Product ID:MISTABOND H3164
MSDS Date:08/25/1993
FSC:8040
NIIN:00N091508
Status Code:A
MSDS Number: CJLKQ

Emergency Phone: (800)424-9300

Info Phone: 314-872-8700

Cage: MARCH

Telephone: 314-872-8700

Cage: MARCH

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE

CAS: 101-68-8

RTECS: NQ9350000

OSHA PEL C0.2 MG/M3;C0.02 PPM

ACGIH TLV: 0.051 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF MUCOUS
MEMBRANES, RUNNING NOSE, SORE THROAT, COUGH, A REDUCTION IN LUNG
FUNCTION, BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA. SKIN:
REDDENING, SWELLING, BLISTERING, DERM ATITIS. EYES: IRRITATING; CAN
CAUSE LACRYMATION; CORNEAL DAMAGE CAN OCCUR.
Effects of Overexposure:INHALATION: MAY CAUSE BREATHLESSNESS,
IRRITATION AND REDUCED PULMONARY FUNCTION. REACTION MAY BE DELAYED
4-8 HOURS. SENSITIVITY MAY DEVELOP LEADING TO ASTHMA-LIKE SYMPTOMS.
Medical Cond Aggravated by Exposure:ASTHMATIC-TYPE CONDITIONS. CHRONIC
BRONCHITIS, CHRONIC RESPIRATORY DISEASES.

First Aid:SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD .
INHALATION: REMOVE TO FRESH AIR. IF BREATHING DIFFICULT ADMINISTER
OXYGEN. IF STOPPED, APPLY ARTIFICIAL RESPIRATION. EYES: FLUSH WITH
WATER F OR AT LEAST 15 MINUTES. CONSULT DOCTOR. INGESTION: DO NOT
INDUCE VOMITING. GIVE 250 ML MILK OR WATER TO DRINK.

Flash Point Method:CC
Flash Point:>148.9C, 300.F
Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:AVOID WATER CONTAMINATION IN CLOSED
CONTAINERS ON CONFINED SPACES (CO*2 EVOLVED).

Spill Release Procedures:PROPERLY PROTECTED PERSONNEL SHOULD CONTAIN
AND COVER SPILL WITH ABSORBENT MATERIAL. PLACE IN OPEN CONTAINER.
REMOVE TO WELL VENTILATED AREA AND DILUTE WITH AMMONIA SOLUTION
(WATER 90%, NH*4OH 8%, DET ERGENT 25%). LEAVE VENTILATED 24 HOURS.

Handling and Storage Precautions:AVOID MOISTURE CONTAMINATION. STORE
UNDER 40F DEW POINT.
Other Precautions:AVOID RAPID OR EXCESSIVE HEAT. DO NOT EXCEED 225 PSIG
IF PACKAGED IN PRESSURIZED CYLINDERS.

Respiratory Protection:NIOSH APPROVED PRESSURE DEMAND SUPPLIED AIR
BREATHING APPARATUS IF PEL OR TLV EXCEEDED.
Ventilation:LOCAL EXHAUST: PREFFERED. MECHANICAL (GENERAL): TO MAINTAIN
BELOW TLV. SPECIAL: N/A. OTHER: N/A.
Protective Gloves:RUBBER OR PLASTIC GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:IF CONTAINER IS EXPOSED TO HIGH HEAT, IT CAN BE
PRESSURIZED & POSSIBLY RUPTURE. MDI REACTS SLOWLY W/WATER TO FORM
CARBON DIOXIDE GAS. THIS GAS CAN CAUSE SEALED CONTAINER TO EXPAND &
POSSIBLY RUPTURE.
Supplemental Safety and Health

Vapor Density:>1(AIR=1)
Spec Gravity:1.1 (H*2O=1)
Solubility in Water:REACTS
Appearance and Odor:BROWN LIQUID.

Stability Indicator/Materials to Avoid:YES
WATER, STRONG BASES, ALCOHOLS, METAL COMPOUNDS.
Stability Condition to Avoid:AVOID TEMPERATURES GREATER THAN 120F OR
BELOW 50F.
Hazardous Decomposition Products:CO, OXIDES OF NITROGEN, TRACES OF HCN,
MDI.
Conditions to Avoid Polymerization:CONTAMINATION BY MOISTURE OR OTHER
MATERIAL THAT REACT WITH ISOCYANATES.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DOT/UN SHIPPING NAME: ADHESIVE. DOT HAZARD CLASS:
NON-HAZARDOUS. DOT/UN HAZARD NUMBER: NONE REQUIRED. DOT PLACARD:
NONE REQUIRED.

SARA Title III Information:THIS MATERIAL FITS THE EPA HAZARD CATEGORY
DEFINITION OF IMMEDIATE (ACUTE) AND DELAYED (CHRONIC) HEALTH
HAZARDS UNDER SARA (SECTIONS 311 AND 312). SARA SECTION 313 TOXIC
CHEMICALS FOR REPORTING: ETHYL ENE GLYCOL CAS 107-21-1, 2%,
METHANOL CAS 67-56-1, 1-2%.
Federal Regulatory Information:CHEMICAL SUBSTANCES HAVE BEEN REPORTED
TO THE EPA OFFICE OF TOXIC SUBSTANCES IN ACCORDANCE WITH THE
REQUIREMENTS OF THE TOXIC CHEMICAL SUBSTANCES CONTROL ACT (TITLE 40
CFR 710).
State Regulatory Information:CALIFORNIA PROPOSITION 65 LISTED
CHEMICALS: NONE KNOWN.