Product ID:312-91, HEAVY DUTY GLOSS ENAMEL
MSDS Date:03/20/1992
FSC:8010
NIIN:00N027762
MSDS Number: BNBFS

O BRIEN CORP

450 EAST GRAND AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 415-761-2300

Cage: 30806

O BRIEN CORPORATION

SOUTH SAN FRANCISCO, CA 94080-6207 US

Cage: 72556

REPORTS HAVE ASSOC PRLNGD

RTECS: 9999999ZZ

SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL

RTECS: 9999999ZZ

HAS BEEN SHOWN TO CAUSE DMG TO KIDNEYS, LIVER,

RTECS: 9999999ZZ

BLOOD STORING ORGAN (SPLEEN), & PERIPHERAL NERVOUS

RTECS: 9999999ZZ

WHILE FLUSHING EYES, SEND FOR MEDICAL

RTECS: 9999999ZZ

TLV IS OBSERVED. (STODDARD SOLV) REPORTS HAVE ASSOC

RTECS: 9999999ZZ

LOW ORAL TOX. NO TOX

RTECS: 9999999ZZ

IRRIT. (STODDARD

RTECS: 9999999ZZ

HAZ, DO NOT INDUCE VOMIT. INHAL MAY IRRIT NOSE,

RTECS: 9999999ZZ

PRLNGD & RPTD CONTACT MAY CAUSE SKIN IRRIT. INGEST

RTECS: 9999999ZZ

DEPRESS. SYMP MAY INCL HDCH, DIZZ, CONFUSION, NAUS,

RTECS: 9999999ZZ

ANESTHETIC. IRRIT OF RESP TRACT &

RTECS: 9999999ZZ

HDCH, DIZZ, STAGGERING GAIT,

RTECS: 9999999ZZ

CAUSES IRRIT.

RTECS: 9999999ZZ

HAVE ASSOC LRG SINGLE OVEREXP TO SOLV W/KIDNEY,

RTECS: 9999999ZZ

REPORTS HAVE ASSOC RPTD & PRLNGD OCCUP EXPOS TO

RTECS: 9999999ZZ

TO AS SOLV/PAINTERS' SYNDROME). (PROPYLENE OXIDE)

RTECS: 9999999ZZ

CARCIN. (TITANIUM DIOXIDE) LAB STUDIES SHOW THAT

RTECS: 9999999ZZ

DIOXIDE CAUSES CANCEROUS TUMORS IN RATS. RESPONSE

RTECS: 9999999ZZ

OVERWHELMING THE NORMAL LUNG CLEARANCE MECHANISMS.

RTECS: 9999999ZZ

5.00.

CAS: 64742-88-7

Fraction By Weight: 15%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

ALIPHATIC PETROLEUM DISTILLATES

Fraction By Weight: 20%

445. LD50

CAS: 75-56-9

RTECS: TZ2975000

Fraction By Weight: <0.1%

OSHA PEL 100 PPM

ACGIH TLV: 20 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

(ORAL,RAT) 9500

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

(ORAL,RAT) 15300 MG/KG.

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <1%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

LD50 LC50 Mixture:SEE INGREDIENTS 3, 4 & 5.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:(ACUTE) (MINERAL SPIRITS) INGEST:ASPIR
OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM WHICH CAN BE
FATAL. DECISION TO INDUCE VOMIT BASED ON MED ADVICE FROM PHYS/POIS
CNTRL CENTER, PHYS. (ALIPHAT IC PETRO DISTILLATES) INGEST MAY CAUSE
IRRIT OF DIGESTIVE TRACT. ASPIR CAN BE HAZ. DO NOT INDUCE
VOMIT.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:PROPYLENE OXIDE: IARC GRP 2A, NTP GRP 2.
Effects of Overexposure:HLTH HAZ: INHAL MAY CAUSE NOSE & THROAT IRRIT &
CAN CAUSE HDCH, DIZZ, NAUS, & NARCOSIS. IRRIT TO SKIN & EYES.
(PROPYLENE OXIDE) INGEST: MOD TOX, CAUSES GI IRRIT, NAUS, VOMIT &
DIARR. ASPIR OF MATL INT O LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM
WHICH CAN BE FATAL. DECISION TO INDUCE VOMIT MUST BE BASED ON (SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY
DISORDERS. PREPLACEMENT & PERIODIC EXAMS SHOULD BE GIVEN TO THOSE
EXPOSED REG.

