Product ID:LA 4220 ACCELERATOR
MSDS Date:04/14/1994
FSC:4920
NIIN:01-292-5965
Kit Part:Y
MSDS Number: BSDBJ

CLIFTON ADHESIVE INC

BURGESS PL
WAYNE, NJ 07474-0282
US

Emergency Phone: 201-694-0845

Info Phone: 201-694-0845

Cage: 79833

CLIFTON ADHESIVE INC

WAYNE, NJ 07470 US

Telephone: 201-694-0845; 973-694-0845

Cage: 79833

DIPHENYLMETHANE DIISOCYANATE (MDI)

CAS: 26447-40-5

Fraction By Weight: 40-50%

HIGHER OLIGOMERS OF MDI (POLYMETHYLENE POLYPHENYLENE

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 50-60%

LD50 LC50 Mixture:LC50 (RAT)=0.369 MG/L
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT MAY CAUSE SKIN AND EYE
IRRITATION. INHALATION MAY CAUSE RESPIRATORY TARCT IRRITATION.
INGESTION MAY CAUSE GI TRACT IRRITATION AND CORROSION OF MOUTH,
THRAOT AND STOMACH. CHRONIC: PROLON GED OR REPEATED EXPOSURE MAY
CAUSE RESPIRATORY AND/OR SKIN SENSITIZATION
Explanation of Carcinogenicity:MANUFACTURE STATES "CARCINOGENIC:
POSSIBLE"; HMIS TECHNICIAN FOUND NO EVIDENCE OF THIS IN RTECS AND
OTHER LITERATURE.
Effects of Overexposure:INHALED: COUGHING, TIGHTNESS OF CHEST,
SHORTNESS OF BREATH, WHEEZING, RUNNY OR STUFFY NOSE, DRY OR SORE
THROAT. EYES: WATERING AND DISCOMFORT. SKIN: REDNESS, DISCOMFORT.
INGESTION: NAUSEA, VOMITING, D IARRHEA, BURNING SENSATION IN MOUTH,
THROAT, STOMACH PAIN.
Medical Cond Aggravated by Exposure:RESPIRATAORY AILMENTS AND
DERMATITIS MAY BE AGGRAVATED.

First Aid:IN EMERGENCY SITUATIONS, NOTIFY PHYSICIAN IMMEDIATELY. SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION. EYES: FLUSH WITH
LOTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. INHALED:
REMOVE TO F RESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT; GIVE
ARTIFICIAL RESPIRATION IF BREATHING STOPPED. INGESTED: DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:>400F,>204C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, HALON 1211. IF
WATER USED, USE IN VERY LARGE AMOUNTS. WATER REACTS WITH PRODUCT.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL-PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DOWN WIND PERSONNEL MUST BE EVACUATED. DO
NOT RESEAL CONTAMINATED CONTAINERS AS PRESSURE BUILD-UP MAY RUPTURE
THEM.

Spill Release Procedures:EVACUATE AND VENTILATER SPILL AREA. WEAR
PROPER PROTECTIVE GEAR. DIKE SPILL TO PREVENT ENTRY INTO WATERWAYS.
ABSORB WITH INERT MATERIAL. SHOVEL ABSORBED MATERIAL INTO STEEL
CONTAINER FOR LATER DISPOSA L.
Neutralizing Agent:WATER/AMMONIA SOLUTION WITH 1-2% DETERGENT

Handling and Storage Precautions:STORE IN AN APPROVED SOVENT STORAGE
AREA. KEEP TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION AND
INCOMPATIBLE MATERIALS.
Other Precautions:USE AND STORE WITH ADEQUATE VENTILATION. PROTECT FROM
FREEZING. STORE BETWEEN 50-90F.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR EMERGENCY
OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE OR SUPPLIED AIR RESPIRATOR OR SCBA, AS REQUIRED. USE IAW
29 CFR 1910.134.
Ventilation:USE ADEQUATE MECHANICAL EXPLOSION-PROOF VENTILATION OR
LOCAL EXHAUST.
Protective Gloves:PVA
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO PREVENT
SKIN CONTACT. HMIS: EYE WASH STATION.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
P/N M11628 CEMENT ACCELERATOR USED IN REPAIR KIT #B4192-9. KEY1=T6.
MATERIAL IS PART B OF A 2 PART KIT. SEE PART A THIS NSN/CAGE FOR
OTHER PART IN KIT.

HCC:F2
Boiling Pt:B.P. Text:392F,200C
Vapor Pres:<<1 MM HG
Vapor Density:0.6(AIR=1)
Spec Gravity:1.2 (WATER=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:BROWN LIQUID
Corrosion Rate:UNKNOWNN

Stability Indicator/Materials to Avoid:YES
WATER, STRONG MINERAL ACIDS, STRONG ALKALIS, ALCOHOLS, METAL COMPOUNDS,
SURFACE ACTIVE MATERIALS.
Stability Condition to Avoid:AVOID HEAT, CARBON DIOXIDE, OPEN FLAMES,
SPRAKS, HOT SURFACES.
Hazardous Decomposition Products:ISOCYANATE VAPOR AND MIST, CARBON
DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES, TRACES OF HYDROGEN
CYANIDE.
Conditions to Avoid Polymerization:MAY OCCUR WITH INCOMPATIBLE
REACTANTS, ESPECIALLY STRONG ALKALIS, WATER OR TEMPERATURES ABOVE
347F.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DISPOSE OF ANY MATERIALS (MOPS, BROOMS)
PROPERLY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.