Product ID:00365 TEXACO UNLEADED
MSDS Date:12/15/1992
FSC:9130
NIIN:01-272-0983
MSDS Number: BSBBJ

TEXACO REFINING AND MARKETING INC

1111 RUSK ST
HOUSTON, TX 77002-3310
US

Emergency Phone: 914-831-3400 800-424-9300(CHEMTREC)

Info Phone: 512-459-6543

Preparer: MANAGER,PRODUCT SERVICES

Cage: 2R503

TEXACO REFINING AND MARKETING INC

HOUSTON, TX 77002-3310 US

Telephone: 713-650-5206

Cage: 2R503

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 95-99.9%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

HYDROCARBON GAS CONTAINED IN INGREDIENT #1

RTECS: MW3860000

OLEFINS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: .2-3.5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:LD50 ORAL RAT(EST)=5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES:IRRITANT.SKIN:THIS MATERIEL IS
ABSORBED BY THE SKIN(HAZARD LEVEL HAS NOT BEEN
DETERMINED);IRRITANT.INHAL:IRRITATES NOSE AND THROAT.MAY CAUSE
ASPHYXIATION IN ENCLOSED SPACES.INGEST:MAY CAUSE LUNG DAMAGE IF
VOMITTED AFTER SWALLOWING.CHRONIC:BENZENE CAUSES LEUKEMIA IN
HUMANS.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES:REDNESS.SKIN:REDNESS,SWELLING.INHAL:
HEADACHE,NAUSEA,VOMITING,DIZZINESS,DROWSINESS,EUPHORIA,LOSS OF
COORDINATION,DISORIENTATION.
Medical Cond Aggravated by Exposure:REPEATED SKIN CONTACT MAY AGGRIVATE
EXISTING DERMATITIS.

First Aid:EYES:FLUSH WITH WATER FOR 15 MINUTES WHILE LIFTING LIDS.CALL
PHYSICIAN.SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND
WATER.CALL PHYSICIAN IF IRRITATION PERSISTS.INGEST:DO NOT INDUCE
VOMITING WI THOUT ADVICE OF A PHYSICIAN.GET PROMPT QUALIFIED
MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL
RESPIRATION OR OXYGEN IF NEEDED.GET PROMPT MEDICAL ATTENTION.

Flash Point Method:COC
Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:850F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,FOAM,CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES,BUT CAN BE
USED TO COOL FIRE EXPOSED CONTAINERS.USE A SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND TRAVEL
ALONG THE GROUND,POSING A FLASHBACK HAZARD(FLOWING GASOLINE
GENERATES STATIC ELECRICITY).

Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.VENTILATE
AREA.AVOID BREATHING VAPORS;STAY UPWIND;USE A SCBA.REMOVE WITH A
NON- FLAMMABLE ADSORBANT(EG.DIATOMACEOUS EARTH);PUT IN AN
APPROPRIATE CONTAINER FOR DISPOSAL.KE EP OUT OF WATERWAYS.
Neutralizing Agent:NONE

Handling and Storage Precautions:TRANSPORT,HANDLE AND STORE PER OSHA
1910.106.GROUND AND BOND SHIPPING CONTAINERS.USE SPARK-PRROF TOOLS.
Other Precautions:USE CAUTION WHEN OPENING CONTAINERS WHICH MAY BE
UNDER PRESSURE.

Respiratory Protection:IN THE ABSENCE OF ENVIROMENTAL CONTROLS A NIOSH
ORGANIC VAPOR RESPIRATOR MAY BE USED;IN ENCLOSED SPACES A
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED.
Ventilation:ENVIRONMENTAL CONTROLS TO MAINTAIN TLV BELOW 500PPM.
Protective Gloves:NITRILE,TEFLON,VITON.
Eye Protection:GOGGLES/FACE SHIELD.
Other Protective Equipment:CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE.

HCC:F2
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:>90F,>32C
Vapor Pres:465-775
Vapor Density:3-4
Spec Gravity:.7-.77
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID;LIGHT STRAW TO LIGHT RED;GASOLINE-LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT,SPARKS ...OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON
DIOXIDE,IRRITATING ALDEHYDES AND KETONES.

Waste Disposal Methods:THIS MATERIEL IS CONSIDERED TO BE HAZARDOUS PER
RCRA,WITH REGARD TO BENZENE TOXICITY AND IGNITABILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.