Product ID:FREON TF CLEANING AGENT FREON PRECISION CLEANING AGENT
MSDS Date:11/23/1995
FSC:6850
NIIN:00-033-8851
MSDS Number: BNBXX

Emergency Phone: 800-441-3637/800-424-9300(CHEMTREC)

Info Phone: 800-441-9442/800-424-9300(CHEMTREC)

Cage: 5P414

Telephone: 800-441-3637-MED 800-424-9300-TRAN

Cage: 5P414

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL; 96

LD50 LC50 Mixture:LD 50 ORAL RAT 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OR INGESTION MAY CAUSE
TEMPORARY NERVOUS SYSTEM DEPRESSION; HIGHER CONCENTRATIONS MAY
ALTER HEART ELECTRICAL ACTIVITY. SKIN & EYE CONTACT MAY CAUSE MILD
IRRITATION. INGESTION HAZARD IS PRIM ARILY ASPIRATION. CHRONIC:
PROLONGED SKIN CONTACT MAY CAUSE TINGLING OR NUMBNESS.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP OR OSHA.
Effects of Overexposure:EYES: MILD IRRITATION, TEARING, BLURRED VISION.
SKIN: MILD IRRITATION, DRYNESS. INHALATION/INGESTION: TEMPORARY
NERVOUS SYSTEM DEPRESSION, DIZZINESS, HEADACHE, CONFUSION,
INCOORDINATION, LOSS OF CONSC IOUSNESS. ASPIRATION: COUGHING,
GASPING, CHOKING, SHORTNESS OF BREATH.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
PERSONS WITH PRE- EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE
TO THE EFFECTS OF THIS AGENT.

First Aid:INHALATION-REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. EYE/SKIN-FLUSH WITH WATER FOR 15 MINUTES. IF
IRRITATION PRESIST S, GET MEDICAL ATTENTION. INGESTED-GET MEDICAL
ATTENTION. DO NOT INDUCE VOMITING AS THE HAZARD OF ASPIRATING INTO
THE LUNGS IS TOO GREAT.

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR.

Spill Release Procedures:USE SCBA FOR LARGE SPILLS. VENTILATE AREA. DO
NOT FLUSH TO SEWERS. DIKE SPILLS. COLLECT ON ABSORBENT MATERIAL &
TRANSFER TO STEEL DRUMS FOR RECOVERY OR DISPOSAL. COMPLY WITH
FEDERAL, STATE AND LOCAL R EGULATIONS ON REPORTING RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA. DO NOT HEAT ABOVE 125F.
Other Precautions:AVOID BREATHING VAPOR AND PROLONGED SKIN EXPOSURE. US
EWITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW
RECOMMENDED LIMITS.

Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS
FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH
APPROVED AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29
CFR 1910.134.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERVIOUS-BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:CHEMICAL SPLASH GOGGLES W/FACESHIELD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: ACTIVATED CHARCOAL SLURRY MAY BE ADMINISTERED, 5
ML/KG OR 350 ML FOR AN ADULT. BECAUSE OF RISK OF CARDIAC
DYSRHYTHMIAS, CATECHOLAMINE DRUGS SHOULD BE USED WITH SPECIAL
CAUTION. BECA USE OF DANGER OF ASPIRATION, GASTRIC LAVAGE SHOULD
NOT BE USED UNLESS THE RISK IS JUSTIFIED.

HCC:T6
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:31.0F,-0.6C
Decomp Temp:Decomp Text:572F,300C
Vapor Pres:334 @ 77F
Vapor Density:2.9
Spec Gravity:1.574
pH:7
Evaporation Rate & Reference:>1 (CCL4 = 1)
Solubility in Water:NEGLIGIBLE (0.02%)
Appearance and Odor:CLEAR COLORLESS LIQUID. SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALAKLI OR ALKALINE EARTH METALS-POWDERED ALUMINUM, ZINC, BERYLLIUM,
ETC.
Stability Condition to Avoid:MATERIAL IS STABLE; HOWEVER, AVOID HIGH
HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS,
POSSIBLY CARBONYL HALIDES.
Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. EPA
HAZARDOUS WATES NOS. F001 AND F002 MAY APPLY TO WASTE MATERIALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.