Product ID:PR-420, PART A
MSDS Date:06/03/1993
FSC:8030
NIIN:01-025-6411
Kit Part:Y
MSDS Number: BXJVW

PROD RESEARCH&CHEM)

5430 SAN FERNANDO ROAD
GLENDALE, CA 91209
US

Emergency Phone: 818-549-7586/800-424-9300(CHEMTREC)

Info Phone: 818-240-2060

Preparer: R.WOODHOUSE

Cage: 83574

PRC-DESOTO INTERNATIONAL, INC. A PPG INDUSTRIES COMPANY

1800 GLENDALE, CA 91209 US

Telephone: 818-240-2060

Cage: 83574

CHLOROBENZENE (SARA 313) (CERCLA)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 50%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA 313)

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 50%

OSHA PEL C 0.02 PPM

ACGIH TLV: 0.005 PPM; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:IRRIT, WATERING, POSSIBLE
REVERSIBLE CORNEAL DAMAGE. SKIN:LOCAL SWELLING, SORENESS, ITCHING.
IN SENSITIZED INDIVIDUALS WILL CAUSE AN ALLERGIC SKIN RASH.
INHAL:DUE TO LOW VOLATILITY SIGNIFICANT EXP O TO ISOCYANATE VAP NOT
EXPECTED UNLESSOVERHEATED. EXCESSIVE INHAL CAN PRODUCE
NOSE/THROAT/RESP TRAC IRRIT. (SUPPLEMEN)
Explanation of Carcinogenicity:PER MSDS:NOTHING CONTAINED IN THIS
PRODUCT IS FOUND IN OSHA/NTP/IARAC FOR CARCINOGEN.
Effects of Overexposure:EYE:WATERING,REVERSIBLE CORNEAL DAMAGE, IRRIT.
SKIN:SWELLING,SORENESS,ITCHING,ALLERGIC SKIN RASH. INHAL:IRRIT OF
NOSE/THROAT/RESP TRACT, BRONCHITIS,ASTHMA-LIKE SYMPTOMS.
INGEST:IRRIT, CORROSIVE ACTION IN MOUTH/STOMACH TISSUE/DIGESTIVE
TRACT,KIDNEY & LIVER DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/LUKE WARM WATER FOR 15MINS. CONSULT PHYSICIAN.
SKIN:WASH W/SOAP/WATER. IRRIT PERSISTS CONSULT PHYSICIAN.
INHAL:REMOVE TO FRESH AIR. IF SYMPTOMS ARE PRESENT CONSULT
PHYSICIAN. INGEST:DO NOT INDUCE VOMITING. GIVE MILK OR WATER
TODRINK. CONSULT PHYSICIAN.

Flash Point Method:PMCC
Flash Point:90.0F,32.2C
Lower Limits:1.8
Upper Limits:9.6
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL
HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE
BUILDUP IN CLOSED CONTIANERS.

Spill Release Procedures:REMOVE ALL IGN SOURCE.WEAR AIR-SUPPLIED RESP
FOR MAJ UNVENTI SPILL.COVER W/ABSORBENT MATL.ADD DECONTAMIN
SOLN(5%CONCEN AMMONIA,2%DETERGENT,93%WATER).ALLOW TO REACT FOR
10MINS.COLLECT IN CNTNR.ADD ADDN DECONTAMIN SOLN.KEEP LOOSELY
COVER 48HRS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID MOISTURE CONTAMIN WHICH WILL
CAUSE CO2 PRESSURE.DO NOT RESEAL CNTNR IF MOISTURE CONTAMIN IS
SUSPECTED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WHEN SPRAYING, APPLYING IN CONFINED AREAS OR IN
OTHER CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVELS OF SOLVENT OR
ISOCYANATE IN EXCESS OF TLB USE AN AIR-SUPPLIED RESPIRATOR.
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPOR BELOW TLV.
Protective Gloves:SOLVENT-RESISTANT GLOVES.
Eye Protection:CHEMCIAL GOGGLES OR FULL FACE SHIELD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
BOILING PT/VAP PRESSURE & DENSITY/EVAPORATION RATE/FLAMM LIMITS ARE FOR
CHLOROBENZENE. HEALTH HAZ:SENSITIZED INDIVIDUALS WILL DEVELOP
ASTHMA-LIKE SYMP @LOW EXPO.INGEST:IRRIT,SOME CORR ACTION IN MOUTH/
STOMACH TISSUE/GI TRACT,KIDNEY/LIVER DAMAGE. PART A OF 2-PART
KIT,SEE SAME NSN PNIND:B. KEY1:F5

HCC:F5
Boiling Pt:B.P. Text:270F(SUPPL)
Vapor Pres:10 @72F
Vapor Density:3.88
Spec Gravity:1.16
Viscosity:5-7 POISE
Evaporation Rate & Reference:6.15 REF UNK
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, SGTRONG BASES, AMINES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. HOWEVER
HIGH TEMPERATURES & MOISTURE.
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN; POSSIBLE
TRACES OF HCN.

Waste Disposal Methods:RQ=200LBS FOR MONOCHLOROBENZENE. EPA WASTE
NO:D-001 & D-021. DISPOSE IN COMPLIANCE WITH FEDERAL & STATE
REGULATIONS. PROD CONTAINS TOXIC CHEM(S) SUBJECT TO REPORTING RQMTS
OF SEC 313 TITLE III OF SARA & 40CFR372.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.