Product ID:GLOSS BLACK CURB MARKING PT, 108-265
MSDS Date:01/26/1990
FSC:8010
NIIN:00N043895
MSDS Number: BSBVR

D J SIMPSON CO

111 SOUTH MAPLE AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 415-873-5990

Info Phone: 415-873-5990

Cage: HO834

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

1@68F

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 4%

OSHA PEL 25 PPM, S

ACGIH TLV: 25 PPM, S

8.8@68F

CAS: 78-83-1

RTECS: NP9625000

Fraction By Weight: <5%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANOL, 2-(2-BUTOXYETHOXY)-; (ETHYLENE GLYCOL MONOBUTYL

CAS: 112-34-5

RTECS: KJ9100000

Fraction By Weight: <5%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

MANGANESE; (MANGANESE COMPOUNDS)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST

AMMONIA

CAS: 7664-41-7

RTECS: BO0875000

Fraction By Weight: <1%

OSHA PEL 35 PPM STEL

ACGIH TLV: 25 PPM;35 PPM STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

COBAL; (COBALT COMPOUNDS) (MFR CAS # 7440-38-4)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.05 MG/M3 (CO)

ACGIH TLV: 0.05 MG/M3 (CO)

1.9 LB/GL (236 G/L)

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ANESTH. IRRIT OF RESP
TRACT W/HDCH, NAUS, DIZZ, UNCON/COMA. DIZZ, IRRIT OF RESP TRACT &
EVEN ASPHY @ HIGH CONC. NOTE TO PHYS: INGEST OF PROD/SUBSEQUENT
VOMIT CAN RSLT IN ASPIR OF LIGHT HYD ROCARBON LIQ INTO LUNGS WHICH
CAN CAUSEFATAL CHEM PNEUM. SKIN: IRRIT, DRY/CRACK. EYE: IRRIT/EYE
BURN. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SKIN ABSORP:IRRIT/BURN SENSATION,
CRACK, DEFAT & DERM MAY OCCUR ON PRLNGD EXPOS. INGEST: DIZZ, NAUS,
NOT EXPECTED TO HAVE ACUTE SYSTEMIC TOX. ANIMAL STUDIES HAVE
CLEARLY DEMONSTRATED DOSE-REL ATED ADVERSE EFTS ON CNS,
HEMATOPOIETICTISSUE, BLOOD, KIDNEYS, & LIVER ASSOC W/ADMIN OF
ETHYLENE GLYCOL (SUPP DATA)
Medical Cond Aggravated by Exposure:PREEXISTING LUNG, HEART, KIDNEY,
LIVER AND SKIN DISORDERS.

First Aid:INHAL: REMOVE FROM EXPOS, RESTORE BREATHING, ADMINISTER
OXYGEN IF NEEDED. SEEK MED HELP IMMED. EYE: FLUSH W/LG AMTS OF
WATER FOR @ LST 15 MIN W/LIDS OPEN. SEE A PHYS IMMED. SKIN: WASH
W/SOAP & WATER. REMOVE CONTAMD CLTHG. INGEST: DO NOT INDUCE VOMIT.
DRINK 1-2 GLASSES OF WATER TO DILUTE. SEEK MED HELP IMMED. KEEP
QUIET, WARM & COMFORTABLE.

Flash Point:>200F,>93C
Lower Limits:0.9%
Upper Limits:24.6%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
FIGHT AS VOLAT LIQ FIRE. USE WATER TO COOL EXPOSED CONTRS. AVOID
SPREADING FIRE W/COOLING WATER (SUPP DATA)
Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. VAPS MAY TRAVEL TO SOURCES OF IGNIT & CAUSE A FLASH.
ISOLATE FROM ALL SOURCES OF HEAT. EMPTY (SUPP DATA)

Spill Release Procedures:VENT AREA. REMOVE ALL SOURCES OF IGNIT.
CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. WEAR
PROTECTIVE EQUIPMENT DURING CLEANUP. CONTAIN LIQUID TO PREVENT
CONTAMINATION OF SOIL AND GROUND WA TER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CONTR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES OF IGNIT. CONTRS MUST
BE GROUNDED &/OR BONDED DURING LIQ TRANSFER.
Other Precautions:HANDLE WHERE VENT IS ADEQ & AWAY FROM SOURCES OF
IGNIT. AVOID PRLNGD BRTHG OF VAPS, SKIN/EYE CONT.

Respiratory Protection:USE NIOSH/MSHA APPROVED CHEMICAL MECHANICAL
FILTER RESPIRATOR.
Ventilation:RED, 200 CFM MININUM.
Protective Gloves:CHEMICALLY RESISTANT PLASTIC/RUBBER.
Eye Protection:ANSI APPROVED CHEM SFTY GOGG .
Other Protective Equipment:EYEWASH & SAFETY SHOWER IN WORK AREA RECOM.
USE PROT HAND CREAMS TO PREVENT DEFATTING OF SKIN.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLOTHING BEFORE HANDLING FOOD/SMOKING. DAILY SHOWERS RECOMMENDED.
Supplemental Safety and Health
FIRE FIGHT PROC: FOG NOZZ FOR WATER RECOM. EXPLO HAZ: CONTRS MAY
EXPLODE DUE TO RESIDUES. OBSERVE THIS MSDS. ALL METAL CONTRS MUST
BE GROUNDED &/OR BONDED DURING LIQ TRANSFER. EFTS OF OVEREXP:
MONOBUT YL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION
NO.90-118) .

HCC:N1
Boiling Pt:B.P. Text:>223F,>106C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1(H2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:VISCOUS COATING WITH A SLIGHT AMMONIA ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS AND BASES.
Stability Condition to Avoid:PROLONGED BREATHING OF VAPORS, SKIN/EYE
CONTACT. STORE AWAY FROM HEAT, ELEC EQUIP, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION; CARBON
DIOXIDE, CARBON MONOXIDE, OTHER OXIDES, SMOKE, FUMES, ETC.

Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS.

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particular situation.