Product ID:SODIUM PERMANGANATE MONOHYDRATE 97+%, 22585-1
MSDS Date:06/03/1992
FSC:6810
NIIN:00N044568
MSDS Number: BSCCG

ALDRICH CHEMICAL

MILWAUKEE, WI 53201
US

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 60928

ALDRICH CHEMICAL CO INC

355 MILWAUKEE, WI 53233 US

Telephone: 414-273-3850

Cage: 60928

HAZ WASTE. DESTROY EXCESS SULFIDE, NEUT & FLUSH SOLN

RTECS: 9999999ZZ

ADEQUATE COOLING IS PROVIDED.

RTECS: 9999999ZZ

PERMANGANIC ACID, SODIUM SALT; (SODIUM PERMANGANATE

CAS: 10101-50-5

RTECS: SD6650000

Fraction By Weight: 97%+

OSHA PEL N/K

ACGIH TLV: N/K

SOME MANGANESE COMPOUNDS. TARGET ORGAN(S)

RTECS: 9999999ZZ

PROVIDED PERSON IS CONSCIOUS. CALL A

RTECS: 9999999ZZ

MATERIAL PICKUP IS COMPLETE.

RTECS: 9999999ZZ

ABOUT 10% OF SODIUM BISULFITE SOLN

RTECS: 9999999ZZ

CHROMIUM, OR MOLYBDENUM ARE PRESENT ADJUST PH OF SOLN

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED,
INHALED/ABSORBED THRU SKIN. CAUSES BURNS. MATL IS EXTREMELY
DESTRUCTIVE TO TISSUE OF MUC MEMB & UPPER RESP TRACT, EYES & SKIN.
INHAL MAY BE FATAL AS A RSLT OF SPASM, INFLA MM & EDEMA OF LARYNX &
BRONCHI, CHEM PNEUM & PULM EDEMA. SYMPS OF EXPOS MAY INCL BURNING
SENSATION, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: COUGH, WHEEZ, LARYNGITIS, SHORT OF
BRTH, HDCH, NAUS & VOMIT. TO THE BEST OF MFR KNOWLEDGE, THE CHEM,
PHYS, & TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THORO INVESTIGATED.
CHRONIC: MEN EXPOSED T O MANGANESE DUSTS SHOWED & A DECR IN
FERTILITY. CHRONIC MANGANESE POISONING PRIMARILY INVOLVES CNS.
EARLY (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN.
ASSURE ADEQ FLUSHING OF EYES BY SEPARATING LIDS W/FINGERS. SKIN:
IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN WHILE REMOVING
CONTAMD CLTHG & SHOES. WASH CONTAMD CLTHG BEFORE REUSE. DISCARD
CONTAMD SHOES. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. INGEST; WASH OUT MOUTH
W/WATER (ING 3)

Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . STRONG OXIDIZER.
Unusual Fire/Explosion Hazard:CONT W/OTHER MATL MAY CAUSE FIRE. EMITS
TOX FUMES UNDER FIRE CNDTNS. MIXING SODIUM PERMANGANATE
W/ACETIC/ACETIC ANHYDRIDE MAY RSLT IN AN EXPLO UNLESS (ING 8)

Spill Release Procedures:EVAC AREA. SHUT OFF ALL SOURCES OF IGNIT. WEAR
NIOSH/MSHA APPRVDD SCBA, RUBB BOOTS & HEAVY RUBB GLOVES. COVER
W/DRY-LIME, SAND/SODA ASH. PLACE IN COVERED CONTRS USING
NON-SPARKING TOOLS & TRANSPORT OU TDOORS. VENT AREA & WASH SPILL
SITE AFTER (ING 4)
Neutralizing Agent:SEE WASTE DISPOSAL.

Handling and Storage Precautions:AVOID BRTHG DUST. DO NOT GET IN EYES,
ON SKIN/CLTHG. AVOID PRNGD/RPTD EXPOS. CORR. HARMFUL SOLID. KEEP
TIGHTLY CLSD. HYROSCOPIC.
Other Precautions:KEEP AWAY FROM COMBUST MATLS, HEAT, SPARKS, & OPEN
FLAME. STORE IN A COOL DRY PLACE.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND
EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: SYMPS INCL LANGUOR, SLEEPINESS & WEAK IN LEGS. A
STOLID MASK-LIKE APPEARANCE OF FACE, EMOTIONAL DISTURB SUCH AS
UNCONTROLLABLE LAUGHTER & A SPASTIC GAIT, W/TENDENCY TO FALL IN
WALKING ARE FINDINGS IN MORE ADVANCED GASES. HIGH INCIDENCE OF
PNEUM HAS BEEN FOUND IN WORKERS EXPOSED TO DUST/FUME OF (ING 2)

HCC:D4
Appearance and Odor:BLACK CRYSTALLINE POWDER

Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS. FINELY POWDERED METALS. STRONG ACIDS. ORGANIC
MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT
KNOWN.

Waste Disposal Methods:CAUTIOUSLY ACIDIFY A 3% SOLN/A SUSPENSION OF
MATL TO PH 2 W/SULFURIC ACID. GRADUALLY ADD A 50% EXCESS OF AQUEOUS
SODIUM BISULFITE W/STIRRING @ ROOM TEMP. AN INCR IN TEMP INDICATES
THAT A RXN IS TAKING PLACE. IF NO RXN IS OBSERVED ON ADDN OF (ING
5)

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