Product ID:BARE WIRE 625(AWS A5.14)
MSDS Date:08/01/1990
FSC:3439
NIIN:01-137-8523
MSDS Number: BNBTQ

NATIONAL WELDING ALLOYS, INC.

1600 SOUTH CANAL STREET
PITTSBURGH, PA 15215
US

Emergency Phone: 412-781-4255/800-424-9300(CHEMTREC)

Info Phone: 412-781-4255

Cage: 0ACE2

NATIONAL WELDING ALLOYS INC

PITTSBURGH, PA 15215-2624 US

Telephone: 412-781-4255

Cage: 0ACE2

ALUMINUM (SARA III)

CAS: 7429-90-5

RTECS: BD0330000

Fraction By Weight: 0.40%

OSHA PEL 15MG/M3 DUST/5 FUME

ACGIH TLV: 10MG/M3 DUST; 9192

CARBON

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 0.10%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9192

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 20-23%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COLUMBIUM

Fraction By Weight: 3.1-4.1%

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 0.50%

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2MG/M3 FUME; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 5.00%

OSHA PEL 10 MG/M3(FE2O3 FUME)

ACGIH TLV: 5 MG/M3 (FE2O3 FUME)

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 0.50%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

MOLYBDENUM

CAS: 7439-98-7

RTECS: QA4680000

Fraction By Weight: 8-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3; 9293

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: >58.0%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

SILICON

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 0.50%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

TITANIUM, METAL

CAS: 7440-32-6

RTECS: XR1700000

Fraction By Weight: 0.40%

LD50 LC50 Mixture:TLV FOR WELDING FUMES IS 5 MG/M3
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: FUMES AND GASES CAN CAUSE EYES
AND UPPER RESPIRATORY SYSTEM IRRITATION, AND CENTRAL NERVOUS SYSTEM
EFFECTS. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN
KILL. NOISE CAN DAMAGE HEA RING. CHRONIC: NEUROLOGICAL DAMAGE, LUNG
FIBROSIS, PNEUMOCONIOSIS.
Explanation of Carcinogenicity:NICKEL AND CHROMIUM ARE LISTED UNDER
IARC AND NTP.
Effects of Overexposure:SHORT TERM EXPOSURE: NAUSEA, FEVER, DIZZINESS,
DRYNESS, IRRITATION OF EYES, NOSE AND THROAT, SKIN SENSITIVITY.
ACUTE EXPOSURE: SAME SYMPTOMS TO HIGHER DEGREE AS WELL AS WATERY
EYES, HEADACHE, BREATHIN G DIFFICULTY, FREQUENT COUGHING, CHEST
PAINS.
Medical Cond Aggravated by Exposure:AGGRAVATION OF EXISTING RESPIRATORY
OR ALLERGIC CONDITIONS.HIGHER LEVEL OF LUNG RELATED PROBLEMS AMONG
SMOKERS.

First Aid:INHALATION: REMOVE FROM EXPOSURE. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF NOT BREATHING, GIVE CPR. IF NO DETECTABLE PULSE,
GIVE HEART MASSAGE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 1 5 MINUTES. SKIN: WASH WITH SOAP AND WATER. INGESTION: SEEK
MEDICAL ATTENTION.

Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:IF THIS MATERIAL IS REDUCED TO POWDER
FORM, CAUTION MUST BE USED TO PREVENT FIRE OR EXPLOSION. TO
EXTINGUISH USE DRY SAND, DRY GRAPHITE.

Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUE
AND PLACE IN APPROPIATE DISPOSAL CONTAINER. AVOID INHALATION AND
SKIN EXPOSURE.

Handling and Storage Precautions:STORE IN DRY AREA. ELECTRODES EXPOSED
TO MOISTURE MAY EXPLODE VIOLENTLY IF USED. DRY MOIST RODS BY BAKING
AT 300F FOR TEN HOURS.
Other Precautions:TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES.
MONITOR AIR TO ENSURE ACCEPTABLE EXPOSURES. AVOID ELECTRICAL SHOCK
BY MAINTAINING DRY WORK AREA.

Respiratory Protection:FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR IN
CONFINED SPACES OR WHERE VENTILATION DOES NOT KEEP EXPOSURE BELOW
TLV.
Ventilation:LOCAL EXHAUST TO KEEP BELOW TLV.
Protective Gloves:WELDER'S GLOVES.
Eye Protection:HELMET OR FACE SHIELD WITH FILTER LENS.
Other Protective Equipment:SUBSTANTIAL DARK CLOTH, ARM PROTECTOR,
APRON, HAT AND SHOULDER PROTECTION. AIR SAMPLING TO DETERMINE
CORRECTIVE MEASURES
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING, SMOKING OR
USING SANITARY FACILITIES.
Supplemental Safety and Health
NONE.

HCC:N1
Appearance and Odor:SOLID ROD, GREY TO SILVER IN COLOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:FUMES OF METALS AND METAL OXIDES FROM
ELECTRODE AND BASE METAL, CARBON MONOXIDE, CARBON DIOXIDE, OZONE,
NITROGEN OXIDES.

Waste Disposal Methods:CONSULT WITH YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF FUMES, FLUX OR WELD GRINDING RESIDUE FROM THE WORK AREA
OR FROM FILTERS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.