Product ID:SHAW'S DURSBAN 50 GRANULES
MSDS Date:06/01/1991
FSC:6840
NIIN:00D003480
MSDS Number: BXBYP

KNOX FERTILIZER COMPANY,INC.

WEST CULVER RD.
KNOX, IN 46534
US

Emergency Phone: 219-772-6275

Info Phone: 219-772-6275

Cage: KNOXF

YORK DISTRIBUTORS

248 KNOX, IN 46534 US

Telephone: 219-772-6275

Cage: 0TS38

CHLORPYRIFOS (CERCLA)

CAS: 2921-88-2

RTECS: TF6300000

Fraction By Weight: 0-5%

OSHA PEL S, 0.2 MG/M3

ACGIH TLV: S, 0.2 MG/M3; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CORN COB (PULVERIZED)

Fraction By Weight: 0-100%

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 100-250MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:**MODERATELY TOXIC - CHOLINESTERASE
INHIBITOR** EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.MAY
BE DERMALLY ABSORBED IN HARMFUL AMOUNTS.INGEST:MAY CAUSE GI TRACT
IRRITATION.INHAL:PRODUCT AT HI GHER TEMPERATURES MAY CAUSE
RESPIRATORYIRRITATION(LC50 INHAL RAT >200MG/KG).
Explanation of Carcinogenicity:DURSBAN HAS BEEN STUDIED BY RTECS FOR
MUTAGENICITY AND REPRODUCTIVE TOXICITY.
Effects of
Overexposure:INGEST:DIARRHEA,TREMORS.OVEREXPOSURE:HEADACHE,DIZZINES
S,INCOORDINATION,MUSCLE TWITCHING,TREMORS,NAUSEA,ABDOMINAL
CRAMPS,DIARRHEA,SWEATING,PIN-POINT PUPILS,BLURRED
VISION,SALIVATION,TEARING,CHEST TIGHT NESS,EXCESSIVE
URINATION,CONVULSIONS.
Medical Cond Aggravated by Exposure:NOT REPORTED.

First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND
WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION IF
SYMPTOMS PERSIST.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR
ARTIFICIAL RESPIRATIO N IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET
PROMPT QUALIFIED MEDICAL ATTENTION.IF SPONTANEOUS VOMITING
OCCURS,KEEP HEAD BELOW HIPS,MAINTAIN CLEAR AIRWAY.

Flash Point Method:OC
Flash Point:350F,177C
Extinguishing Media:WATER,DRY CHEMICAL,CARBON DIOXIDE,FOAM.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES.

Spill Release Procedures:CONTAIN;PLACE COLLECTED MATERIAL IN AN
APPROPRIATE CONTAINER FOR DISPOSAL;AVOID CONTAMINATION OF FOOD OR
FEED;AVOID RUNOFF INTO WATER WAYS.REPORT SPILLS TO NRC AT
800-424-8802.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:KEEP DRY.STORE AT TEMPERATURES BELOW
120F.FOLLOW LABEL DIRECTIONS.
Other Precautions:EMPTY BAG MAY CONTAIN HAZARDOUS RESIDUE;DISPOSE OF
PROPERLY.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE.
Ventilation:USE LOCAL EXHAUST.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
ORAL LD50 (RAT) IS 82MG/KG FOR DURSBAN(TECH) PER RTECS 93-3.HMIS WAS
UNABLE TO FIND THE EPA REG NUMBER ON THE MFR'S MSDS.

HCC:T4
Boiling Pt:B.P. Text:107F,42C
Melt/Freeze Pt:M.P/F.P Text:212F,100C
Decomp Temp:Decomp Text:212F,100C
pH:6-8
Solubility in Water:APPRECIABLE
Appearance and Odor:GRANULES;TAN;MILD AROMATIC ODOR.

Stability Indicator/Materials to Avoid:YES
WATER(CAUSES PRODUCT TO DECOMPOSE AND GIVE OFF AMMONIA).
Stability Condition to Avoid:TEMPERATURES ABOVE 120F,SUNLIGHT.
Hazardous Decomposition Products:HCL(GAS),DIETHYL SULFIDE,NITROGEN
OXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.