORAL, DO NOT INDUCE VOMITING. GIVE 2
GLASES OF WATER

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:"ALCOHOL" FOAM. DRY POWER (SAND OR MET L X). CO2.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA.
DECOMPOSITION AT FLAME TEMPERATURES FORMS POTENTIALLY TOXIC
COMPOUNDS.SELF CONTAINED APPARATUS MAY BE REQUIRED IF CAN RUPTURE
Unusual Fire/Explosion Hazard:PRESSURIZED AEROSOL CONTAINERS AT HIGH
TEMPERATURES MAY VENT, RUPTURE OR BURST AND ADD TO FLYING
DEBRIS.MAY CAUSE DECOMPOSITION W/EMMISSION OF HALOGEN ACIDS.

Spill Release Procedures:PROPELLANT VAPORS TEND TO CONCENTRATE IN LOW
PLACES VENTILATE AREA. DIKE SPILL COLLECT ON ABSORBENT MATERIAL AND
TRANFER TO STEEL DRUMS FOR RECOVERY OR DISPOSAL. FLUSH SPILL AREA
WITH WATER DO NOT BUR N. COMPLY WITH FEDERAL, STATE, AND
LOCALREGULATION

Handling and Storage Precautions:DO NOT STORE NEAR SOURCES OF HEAT, IN
DIRECT SUNLIGHT OR WHERE TEMPERATURE EXCEEDS 49C/120F. DO NOT
PUNCTURE OR DAMAGE CONTAINER.
Other Precautions:DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN
AREA WHERE IT HAS BE CONTAMINATED WITH THIS MATERIAL. FREEZING WILL
AFFECT THE PHYSICAL CONDITION BUT WILL NOT DAMAGE. THAW AND MIX
BEFORE USING ROTA TE STOCK TO SHELF LIFE OF ONE YEAR.

Respiratory Protection:NORMAL VENTILATION FOR STANDARD MANUFACTURING
PROCEDURES IS GENERALLY ADEQUATE. LOCAL EXHAUST SHOULD BE USED WHEN
LARGE AMOUNTS ARE RELEASED.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Protective Gloves:RUBBER GLOVES
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:NONE
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health

HCC:V2
Boiling Pt:B.P. Text:75
Decomp Temp:Decomp Text:>300F,>149C
Vapor Pres:250MM HG68
Vapor Density:6.0 68 F
pH:5.0
Evaporation Rate & Reference:1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MILKY. WHITE. FAINT SOLVENT ODOR.
Percent Volatiles by Volume:99

Stability Indicator/Materials to Avoid:YES
FINELY DIVIDED REACTIVE METALS.
Stability Condition to Avoid:SPRAYING NEAR OPEN FLAMES OR RED HOT
COILS.
Hazardous Decomposition Products:THIS COMPOUND CAN BE DECOMPOSED BY
HIGH TEMPERATURES. (>300 F). EMTPTING HALOGEN ACIDS,PHOSGENE &
PERFLUOROCABONS.

Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE AEROSOL CANS.
TREATMENT STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.