Product ID:HYDRAZINE HYDRATE 11%
MSDS Date:06/01/1993
FSC:6810
NIIN:01-344-9158
MSDS Number: BSDBZ

POLY RESEARCH CORP

125 CORPORATE DR
HOLTSVILLE, NY 11742
US

Emergency Phone: 800-424-9300(CHEMTREC)

Cage: 64713

POLY RESEARCH CORPORATION

HOLTSVILLE, NY 11742-2007 US

Telephone: 516-758-0460

Cage: 64713

HYDRAZINE; (HYDRAZINE HYDRATE) (SARA III)

CAS: 302-01-2

RTECS: MU7175000

Fraction By Weight: 11%

OSHA PEL 0.1 PPM, S

ACGIH TLV: 0.1 PPM, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:LD50 (ORAL, RAT): 129 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGESTION:POISON. DAMAGES LIVER &
DESTROYS RED BLOOD CELLS. INHALATION:CORROSIVE. CAUSES BURNS TO
MUCOUS MEMBRANES. SKIN:CORROSIVE. CAUSES SKIN BURNS, MAY CAUSE SKIN
SENSITIZATION & SYSTEMIC POISONING . EYES:CORROSIVE, CAUSES EYE
BURNS, MAYCAUSE BLINDNESS. CHRONIC:ALLERGIC SENSITIZER. CARCINOGEN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:HYDRAZINE:IARC MONOGRAPHS, SUPPLEMENT,
VOL 7, PG 223, 1987:GROUP 2B. NTP 6TH ANNUAL REPORT ON CARCINOGENS,
(SUPDAT)
Effects of Overexposure:HLTH HAZ:AFFECTING LUNGS, NERVOUS SYSTEM,
LIVER, KIDNEYS & SUBCUTANEOUS TISSUE.
Medical Cond Aggravated by Exposure:POSS DMG TO LIVER, BLOOD & EYE
IRRITANT. AS W/ANY ORGANIC COMPOUND THAT IS HEATED TO VAPORIZATION,
EXPOS MAY AGGRAVATE PRE-EXISTING CONDITIONS SUCH AS COLDS,
ALLERGIES, ASTHMA, EMPHYSEMA & PSORIASIS.

First Aid:EYES:FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MIN. SEEK MED
ATTN. SKIN:WASH W/SOAP & WATER. REMOVE & LAUNDER CONTAMD CLTHG. GET
MED ATTN. INHAL:REMOVE TO FRESH AIR. GET MED ATTN. INGEST:INDUCE
VOMIT. FO R LG AMTS INGESTED INDUCE VOMIT W/IPECAC. DO NOT INDUCE
VOMIT IF COMATOSE. GET EMER MED ATTN. NOTE TO MD:HYDRAZINE IS
POISON & CARCIN AFFECTING LUNGS, NERVOUS SYS, LIVER, KIDNEYS &
SUBCUTANEOUS TISS.

Flash Point:193F,89C
Lower Limits:4.7%
Upper Limits:100%
Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
VAP CAN BE IGNITED BY SPK/FLAME. DILUGE UNIGNITED SPILLS W/LG
AMOUNTS WATER DILUTING CONC < 40% BY WT.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID.

Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA. FOLLOW OSHA
REGULATIONS FOR RESPIRATION USE (CFR 1910.134). WEAR GOGGLES,
COVERALLS & PVC/BUTYL RUBBER GLOVES & BOOTS. WASH ALL CONTAMINATED
CLOTHING BEFORE REUSE. DESTR OY ANY CONTAMINATED LEATHER ARTICLES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES/ON SKIN/ON CLTHG.
DO NOT TAKE INTERNALLY. AVOID BRTHG MIST/VAP. DESTROY ANY CONTAMD
LEATHER ARTICLES.
Other Precautions:MAINTAIN ATMOSPHERE OF NITROGEN OVER HYDRAZINE.
CONTAINERS MUST BE GROUNDED. ADEQUATE WATER SUPPLY MUST BE
AVAILABLE FOR FLUSHING. CONTACT LENSES SHOULD NOT BE WORN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . AS REQUIRED TO KEEP AIRBORNE CONCENTRATION
BELOW TLV OF HYDRAZINE.
Ventilation:FRESH AIR; AVOID DIRECT FUMES.
Protective Gloves:PVC OR BUTYL RUBBER GLOVES.
Eye Protection:ANSI APPR CHEM WORK GOG W/FULL FCSHLD.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER . PVC OR
BUTYL RUBBER APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EVAP RATE:SAME AS WATER (BUTYL ACETATE =1). EXPLAN OF CARCIN:
1991:ANTICIPATED TO BE A CARCINOGEN.

HCC:T4
Boiling Pt:B.P. Text:230F,110C
Vapor Pres:SAME/H*2O
Vapor Density:SAME/H*2O
Spec Gravity:1.01
Evaporation Rate & Reference:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS; AMMONIA ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG BASES, ACIDS, & OXIDIZING MATLS; BARIUM OXIDE, CALCIUM OXIDE,
CHROMATE SALTS, ALKALI METALS & METAL SALTS
Stability Condition to Avoid:WILL REACT WITH OXYGEN.
Hazardous Decomposition Products:AMMONIA

Waste Disposal Methods:DISP MUST BE IN ACCORDANCE WITH FED, STATE &
LOCAL REGS . FLUSH W/LARGE AMTS OF WATER & DRAIN INTO CATCH BASIN.
TRANSFER INTO APPRVD DOT CNTNR & SEAL. NEUT ANY REMAINING MATL
W/DILUTE HYPOCHLORI TE SOLN & WASH DOWN WITH WATER.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.