Product ID:PHENOLINE, 314
MSDS Date:02/23/1988
FSC:8040
NIIN:00N015918
MSDS Number: BLBKY

CARBOLINE CO

350 HANLEY INDUSTRIAL CT
ST LOUIS, MO 63144
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 314-644-1000

Preparer: JKM

Cage: 06634

CARBOLINE CO

ST. LOUIS, MO 63144-1599 US

Telephone: 314-644-1000

Cage: 06634

DIETHYLENE TRIAMINE

CAS: 111-40-0

RTECS: IE1225000

Fraction By Weight: 20%

OSHA PEL 1 PPM

ACGIH TLV: S, 1 PPM; 9192

EPOXY RESIN

CAS: 25085-99-8

Fraction By Weight: 30%

2.0

Fraction By Weight: 15%

ACGIH TLV: 275 PPM (MFR)

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 15%

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CONTAINERS MUST BE BONDED AND GROUNDED.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE TOXICITY: OVEREXPOS CAN LEAD TO
CNS DEPRESSION PRODUCING HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
CONSCIOUSNESS. EYE: SHORT-TERM CONTACT MAY RESULT IN SLIGHT EYE
IRRIT. PROLONGED AND REPEATED CO NTACT MAY BE MORE IRRITATING.
SKIN: PRLNG/RPTD LIQ CONTACT CAN CAUSE DEFATTING DRYING OF SKIN
(SEE EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: WHICH MAY RSLT IN SKIN IRRIT OR
DERMATITIS. INHAL: HIGH CONCENTRATIONS OR PRLNGD EXPOS TO LOWER
CONCENTRATIONS MAY BE SLIGHTLY IRRIT TO MUC MEMB. CAUSES EYE IRRIT.
CAUSES BURNS. MAY CAUSE AL LERGIC SKIN RXN. HARMFUL IF SWALLOWED.
MAY BE FATAL IF ABSORBED THROUGH SKIN. MAY CAUSE LUNG IRRIT &
ALLERGIC RESP RXN.
Medical Cond Aggravated by Exposure:NONE

First Aid:EYE: FLUSH W/WATER FOR AT LEAST 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MD ATTN. SKIN: WASH W/SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING AND SHOES. CLEAN BEFORE REUSING. IF
PERSISTENT IRRIT OCCUR S, GET MED ATTN. INHAL: REMOVE TO FRESHAIR.
PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF NOT BREATHING. GET MED ATTN. IF SWALLOWED, DO NOT
INDUCE VOMITING!! GET MD.

Flash Point Method:PMCC
Flash Point:53.0F,11.7C
Lower Limits:1.0%
Upper Limits:12.7%
Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:EVAC HAZ AREA. WEAR NIOSH/MSHA APPRVD SCBA &
FULL PROT EQUIP . COOL FIRE EXPOSD CNTNRS W/H*2O. IN CASE OF LRG
FIRES, ALSO COOL SURROUND (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:VAP ARE HVR THAN AIR AND MAY ACCUMULATE.
VAPORS MAY BE IGNITED AT LOCATIONS DISTANT FROM HANDLING SITE.
FLASHBACK OF FLAME TO HANDLING SITE MAY OCCUR.

Spill Release Procedures:WARNING:FLAM. ELIMINATE ALL IGNITION SOURCES.
HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. LRG SPILLS: EVAC HAZ
AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESP & PROT
CLOTHING. DIKE & CONTAIN. TRANSFER TO STORAGE/SALVAGE
VESSELS(SEESUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME, STRONG OXIDIZING AGENTS. KEEP CNTNRS CLSD. STORE IN COOL,
DRY PLACE W/ADEQ VENT. GROUND EQUIP(SEE SUPP DATA)
Other Precautions:DON'T WELD, HEAT/DRILL ON/NEAR CNTNR; EVEN EMPTIED
CNTNRS CAN CONTAIN EXPLOSIVE VAP. PROVIDE RESP PROT AGAINST SMOKE &
FUMES GENERATED DURING BURNING/DUSTS GENERATED DURING REMOVAL OF
DRY COATINGS.

Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS USE A NIOSH/MSHA APPROVED RESP TO PVNT OVEREXPOS.
IN ACCORD W/29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESP
OR AN AIR-PURIFYING RE SP FOR ORGANIC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR PROT CLOTHING AS REQUIRED TO PREVENT
SKIN CONTACT.
Work Hygienic Practices:WASH W/SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAM CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
FIRE FIGHT PROC:EQUIP & STRUCTURES W/WATER.SPILL PROC:SOAK UP RESIDUAL
W/AN ABSORB SUCH AS CLAY/SAND.FLUSH AREA W/WATER & DISP OF FLUSH
SOLN AS INDICATED BELOW.SMALL SPILLS:TAKE UP W/AN ABSORB MATL &
SEAL TIGHTLY FOR PROPER DISP.HNDLG/STORPREC:TO PVNT ACCUM OF STATIC
CHARGE.IF POURING/TRANSFERRING MATL,(SEE INGRED )

HCC:F3
Boiling Pt:B.P. Text:180F,82C
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:62.4

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.

Waste Disposal Methods:PLACE CONTAM MATL IN SUITABLE CNTNRS FOR DISP.
PLACE IN A DISPOSAL FACILITY APPROVED UNDER RCRA REGULATIONS FOR
HAZ WASTE. USE NON-LEAKING CONTAINERS, SEAL TIGHTLY & LABEL
PROPERLY. DISPOSE OF IN ACCO RDANCE WITH FEDERAL, STATE AND LOCAL
REGS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.