Product ID:CLP,LIQUID
MSDS Date:10/30/1991
FSC:9150
NIIN:01-079-6124
MSDS Number: BLBDD

BREAK-FREE DIV OF SAN/BAR CORP

1035 S LINWOOD AVE
SANTA ANA, CA 92799-5020
US

Emergency Phone: 800-424-9300(CHEMTREC)/202-483-7616

Info Phone: 714-953-1900/202-483-7616

Preparer: DONALD E. YODER

Cage: 65983

BREAK-FREE INC

JACKSONVILLE, FL 32218 US

Telephone: 800-428-0588/ 904-741-5400

Cage: 65983

SYNTHETIC & PARAFINIC OILS & OTHER PROPRIETARY ING

Fraction By Weight: 74.1%

OSHA PEL 5 MG/M (OIL MIST)

ACGIH TLV: 5 MG/M (OIL MIST)

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 4.0%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 6.2%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 12.0%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 2.0%

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

TAR ACIDS, CRESYLIC,PHENYL,PHOSPHATE

CAS: 68952-35-2

Fraction By Weight: 1.0%

INSOLUBLE BARIUM COMPOUNDS

Fraction By Weight: 0.6%

TERT-BUTYL ALCOHOL (SARA III)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0.1%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM 9394

LD50 LC50 Mixture:LD50 (ORAL RAT) IS >500 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WHILE EXPECTED TO BE NON-IRRITATING
FROM THE SKIN, EYE AND ORAL TESTING DONE, AS WITH ALL PETROLEUM
PRODUCTS PROLONGED AND REPEATED CONTACT ON THE SKIN COULD CAUSE
IRRITATION AND POSSIBLE DERMATITIS. REPETITIVE AND CONTINUOUS
EXPOSURES TO HIGH VAPOR LEVELS OR DIRECT CONTACT ON SKIN COULD
RESULT IN LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:MAY CAUSE IRRITATION TO NOSE AND THROAT.
SOLVENT VAPORS MAY CAUSE IRREGULAR HEARTBEATS, LIGHTHEADEDNESS,
DIZZINESS, NAUSEA TO UNCONSCIOUSNESS AND POSSIBLY BE LETHAL.
AABSORPTION THROUGH THE SKIN MAY C AUSE SYSTEMIC EFFECTS TO BLOOD,
LIVER AND KIDNEYS. MAY BE IRRITATING TO DIGESTIVE TRACT WITH
SYSTEMIC EFFECTS TO LUNGS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
MATERIAL.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:
REMOV E CONTAMINATED CLOTHING. WASH WITH SOAPAND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:SOLVENT VAPORS, WHEN CONCENTRATED IN
CONFINED OR POORLY VENTILATED AREAS MAY FLASH UPON CONTACT WITH
FLAMES, SPARKS OR HIGH INTENSITY HEAT SOURCES.

Spill Release Procedures:SMALL SPILL: WIPE/SOAK UP WITH PAPER TOWEL OR
INERT ABSORBANT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH
WATER. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP
LEAK. DIKE TO RETAIN RU N OFF. VACUUM UP FREE LIQUID. ABSORB/WASH
RESIDUE.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:DO NOT STORE ABOVE 120 F. DO NOT USE
AROUND OPEN FLAMES. MAINTAIN ADEQUATE VENTILATION. VAPORS ARE
HEAVIER THAN AIR AND COLLECT IN LOW PLACES.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR
INDUSTRIAL USE ONLY.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR
CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29
CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR
SELECTION.
Ventilation:GENERAL DILUTION OR LOCAL EXHAUST SUFFICIENT TO MAINTAIN
ADEQUATE AIR EXHANGE TO AVOID VAPOR BUILD-UP.
Protective Gloves:POLYETHYLENE, NEOPRENE OR PVC.
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A UNDER THE SAME
NSN.

HCC:V6
Boiling Pt:B.P. Text:140F,60C
Vapor Density:2.4
Spec Gravity:0.9
Evaporation Rate & Reference:3.8 (SOLVENTS ONLY)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER COLORED LIQUID WITH SLIGHT FRUITY ODOR.
Percent Volatiles by Volume:26.0

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR AND NITROGEN,
ACIDIC PRODUCTS OF THERMAL DECOMPOSITION, INCLUDING HYDROGEN
CLORIDE, PHOSGENE.

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
INCINERATION IS NORMALLY PREFERRED. NEVER DUMP INTO THE SEWER OR ON
THE GROUND OR INTO ANY NAVI GATIBLE WATERS, STREAMS, LAKES OR
RIVERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.