Product ID:48800 4-BROMOFLUOROBENZENE, 1X1ML, MEOH, 25000UG/ML
MSDS Date:01/17/1996
FSC:6810
NIIN:01-353-5115
MSDS Number: BXCCT

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

1-BROMO-4-FLUOROBENZENE

CAS: 460-00-4

Fraction By Weight: 2.5%

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 97.5%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 95

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 ORAL RAT = 5628MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. HEADACHE. NAUSEA, GASTROINTESTINAL DISTURBANCES.
BLINDNESS.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:HEADACHE, NAUSEA, GASTROINTESTINGAL
DISTURBANCES, BLINDNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN-FLUSH
WITH LOTS OF WATER. INHALED-REMOVE TO FRESH AIR. IF BREATHING
STOPS, GIVE ARTIFICIAL RESPIRATION. CONTACT A PHYSICIAN.
INGESTED-IF CONSCIOU S, GIVE 2 TABLESPOONS BAKING SODA IN A GLASS
OF WATER; STICK FINGERS DOWN THROAT & INDUCE VOMITING. IMMEDIATELY
SEE DOCTOR.

Flash Point:50.0F,10.0C
Lower Limits:6.0
Upper Limits:36.0
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION.KEEP AWAY FROM OXIDIZERS.KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:DLA-HMIS: EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health

HCC:F2
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL REGULATIONS. SUBJECT TO REPORTING REQUIREMENTS OF SARA
TITLE III SEC 313.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.