Product ID:VINYL BLACK A.F., F-129
MSDS Date:10/02/1990
FSC:8010
NIIN:01-286-7051
MSDS Number: BLBFJ

DEVOE COATINGS CO DIV OF GROW GROUP INC

4000 DUPONT CIR
LOUISVILLE, KY 40207-4802
US

Emergency Phone: 800-424-9300

Info Phone: 502-897-9861

Preparer: LOUIS F HOLZKUECHT

Cage: 1HK86

DEVOE COATINGS CO

7600 LOUISVILLE, KY 40207-4802 US

Telephone: 502-897-9861

Cage: 1HK86

COPPER OXIDE (SARA 313)

CAS: 1317-39-1

RTECS: GL8050000

Fraction By Weight: 59.5%

OSHA PEL 1 MG/M3 CU

ACGIH TLV: 1 MG/M3 CU

IRON OXIDE

CAS: 1317-61-9

Fraction By Weight: 11.4%

OSHA PEL N/E

ACGIH TLV: 5 MG/M3 FUME

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 8.0%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ROSIN

CAS: 8050-09-7

Fraction By Weight: 11.2%

OSHA PEL N/E

ACGIH TLV: N/E

TRICRESYL PHOSPHATE

CAS: 1330-78-5

RTECS: TD0175000

Fraction By Weight: 2.4%

OSHA PEL N/E

ACGIH TLV: N/E

VINYL RESIN

CAS: 9003-22-9

RTECS: AK0950000

Fraction By Weight: 2.4%

OSHA PEL N/E

ACGIH TLV: N/E

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4.3%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

313.8 (GRAMS/LITER)

RTECS: 9999999VO

LD50 LC50 Mixture:LD 50:1.6 GM/KG/KG RAT ORAL LC 50: 200 *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:BREATHING: RESPIRATORY TRACT
IRRITATION: HEADACHE, NAUSEA, DIZZINESS, WEAKNESS & FATIGUE.
EXTREME EXPOSURE CAN RESULT IN UNCONSCIOUSNESS & EVEN RESPIRATORY
ARREST. SKIN/EYE: IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH
SKIN. SWALLOWING: CAN CAUSE STOMACH AND/OR INTESTINAL IRRITATION,
NAUSEA, VOMITING & DIARRHEA.
Explanation of Carcinogenicity:*MG/L RAT
Effects of Overexposure:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS
SYSTEM DAMAGE. PROLONGED/REPEATED BREATHING OF SPRAY MIST AND/OR
SANDING DUST OVER A PERI OD OF YEARS MAY CAUSE DUST DISEASE OF THE
LUNGS.
Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH
SAFE HANDLING AND USE INFORMATION.

First Aid:INHAL:DIFFICULT BREATHING, REMOVE TO FRESH AIR. BREATHING
DIFFICULTY CONTINUES, CALL DR. IF BREATHING CEASES, GIVE CPR & GET
MED ATTN IMMED. EYES: FLUSH IMMED WITH LARGE AMNTS OF WATER--15
MIN. CALL D R. SKIN: WASH AREA WITH SOAP & WATER. REMOVE SOILED
CLOTHING & GET MED ATTN IF IRRIT PERSIST. SWALLOWED: DO NOT INDUCE
VOMITING. CALL DR. ASPIRATION OF VOMITUS CAN CAUSE FATAL CHEMICAL
PNEUMONITIS.

Flash Point Method:SCC
Flash Point:85.0F,29.4C
Lower Limits:1
Extinguishing Media:IN CASE OF FIRE, USE CO2, DRY CHEMICAL, FOAM OR
OTHER NFPA METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:FIREFIGHTERS WEAR FULL PROTECTIVE EQUIP &
SCBA. WATER INEFFECTIVE, USE TO COOL CONTAINERS (FOG NOZZLES
PREFERABLE) TO PREVENT PRESSURE BUILD-UP OR AUTO-IGNITE.
Unusual Fire/Explosion Hazard:KEEP CNTNR CLOSED TIGHT & FROM IGNITE
SOURCES. VAPOR: CAUSE FLASH FIRE/IGNITE EXPLOS/SPREAD LONG
DISTANCES. CLOSED CNTNR MAY EXPLODE W/HEAT. NEVER USE WELD/CUT*

Spill Release Procedures:REMOVE ALL IGNITE SOURCES. PREVENT INHALE OF
VAPORS. VENT AREA. BEFORE ATTEMPT CLEAN-UP, REFER TO HAZARD CAUTION
INFO IN OTHER SECTIONS OF THIS MSDS. CONTAIN SPILL & REMOVE W/INERT
ABSORB & NON-SPARK TOOLS. STORE IN CLOSED CONTAINER UNTIL
DISPOSAL.

Handling and Storage Precautions:KEEP AWAY ALL IGNITION SOURCES. VAPORS
MAY IGNITE ALSO. DO NOT REUSE EMPTY CONTAINERS. VAPORS MAY SPREAD
LONG DISTANCES & BEYOND CLOSED DOORS.
Other Precautions:PREVENT BUILD-UP OF VAPORS BY MAINTAIN CONTINUOUS
FLOW OF FRESH AIR. DON'T STORE > 120F/NEAR FIRE/OPEN FLAME. STORE
LG AMTS IN BLDGS TO COMPLY W/OSHA 1910.106. KEEP CONTAINER CLOSED
WHEN NOT IN USE. D O NOT TRANSFER TO UNLABELLED CONTAINER.

Respiratory Protection:OUTDOORS: IF DURING SANDING/GRINDING, USE
NIOSH/MSHA APPROVED MECHANICAL FILTER RESPIRATOR. RESTRICTED VENT:
WEAR NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTER. CONFINED: WEAR
NIOSH/MSHA APPROVED AIR SUPPLY RESPIRATORS OR USE HOODS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENT IN VOLUME/PATTERN TO
KEEP AIR CONTAM CONC BELOW CURRENT SAFETY/HEALTH STANDARD.
Protective Gloves:WEAR SOLVENT IMPERMEABLE GLOVES.
Eye Protection:SAFETY WEAR W/SPLASH GUARDS/SIDE SHIELDS
Other Protective Equipment:DO NOT GET ON SKIN. SOLVENT IMPERMEABLE
CLOTHING & BOOTS TO PREVENT SKIN CONTACT ARE RECOMMENDED.
Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
IF MAT'L IS PART OF A TWO COMPONENT PROD, THEN MIX OF BASE/CONVERTER
PORTIONS WILL HAVE HAZARDS OF BOTH COMPONENTS. OBSERVE ALL
PRECAUTIONS. THIS PRODUCT MAY CONTAIN A CHEM KNOWN TO CALIF STATE
TO CAU SE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTENTIONAL MISUSE BY DELIBERATELY INHALING CONTENTS/HARMFUL/FATAL.

HCC:F3
Boiling Pt:B.P. Text:241 TO 466F
Vapor Density:> AIR
Spec Gravity:2.33 TO 2.45
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:BLACK VISCOUS LIQUID; SOLVENT ODOR
Percent Volatiles by Volume:38.23

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:*TORCH ON OR NEAR CNTNR/MAY IGNITE.
OVEREXPOS TO DECOMP PROD/HEALTH HAZARD. SYMPTOMS NOT IMMED
APPARENT. GET MED AID.
Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO
DECOMP. FUMES MAY CONTAIN CO, CO2, PHOSPHORUS OXIDES, COPPER CMPDS,
CHLORINE, HCL.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. HAZARDOUS WASTE CODE D001, IGNITABLE
PESTICIDE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.