Product ID:CERTANIUM 70 F, 14270
MSDS Date:01/27/1990
FSC:9510
NIIN:00N016827
MSDS Number: BLBVQ

CERTANIUM ALLOYS & RESEARCH CO

4500 EUCLID AVENUE
CLEVELAND, OH 44103-1395
US

Emergency Phone: 216-391-8300

Info Phone: 216-391-8300

Preparer: MB

Cage: 61404

CERTANIUM ALLOYS & RESEARCH CO

CLEVELAND, OH 44103-1395 US

Telephone: 216-391-8300

Cage: 61404

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 30-60%

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2MG/M3 FUME; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ZINC (SARA III)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 30-60%

OSHA PEL 10 MG ZNO/M3

ACGIH TLV: 10 MG ZNO/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SILICA, CRYSTALLINE - FUSED

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 0.01-1%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

BORIC ACID, DISODIUM SALT (BORATES) (ANHYDROUS)

CAS: 1330-43-4

RTECS: ED4588000

Fraction By Weight: > 50%

OSHA PEL 10 MG/M3

ACGIH TLV: 1 MG/M3

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1-10%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

GASES WHICH MAY BE FOUND IN THE WELDING OR HIGH

RTECS: 9999999ZZ

AVOID PRLNG CONTACT WITH SKIN. DO NOT TAKE

RTECS: 9999999ZZ

FROM FOOD, DRINK & ANIMAL FEEDS. IN CASE OF

RTECS: 9999999ZZ

LISTED IN SARA TITLE III, SEC 313.

RTECS: 9999999ZZ

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 10-30%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

LD50 LC50 Mixture:LD50: (ORAL,GPIG) > 5 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE IRRIT CHRONIC: RESPIRATORY
OVEREXPOSURE TO WELDING FUMES MAY RESULT IN DIZZINESS, NAUSEA, OR
DRYNESS OR IRRIT OF NOSE, THROAT, & EYES. CHRONIC EXCESS WELDING
FUMES ABOVE PEL OR TLV MAY BE H AZARDOUS BECAUSE PROLONGED &
REPEATED INHALATION MAY BE HARMFUL TO RESPIRATORY SYSTEM. HARMFUL
OR FATAL IF SWALLOWED.
Explanation of Carcinogenicity:NICKEL: CLASS 1 (IARC). CLASS 2 (NTP).
CRYSTALLINE SILICA:CLASS 2A (IARC).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MIN & CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER &
SOAP. INHAL: IF AFFECTED, REMOVE TO FRESH AIR, ADMINISTER OXYGEN &
CALL P HYSICIAN. INGEST: SEEK PHYSICIAN IMMEDIATELY, SHOW MSDS OR
LABEL, INDUCE VOMITING.

Extinguishing Media:WATER/FOG/DRY CHEMICAL/CARBON DIOXIDE
Fire Fighting Procedures:FIREFIGHTER SHOULD WEAR NIOSH/MSHA APPROVED
SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.

Spill Release Procedures:CONTAIN AND PICK UP WASTE MATERIALS. PUT IN A
SEALED APPROVED CONTAINER. LISTED IN SARA TITLE III, SEC 304 AND
313. REPORTABLE QUANTITIY 333 LBS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ARCS, SPARKS, & FLAME MAY BE A SOURCE
OF IGNIT OF COMBUST MATLS. AVOID PRLNG/RPTD BRTHNG OF GAS, FUMES.
IF VENT IS INADEQ, WEAR RESP EQUIP.(INGRED 8)
Other Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP ONLY IN ORIGINAL
LABELED CONTAINERS. ALWAYS READ & FOLLOW DIRECTIONS ON PRODUCT
LABEL. ADDTN TECH DATA SHEETS &/OR MSDS ARE AVAILABLE UPON REQUEST.
FOR PROFESSIONAL AND INDUSTRIAL USE ONLY.

Respiratory Protection:USE NIOSH/MSHA APPROVED HOOD, RESPIRATOR, OR
SUPPLIED AIR MASK.
Ventilation:LOCAL & MECHANICAL EXHAUST REQUIRED. SPECIAL WELDERS, ANSI
Z49.1.
Protective Gloves:WELDERS PROTECTIVE GLOVES.
Eye Protection:FACESHIELD/COLOR ABSOPTIVE LENS
Other Protective Equipment:WELDERS LEATHER APRONS, SLEEVES, AND
LEGGINGS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD: OF BOTH DEPEND ON THE ALLOY BEING WELDED, PROCESS,
PROC, & ELECTRODES USED. CONSTITUENTS OF FUME MAY BE DIFFERENT FROM
INGRED LISTED, & MAY INCLUDE PARTICLES CNTNG IRON, MANGANESE, SI
LICON, CHROMIUM, NICKEL,/OTHER AMORPHOUS SLAGS. GASES MAY INCLUDE
CO, OZONE, METAL OXIDESS, & (INGRED 7)

HCC:N1
Appearance and Odor:FLUX COATED ROD, SOLID

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES AND GASES FROM WELDING AND HIGH
TEMP CUTTING CANNOT BE CLASSIFIED SIMPLY. THE COMPOSITION AND
QUANTITY.(SUPP DATA)

Waste Disposal Methods:DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.