Product ID:PEN
MSDS Date:04/01/1994
FSC:9135
NIIN:00N010466
MSDS Number: BXDSD

STATE CHEMICAL MFG CO

31 HAMILTON AVE
CLEVELAND, OH 44114-3701
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

ETHYLENE, TETRACHLORO-; (PERCHLOROETHYLENE) (SARA 313)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: <75%

OSHA PEL 100 PPM

ACGIH TLV: 25 PPM; 100 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PROPANOL, (1,1-DIMETHYLETHOXY)-; (PROPYLENE GLYCOL T-BUTYL

CAS: 57018-52-7

RTECS: UB3772000

Fraction By Weight: <10%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: <10%

OSHA PEL 5000 PPM

ACGIH TLV: 5000 PPM; 30000 STEL

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY

CAS: 64741-88-4

RTECS: PY8040501

Fraction By Weight: <10%

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE),

CAS: 64742-52-5

RTECS: PY8035001

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

COMPUTERS OR ELECTRONIC MEMORY SYS. BE CAREFUL

RTECS: 9999999ZZ

AREA BEFORE USING. WIPE OFF OVERSPRAY IMMED. READ &

RTECS: 9999999ZZ

USING PROD. THESE PRODS ARE INTENDED FOR INDUS &

RTECS: 9999999ZZ

KEEP OUT OF THE REACH OF CHILDREN.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . HARMFUL/FATAL IF
SWALLOWED. PRLNGD (EFTS OF OVEREXP)
Explanation of Carcinogenicity:TETRACHLOROETHYLENE: IARC MONO, SUPP,
VOL 7, PG 355, 1987:GRP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:
(SUPDAT)
Effects of Overexposure:HLTH HAZ: BRTHG OF VAPS MAY RESULT IN HDCH,
DIZZ, DROW OR NAUS. MAY CAUSE EYE/SKIN IRRIT. PRLNGD SKIN CNTCT MAY
RSLT IN DRYING/CRACKING. CHRONIC: LONG TERM EXPOS TO VAPS MAY CAUSE
LUNG, LIVER OR KIDNE Y DMG. PERCHLOROETHYLENE IS A CARCINOGEN & MAY
CAUSE SPLEEN & BRAIN DMG.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: CONTAINS SOLVENTS. DO NOT INDUCE VOMITING. SEEK
MEDICAL ATTENTION IMMEDIATELY. INHAL: REMOVE TO FRESH AIR. ADMIN
OXYGEN IF NECESSARY. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS.
EYES: FLUSH IMMEDIATELY W/PLENTY OF COOL WATER FORAT LEAST 15
MINUTES. IF IRRITATION PERSISTS, CONTACT MD. SKIN: WASH W/SOAP &
WATER. IF IRRITATION PERSISTS, CONTACT MD.

Flash Point Method:TCC
Flash Point:>300F,>149C
Extinguishing Media:WATER FOG, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . KEEP CNTNRS COOL. USE EQUIP/SHIELDING TO PROT
PERS AGAINST VENTING/RUPTURING/BURSTING CNTNRS.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . AT TEMPERATURES ABOVE 120F CONTAINERS
MAY VENT, RUPTURE OR BURST.

Spill Release Procedures:REMOVE SOURCES OF FLAME, SPARKS OR HEAT.
VENTILATE AREA. WIPE UP EXCESS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE IN DIRECT SUN/IN TEMPS
>120F. AVOID BRTHG VAPS FROM PROD. HARMFUL/FATAL IF SWALLOWED. DO
NOT TAKE INTERNALLY. IF SWALLOWED DO NOT(SUPDAT)
Other Precautions:NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING/OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . PROD CNTNS SOLVS WHICH MAY AFFECT
PLASTICS & PAINT S. NOT FOR USE ON ELECTRONIC (ING 6)

Respiratory Protection:USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS WHEN USING PROD IN ANY AREA W/OUT VENT. IN AREAS W/VAPOR
ABOVE TLV BUT STILL PLENTY OF OXYGEN, USE NIOSH/MSHA APPRVD
CARTRIDGE TYPE RESP FITT ED WITH ORGANIC VAPOR CARTRIDGES.
Ventilation:USE VENTILATION TO KEEP VAPOR CONCENTRATION BELOW TLV.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:SOURCE OF CLEAN WATER NEARBY IN CASE OF
ACCIDENTAL EYE SPLASHING. WEAR LONG PANTS & LONG SLEEVES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: ANTIC TO BE CARCIN. ANIMAL:LIVER TUMORS. HNDLG/STOR
PREC:INDUCE VOMIT. CALL MD. VAP MAY BE HARMFUL. CONTENTS UNDER
PRESS. DO NOT PUNCTURE/INCIN. DO NOT USE IN POORLY VENT/CONFINED SP
ACES. VAPS ARE HVR/AIR & WILL COLLECT IN LOW AREAS SUCH AS PITS,
DEGREASERS, STOR TANKS/OTHER CONFINED AREAS.

Boiling Pt:B.P. Text:>250F,>121C
Vapor Density:4.0
Spec Gravity:1.3 (H*2O=1)
Solubility in Water:NIL
Appearance and Odor:AMBER PRESSURIZED SPRAY WITH STRAWBERRY SCENT.
Percent Volatiles by Volume:>80 WT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACTIVE METALS, ACIDS, DEHYDRATING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING THIS PRODUCT MAY RESULT IN THE
FORMATION OF CARBON DIOXIDE, PHOSGENE, WATER AND HYDROGEN CHLORIDE.

Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE CONTAINERS. GIVE
TO DISP SERVICE EQUIPPED TO SAFELY HANDLE & DISPOSE OF PRESSURIZED
CONTAINERS. USED LIQUID IS RCRA HAZ WASTE (NO F001). FOLLOW ALL
FEDERAL, STATE & LOCAL REGULATIONS REGARDING WASTE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.