Product ID:ARKLONE P
MSDS Date:09/24/1989
FSC:6850
NIIN:00-319-0834
MSDS Number: BSDFH

Emergency Phone: 302-575-3000

Info Phone: 302-275-3000

Cage: 13992

Telephone: 302-886-3000

Cage: 13992

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 99.9%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 42,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INGESTION-A SINGLE DOES OF THIS
PRODUCT IS PRACTICALLY NONTOXIC BY INGESTION. EYE-THIS MATERIAL IS
SLIGHTLY IRRITATING TO HUMAN EYES. SKIN-IRRITATION CAN DEVELOP
FOLLOWING PROLONGED CONTACT WITH HUMAN SKIN. INHALATION-MISTS OR
VAPOR CAN INDUCE IRRITATION OF MUCOUS MEMBRANES OF THE THROAT, NOSE
& RESPIRATORY PASSAGE.
Explanation of Carcinogenicity:NO DATA AVAILABLE.
Effects of Overexposure:EXPOSURE TO HIGH CONCENTRATIONS OF 1,1,2-
TRICHLORO-1,2,2-TRIFLUOROETHANE INDUCES TOXICITY WHICH PROGRESSES
FROM IRRITATION OF MUCOUS MEMBRANES & SKIN, DEPRESSION, WEAKNESS,
VERTIGO, DISORIENTATION, U NCOORDINATION, HEADACHE, DROWSINESS,
NAUSEA, VOMITING AND LOSS OF SENSATION TO UNCONSCIOUSNESS & ANORIC
DEATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN-REMOVE CONTAMINATED CLOTHING. WASH MATERIAL OFF THE SKIN
WITH PLENTY OF SOAP & WATER. IF REDNESS OCCURS, GET MEDICAL
ATTENTION. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN.
IF REDNESS OCCURS, HAVE EYES EXAMINED & TREATED BYPHYSICIAN.
INGESTION- GIVE 1 OR 2 GLASSES OF WATER TO DRINK. CONSULT
PHYSICIAN. INHALATION-REMOVE VICTIM TO FRESH AIR. CONSULT MEDICAL
PERSONNEL. PERFORM CPR.

Flash Point:DOES NOT FLASH
Extinguishing Media:NOT APPLICABLE. USE MEDIA SUITABLE FOR SURROUNDING
FIRES.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE AND PROTECTIVE CLOTHING IF INVOLVED IN A FIRE OF OTHER
MATERIALS.
Unusual Fire/Explosion Hazard:HEAVY VAPORS CAN SUFFOCATE. HIGHLY TOXIC
DECOMPOSITION PRODUCTS.

Spill Release Procedures:RECOVER ANY LIQUID AND VENTILATE SPILL AREA.
USE SELF-CONTAINED BREATHING APPARATUS TO AVOID SUFFOCATION.
[HMIS-REMOVE UNPROTECTED PERSONNEL. HMIS]

Handling and Storage Precautions:STORE IN A COOL AREA WITH GOOD
VENTILATION. ENFORCE NO SMOKING RULES IN AREAS OF USE. OBSERVE TLV
LIMITATIONS. [HMIS-AVOID BREATHING VAPORS. HMIS]
Other Precautions:DISPOSAL: DISPOSE OF WASTES OF THESE SPENT MATERIALS
IN A FACILITY PERMITTED FOR HAZARDOUS WASTE. STORAGE: THIS MATERIAL
OR ITS VAPORS IN CONTRACT WITH OPEN FLAMES, HEAT ABOVE 1300F MAY
FORM VARIOUS, TOXIC/CORROSIVE DECOMPOSITION PRODUCTS.

Respiratory Protection:NOT NORMALLY NEEDED IF CONTROLS ARE ADEQUATE. IF
NEEDED, USE MSHA-NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS. IN
HIGH CONCENTRATIONS OR IN OXYGEN-DEFICIENT ATMOSPHERES, USE
MSHA-NIOSH APPROVED SELF- CONTAINED BREATHING APPARATUS.
Ventilation:VENTILATE LOW--LYING AREAS SUCH AS SUMPS OR PITS WHERE
DENSE VAPORS MAY COLLECT. PROVIDE LOCAL EXHAUST IF TLV IS EXCEED.
Protective Gloves:IMPERVIOUS GLOVES AND APRONS.
Eye Protection:CHEMICAL TIGHT GOGGLES; FULL FACE SHILD.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER IN WORK
AREA.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN.DO NOT BREATHE
VAPORS/MIST.DO NOT EAT,DRINK OR SMOKE IN WORK AREA.
Supplemental Safety and Health
CONTAINER DISPOSAL: EMPTY CONTAINERS RETAIN HAZARDOUS PRODUCTS RESIDUE.
OBSERVE ALL HAZARD PRECAUTIONS. DO NOT DISTRIBUTE, MAKE AVAILABLE,
FURNISH OR REUSE EMPTY CONTAINER EXCEPT FOR STORAGE & SHIPMEN T OF
ORIGINAL PRODUCT. [HMIS-FREON 113 MAY DILUTE OR DISPLACE OXYGEN
BELOW LEVELS NECESSARY TO SUSTAIN LIFE. HMIS]

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Vapor Pres:270 MMHG
Vapor Density:6.75
Spec Gravity:1.6
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID WITH FAINT ETHER LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
SODIUM, POTASSISUM, & BARIUM METALS; FINELY DIVIDED ALUMINUM, ZINC &
MAGNESIUM, ESPECIALLY AT HIGH TEMPERATURES.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS.
Hazardous Decomposition Products:HALOGEN, HALOGEN ACIDS, POSSIBLE TRACE
AMOUNT OF CARBONYL HALIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCARDED PRODUCT IS NOT A HAZARDOUS WASTE UNDER
RCRA CFR 261. HOWEVER, SPENT 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
& STILL BOTTOMS FROM RECOVERY OF THIS SOLVENT ARE HAZARDOUS WASTES,
NO 1002, UNDER R CRA, 40 CFR 261.31.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.