Product ID:1,3,5-BENZENETRICARBONYL TRICHLORIDE, 98%,
MSDS Date:12/01/1987
FSC:6810
NIIN:00N016525
MSDS Number: BLBRY

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 60928

Telephone: 414-273-3850

Cage: 60928

1,3,5-BENZENETRICARBONYL TRICHLORIDE

CAS: 4422-95-1

Fraction By Weight: 98%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED
OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES &
SKIN. INHAL:MAY BE FATAL AS A RESUL T OF SPASM, INFLAMMATION &
EDEMA OF THELARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY
EDEMA.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA &
VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IMMED FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINS. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING THE EYELIDS
W/FINGERS. SKIN:IMMED FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST
15 MINS WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INHAL:REMOVE
TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST:CALL MD IMMED
.

Flash Point:>230F,>110C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY LIME OR SODA ASH,
PICK UP, KEEP IN A CLOSED CONTAINER & HOLD FOR WASTE DISPOSAL.
VENTILATE AREA & WASH SPI LL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL DRY PLACE. KEEP TIGHTLY
CLOSED, MOISTURE-SENSITIVE. USE ONLY IN A CHEMICAL FUME HOOD.
Other Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES/ON
SKIN/CLTHG. AVOID PRLNGD/RPTD EXPOS. CORR. LACHRYMATOR. NO SMKNG IN
AREA OF USE. DO NOT USE IN GEN VICIN OF ARC WELDING/OPEN FLAMES/HOT
SURF. HEAT MAY CAUSE FORMATION OF HCL .

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
FOR EXPOSURE OF CONCERN .
Ventilation:CONSULT LOCAL/SAFETY HEALTH AUTHORITIES IF ADDITIONAL
GUIDANCE IS NECESSARY.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SAFETY SHOWER, EYE BATH, FACESHIELD (8 IN
MIN) MAY BE ADDED FOR ADDITIONAL PROTECTION.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH
CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:C2
Melt/Freeze Pt:M.P/F.P Text:94.1F,34.5C
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

STRONG OXIDIZING AGENTS, STRONG BASES, ALCOHOLS. MAY DECOMPOSE ON
EXPOSURE TO MOIST AIR OR WATER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE & HYDROGEN CHLORIDE GAS. HCL AND PHOSGENE .

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL W/A COMBUSTIBLE
SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER
& SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.