First Aid:INGEST:DRINK 1-2 GLASSES OF H*2O TO DILUTE.KEEP PERSON
WARM,QUIET & GET MED ATTN IMMED.DECISION TO INDUCE VOMIT MUST BE
BASED ON ADVICE OF PHYS/POIS CTL CTR.NEVER GIVE ANYTHING BY MOUTH
TO AN UNCON PE RSON.INHAL: REMOVE FROM AREA TO FRESH AIR.RESTORE
BRTHG. CONSULT PHYS.EYE: IMMED BEGIN FLUSHING EYES W/COOL H*2O FOR
AT LEAST 15 MIN,OCCASIONALLY LIFTING LIDS TO ENSURE THORO RINSING.
(ING 25)

Flash Point:110F,43C
Lower Limits:1.00%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.H*2O MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP &
POSS AUTO-IGNIT/EXPLO WHEN EXPOS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, SPARKS, FLAME & ELEC EQUIP. CLSD CNTNRS MAY EXPLO WHEN EXPOS
TO EXTREME HEAT. APPLIC TO HOT SURFS REQS (SUPP DATA)

Spill Release Procedures:REMOVE SOURCES OF IGNITION. SOAK UP AND REMOVE
WITH INERT ABSORBENT MATERIAL WITH NON-SPARKING TOOLS. PROVIDE
ADEQUATE VENTILATION. USE NIOSH/MSHA APPROVED VAPOR RESPIRATOR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE UPRIGHT IN SEALED CONTAINERS AND
USE AWAY FROM HIGH TEMPERATURE, SPARKS AND FLAME. AVOID PROLONGED
CONTACT WITH SKIN.
Other Precautions:DO NOT INGEST. KEEP CONTAINER TIGHTLY SEALED WHEN NOT
IN USE. KEEP OUT OF REACH OF CHILDREN. FOR BAKING FINISHES,
VENTILATE VAPORS EMITTED ON HEATING. FOLLOW RESPIRATOR MFR
RECOMMENDATIONS FOR USE.

Respiratory Protection:USE NIOSH/MSHA APPRVD PROPERLY FITTED MECH
RESP/MASK TO AVOID BRTHG VAP/SPRAY MIST DURING MIXING, SPRAYING,
APPLIC/CURING. USE TC 19C NIOSH/MSHA APPRVD PROPERLY FITTED POS AIR
SUPP RESP IN CONFINED AR EAS/WHEN OVERSPRAY IS PRESENT.
Ventilation:PROVIDE SUFF VENT IN VOL & PATTERN TO KEEP AIR CONTAM CONC
BELOW APPLIC OSHA PERMISSIBLE EXPOS LEV/ACGIH'S TLV LIMIT.
Protective Gloves:SYNTHETIC RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE OVERALLS RECOMMENDED.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING. DISCARD
CONTAMINATED SHOES.
Supplemental Safety and Health
FIRE FIGHT PROC: TO EXTREME HEAT. EXPLO HAZ: SPECIAL PREC. DURING EMER
CNDTNS, OVER-EXPOS TO DECOMP PRODS MAY CAUSE HLTH HAZ. OBTAIN MED
ATTN. EFTS OF OVEREXP: ADVICE FROM PHYS/POIS CNTRL CENTER. INHA L:
IRRIT UPPER RESP TRACT. SYMP OF ATAXIA. EYE: IRRIT & POSS DMG.
SKIN: IRRIT, PRLNGD CONTACT CAUSES BURNS. (ING 6)

HCC:F4
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:ING 1,3,5
Vapor Density:HVR/AIR
Spec Gravity:1.07
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:51.41

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, BASES.
Stability Condition to Avoid:HIGH TEMPERATURE.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CO, CO*2, AND NO*2.

Waste Disposal Methods:DISPOSE IN SEALED METAL CONTAINER AWAY FROM HEAT
AND FLAME IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.