Product ID:N,N-DIMETHYLFORMAMIDE, 99.9+%,HPLC GRADE, 2
MSDS Date:09/21/1989
FSC:6850
NIIN:00N017197
MSDS Number: BLCDH

ALDRICH CHEMICAL CO

MILWAUKEE, WI 53201

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 60928

ALDRICH CHEMICAL CO INC

355 MILWAUKEE, WI 53233 US

Telephone: 414-273-3850

Cage: 60928

DIMETHYLFORMAMIDE

CAS: 68-12-2

RTECS: LQ2100000

Fraction By Weight: 99.9%

OSHA PEL S, 10 PPM

ACGIH TLV: S, 10 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

THE MANUFACTURER STATES THAT NO HAZARDOUS INGREDIENTS ARE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT)2800 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRIT TO EYES, MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION.
EXPOSURE CAN CAUSE STOMACH PAINS, VOMITING, DIARRHEA, NAUSEA,
DIZZINESS AND HEADACHE. CHRONIC: DAMAGE TO LIVER AND KIDNEYS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS
WITH FINGERS. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST
15 MIN WHI LE REMOVING CONTAM CLOTHING AND SHOES. INHAL: REMOVE TO
FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE
O*2. CALL A PHYS. INGEST: CALL MD IMMEDIATELY .

Flash Point:136F,58C
Lower Limits:2.2%
Upper Limits:15.2%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . COMBUSTIBLE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. WEAR
NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATH VAP. AVOID CONTACT
W/EYES, SKIN & CLTHG. AVOID PRLNGD/RPTD EXPOS. READILY ABSORBED
THROUGH SKIN. WASH THORO AFTER HANDLING.
Other Precautions:IRRITANT. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT
AND OPEN FLAME. STORE IN A COOL DRY PLACE.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES.(SEE SUPP DATA)
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING. SAFETY
SHOWER AND EYE BATH.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISCARD CONTAMINATED SHOES.
Supplemental Safety and Health
EYE PROT: MAY ADD FULL LENGTH FACESHIELD TO GOGGLES .

HCC:F4
Boiling Pt:B.P. Text:307F,153C
Melt/Freeze Pt:M.P/F.P Text:-78F,-61C
Vapor Pres:2.7MM @20C
Vapor Density:2.5
Spec Gravity:0.944
Appearance and Odor:COLORLESS LIQUID.

ACID CHLORIDES, OXIDIZING AGENTS, CHLOROFORMATES, REDUCING AGENTS,
HALOGENS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.