Product ID:06019, MARINE CLEANER AND DEGREASER AEROSOL
MSDS Date:11/30/1987
FSC:6850
NIIN:00N028771
MSDS Number: BNBKJ

CRC CHEMICALS

885 LOUIS DR
WARMINSTER, PA 18974
US

Emergency Phone: 215-674-4300

Info Phone: 215-674-4300

Preparer: ALLEN B. REED

Cage: CRCCE

CRC INDUSTRIES, INC.

WARMINSTER, PA 18974-2820 US

Telephone: 215-674-4300/800-424-9300

Cage: 10136

1,1,1-TRICHLOROETHANE;(METHYL CHLOROFORM) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 89.2%

OSHA PEL 350 PPM;450 STEL

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-DIOXANE; (DIETHYLENE ETHER) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

3-BUTYN-2-OL, 2-METHYL-;(METHYL BUTYNOL)

CAS: 115-19-5

RTECS: ES0810000

Fraction By Weight: <6.8%

SEC BUTYL ALCOHOL

CAS: 78-92-2

RTECS: EO1750000

OSHA PEL 150 PPM

ACGIH TLV: 100 PPM; 9293

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 4%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:HEADACHES, DIZZINESS,
ANESTHESIA, UNCONSCIOUSNESS. EYE:CAUSES PAIN AND SOME IRRITATION.
SKIN:IRRITATION ON REPEATED EXPOSURES. CHRONIC:REPEATED
OVEREXPOSURES MAY CAUSE LIVER AND KIDNEY EFFECTS.
Explanation of Carcinogenicity:P-DIOXANE IARC GROUP 2B; NTP GROUP 2
Effects of Overexposure:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LABORATORY
ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS
(E.G., EPINEPHRINE) MAY BE CONTRAIND ICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CHLOROCARBONS .
Medical Cond Aggravated by Exposure:HIGH LEVELS (8000 PPM+) OF VAPOR
MAY CAUSE CARDIAC ARRTHYMIAS.

First Aid:INHAL:MOVE TO FRESH AIR, APPLY ARTIFICIAL RESPIRATION IF
NECESSARY. EYE:FLUSH FOR AT LEAST 15 MINUTES WITH LARGE AMOUNTS OF
WATER. SKIN:REMOVE CONTAMINATED CLOTHING; WASH EXPOSED AREAS WITH
SOAP & WAT ER. INGEST:DO NOT INDUCE VOMITING. CALLMD. (IF SYMPTOMS
PERSIST, CALL MD).

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7%
Upper Limits:15.5%
Extinguishing Media:WATER, FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY EXPLODE IF THEIR
TEMPERATURES EXCEEDS 130F. THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL, PHOSGENE .

Spill Release Procedures:USUALLY NOT A PROBLEM WITH AEROSOLS. AREA
SHOULD BE VENTILATED AND ABSORBENT USED TO PICK UP EXCESS MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AEROSOLS AWAY FROM HEAT. AVOID
PROLONGED SKIN CONTACT OR BREATHING OF VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:IF VAPORS ARE SUSPECTED IN LOW AREAS, DO NOT
ENTER UNLESS NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IS USED AND
OBSERVER IS PRESENT FOR ASSISTANCE. ABOVE TLV, USE NIOSH/MSHA
APPROVED SCBA (AIR MASK O R VAPOR MASK).
Ventilation:SINCE VAPORS ARE HEAVIER THAN AIR, AEROSOLS SHOULD NOT BE
USED IN CONFINED AREAS OR LOW SPOTS W/OUT ADEQ (SUPP DATA).
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT NORMALLY REQUIRED FOR AEROSOL PRODUCT
USAGE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT:VENTILATION. MAINTAIN VAPOR CONCENTRATION MEANS IF NECESSARY.

Boiling Pt:B.P. Text:164F,73C
Vapor Pres:73 @ 20C
Vapor Density:4.16
Spec Gravity:1.293 @ 70F
Evaporation Rate & Reference:RAPID
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID-IRRITATING ODOR AT HIGH
CONCENTRATIONS
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID STORAGE IN ALUMINUM CONTAINERS OR CONTACT WITH ALUMINUM AND/OR
ZINC POWDER.
Stability Condition to Avoid:AVOID EXPOSURES TO OPEN FLAMES, ARCS, AND
HIGH TEMPERATURES.
Hazardous Decomposition Products:THERMAL-HYDROGEN CHLORIDE, CHLORINE &
SOME PHOSGENE.

Waste Disposal Methods:DISCARDED FULL CANS OR PARTIALLY FILLED CANS ARE
CONSIDERED HAZARDOUS WASTE-DISPOSE OF IN CONFORMANCE WITH LOCAL,
STATE, AND FEDERAL REGULATIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.