Product ID:CARBAMATE 1.5 EC TH 1 GAL, 12-23825-00
MSDS Date:01/19/1987
FSC:6840
NIIN:00N040929
MSDS Number: BSBSX

THOMPSON-HAYWARD CHEMICAL CO

5200 SPEAKER RD
KANSAS CITY, KS 66106
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 913-321-3131

Preparer: EDWARD E. CHAPMAN

Cage: 5G633

THOMPSON-HAYWARD CHEMICAL CO

KANSAS CITY, KS 66106 US

Telephone: 913-321-3131

Cage: 5G633

CARBAMIC ACID, METHYL-, O-ISOPROPOXYPHENYL ESTER;

CAS: 114-26-1

RTECS: FC3150000

Fraction By Weight: 14.6%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

OSHA PEL 500 PPM;1000 PPM, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,1,1-TRICHLOROETHANE

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM;450 STEL

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: CONTRICTED PUPILS. SKIN:
SWEATING. INHALATION: HEADACHES, DIZZINESS, ATAXIA, RESPIRATORY
DEPRESSION, CHOLINESTERASE DEPRESSION. INGESTION: NAUSEA, VOMITING,
SWEATING. METHYLENE CHLORIDE IS CURRE NTLY UNDER INVESTIGATION FOR
CARCINOGENIC EFFECTS. CHOLINESTERASE INHIBITOR. CHLOROCARBON
MATERIALS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: GRP 2B (IARC VOL
SUP7, P194, '87), ANTICIP TO BE A CARCINOGEN (NTP 6TH ANN RPT,
'91).
Effects of Overexposure:HEALTH HAZARDS: HAVE PRODUCED SENSITIZATION OF
MYOCARDIUM TO EPINEPHRINE IN LABORATORY ANIMALS AND COULD HAVE
SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS
APART TO ENSURE FLUSHING OF ENTIRE EYE SURFACE. SKIN: REMOVE
CONTAMINATED CLOTHING AND CLEAN BEFORE REUSE. FLUSH SKIN WITH
WATER. SHOWER THO ROUGHLY WASHING SKIN AND HAIR WITH SOAPAND WATER.
INHALATION: REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING.
CONSULT PHYSICIAN.

Flash Point:NONFLAMMABLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . DO NOT BREATHE FUMES. STAY OUT OF
SMOKE. PVNT SPREAD OF CONTAM RUNOFF.
Unusual Fire/Explosion Hazard:MAY GENERATE PHOSGENE GAS, OR METHYL
ISOCYANATE IN FIRE. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL
.

Spill Release Procedures:ABSORB SPILLED MATERIAL. SCRUB CONTAMINATED
AREA WITH STRONG DETERGENT AND BLEACH. RINSE WITH WATER. AVOID SKIN
CONTACT AND BREATHING VAPORS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MIN TEMPERATURE 32F. DO NOT STORE NEAR
MATERIALS INTENDED FOR USE OR CONSUMPTION BY HUMANS OR ANIMALS.
PERIODICALLY INSPECT STORED MATERIALS.
Other Precautions:DO NOT CONTAM WATER SUPPLIES. DO NOT SWALLOW. AVOID
BRTHG VAP & CONT W/SKIN. WASH THORO AFTER USING. NO SMOKING IN AREA
OF USE. DO NOT USE IN GEN VICINITY OF ARC WELDING, OPEN FLAMES/HOT
SURFS. HEAT & /OR UV RADIA MAY CAUSE FORM OF (SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE OR FULL
FACE RESPIRATOR WITH PESTICIDE CANISTERS.
Ventilation:LOCAL EXHAUST AS REQUIRED. MECHANICAL (GENERAL) AS
REQUIRED.
Protective Gloves:LATEX OR NEOPRENE GLOVES.
Eye Protection:ANSI APRV CHEM WORK GOGG .
Other Protective Equipment:RUBBER BOOTS AND APRON.
Work Hygienic Practices:LAUNDER CLOTHING DAILY AFTER USE. WASH
THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
OTHER PRECAUTIONS: HCL AND/OR PHOSGENE .

Boiling Pt:B.P. Text:SEE ING 1
Melt/Freeze Pt:M.P/F.P Text:SEE ING 1
Vapor Pres:SEE ING 1
Spec Gravity:1.2294 (H*2O=1)
Solubility in Water:EMULSIFIES
Appearance and Odor:LIGHT AMBER LIQUID, METHYLENE CHLORIDE ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ALKALIES.
Stability Condition to Avoid:HEAT. EXCESS HEAT ABOVE 100F CAUSES
PRESSURE BUILDUP IN CONTAINERS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
PHOSGENE, METHYL ISOCYANATE, AND MONOMETHYLAMINE. HCL .

Waste Disposal Methods:USE AN APPROVED DISPOSAL FACILITY OR BURN IN AN
INCINERATOR APPROVED FOR PESTICIDE DESTRUCTION. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.