Product ID:CERTANIUM HCR-9076, 16039
MSDS Date:09/09/1988
FSC:6810
NIIN:00N016330
MSDS Number: BLBPC

CERTANIUM ALLOYS & RESEARCH CO

4500 EUCLID AVENUE
CLEVELAND, OH 44103
US

Emergency Phone: 216-391-8300

Info Phone: 216-391-8300

Preparer: BK/DS

Cage: 61404

CERTANIUM ALLOYS & RESEARCH CO

CLEVELAND, OH 44103-1395 US

Telephone: 216-391-8300

Cage: 61404

SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE

RTECS: 9999999ZZ

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 5-10%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 10-30%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE, 2-METHYL-(BUTANE)

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 5-10%

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5-10%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

NO SMOKING IN AREA OF USE. DO NOT USE IN THE

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: IRRIT. CHRONIC: LUNGS,
CNS. EYE/SKIN: IRRIT. VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC
AND IRRITATE UPPER RESPIRATORY SYSTEM. INHAL: MAY CAUSE DIZZSINESS,
GIDDINESS, AND NAUSEA. PROLONGE D AND REPEATED INHALATION: MAY BE
HARMFUL TO RESPIRATORY SYSTEM, CNS, LIVER, AND KIDNEYS. (SEE EFTS
OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GROUP 2B (IARC);
GROUP 2 (NTP); IS A SUSPECTED HUMAN CARCINOGEN (ACGIH) A2.
Effects of Overexposure:HLTH HAZ:CHLOROCARBON/CHLOROFLUOROCARBON (CFC)
MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB
ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS
(E.G.,EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CHLOROCARBONS OR CFC'S.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MIN & CALL MD. SKIN: FLUSH AND WASH THOROUGHLY WITH PLENTY OF WATER
& SOAP. INHAL: IF AFFECTED BY VAPOR, REMOVE TO FRESH AIR. SUPPORT
BREATH ING. (GIVE O*2/ART RESP). INGEST:SEEK A PHYSICIAN
IMMEDIATELY & SHOW THE LABEL OR MSDS. DO NOT INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:40F/4C
Lower Limits:1.0%
Upper Limits:7.1%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FIRE-FIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PROD MAY INCLUDE HCL &
PHOSGENE . EXP TO FIRE/HEAT/PRLNG SUNLIGHT MAY CAUSE BURSTING. IF
USED IN CONFINED SPACES, HAZ VAPS MAY (SUPP DATA)

Spill Release Procedures:EVACUATE AREA. REMOVE ALL SOURCES OF IGNITION,
VENT AREA, WEAR NIOSH/MSHA APPROVED RESP PROT, WEAR SUITABLE PROT
CLOTHING, GLOVES, & EYE/FACE PROT. CLEAN UP W/ABSORBENT MATL,
CONTAIN & PICK UP WASTE M ATL. PUT IN SEALED APPROVED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM
HEAT/SPARKS/FLAMES/SOURCES OF IGNITION. AVOID PRLNG/RPTD BRTHG OF
GAS FUMES/VAPS/SPRAY MIST. AVOID PRLNG/RPTD SKIN (SEE SUPP DATA)
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT EMPTY INTO
DRAINS. ALWAYS READ & FOLLOW DIRECTIONS ON PROD LABEL. ADDTNL
TECHNICAL DATA SHEETS &/OR MATL SAFTEY DATA SHEETS (MSDS) ARE
AVAILABLE UPON REQUEST. FOR PROFESSIONAL & INDUS USE ONLY.(ING 7)

Respiratory Protection:USE ONLY IN WELL VENTILATED AREAS.
Ventilation:LOCAL AND MECHANICAL EXHAUST REQUESTED.
Protective Gloves:SOLVENT RESISTANT.
Eye Protection:CHEMICAL WORKERS GOGGLES.
Other Protective Equipment:IF VENTILATION IS INADEQUATE, WEAR
NIOSH/MSHA APPROVED RESPIRATORY EQUIPMENT.
Work Hygienic Practices:WASH THOROUGHLY AFTER USING.
Supplemental Safety and Health
EXPLO HAZ:SPREAD, BURN/BUILD UP IN LOW AREAS. CONT W/HOT SURF MAY PRDCE
TOX GASES. LD50-LC50 MIX: (ORL,RAT)
>5000MG/KG(DERM,RBT)>10000MG/KG. HNDLG/STOR PREC:CONT. DO NOT TAKE
INTERNALLY. IN CASE OF AC CIDENT/ILLNESS, SEEK MD IMMED & SHOW
LABEL/MSDS. KEEP IN COOL PLACE. USE ONLY IN WELL VENTILATED AREAS.

HCC:V3
Boiling Pt:B.P. Text:104F/40C
Vapor Pres:4.7 ATM
Vapor Density:2.66
Spec Gravity:10.13
Evaporation Rate & Reference:0.75 (ETHER=1)
Solubility in Water:NIL
Appearance and Odor:LIQUID SILVER GRAY AEROSOL-CHLORINATED SOLVENT ODOR
Percent Volatiles by Volume:52.5

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, FLAMES, OR
SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, HCL, AND PHOSGENE .

Waste Disposal Methods:DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. DO NOT PUNCTURE, INCINERATE (OR BURN)
CONTAINER. HAZ WASTE EPA#: D001, U080, U220, U239.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.