Product ID:ESTERON 99 CONCENTRATE 2,4-D HERBICIDE
MSDS Date:05/15/1986
FSC:6840
NIIN:00F001442
MSDS Number: BBJHR

DOW CHEMICAL U.S.A.

2020 DOW CENTER
MIDLAND, MI 48674

Emergency Phone: (517) 636-4400

Info Phone: (517) 636-4400

Cage: 71954

DOW CHEMICAL U.S.A.

MIDLAND, MI 48674 US

Telephone: 517-636-4400

Cage: 71983

2,4-D ESTERS (SARA III)

CAS: 25168-26-7

RTECS: AG8575000

Fraction By Weight: <65.4%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

KEROSENE

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: <34.6%

EMULSIFIERS

Fraction By Weight: <34.6%

ISOOCTYL ALCOHOL

CAS: 26952-21-6

RTECS: NS7700000

Fraction By Weight: <34.6%

OSHA PEL S, 50 PM

ACGIH TLV: S, 50 PPM; 9192

LD50 LC50 Mixture:ORAL LD50 (RATS): 1792 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE MODERATE IRRITATION &
CORNEAL INJURY. SKIN: IRRITATION. INGESTION: GASTROINTESTINAL
IRRITATION, ULCERATION, LUNG DAMAGE, CHEMICAL PHEUMONIA, EVEN DEATH
& BURNS. INHALATION: RESPIRATORY IRRITATION. EYES: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: LIVER, KIDNEY, GASTROINTESTINAL,
MUSCULAR EFFECTS, NAUSEA, VOMITING, ABDOMINAL CRAMPS, DIARRHEA,
ANESTHETIC, NARCOTIC EFFECTS, & RESPIRATORY IRRITATION. EYES:
IRRITATION & CORNEAL INJURY. SKIN: IRRITATION. INGESTION:
GASTROINTESTINAL IRRITATION, ULCERATION, LUNG DAMGE, CHEMICAL
PNEUMONIA & EVEN DEATH.

First Aid:EYES: FLUSH W/FLOWING WATER FOR 15 MINUTES. CONSULT
PHYSICIAN. SKIN: WASH OFF IN FLOWING WATER. INGESTION: DON'T INDUCE
VOMITING. CALL PHYSICIAN. INHALATION: REMOVE TO FRESH AIR IF
EFFECTS OCCUR. CONS ULT PHYSICIAN.

Flash Point Method:TCC
Flash Point:150F
Extinguishing Media:WATER FOG, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE, SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NOXIOUS VAPORS FORMED UNDER FIRE
CONDITIONS. CONTAIN WATER FROM FIRE-FIGHTING TO PREVENT ENTRY TO
WATER SUPPLIES.

Spill Release Procedures:ABSORB IN INERT MATERIAL SUCH AS SAND &
SAWDUST. DIKE AREA IN CASE OF LARGE SPILLS. DON'T USE WATER FOR
CLEANUP.

Handling and Storage Precautions:KEEP OUT OF REACHOF CHILDREN. DON'T
SWALLOW. AVOID CONTACT W/SKIN & EYES.
Other Precautions:DON'T STORE NEAR FERTILIZER, SEEDS, INSECTICIDES &
FUNGICIDES. KEEP AWAY FROM OPEN FLAME.

Respiratory Protection:WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
CERTAIN OPEATIONS, USE AN APPROVED AIR-PURIFYING RESPIRATOR.
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED Ventilation:PROVIDE LOCAL EXHAUST/MECHANICAL VENTILATION FOR SOME
OPERATION.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES, GOGGLES
Other Protective Equipment:IMPERVIOUS BOOT, APRON, FULL-BODY SUIT, EYE
FOUNTAIN & WASHING FACILITIES.
Supplemental Safety and Health
IN LABORATORY ANIMALS, EXPOSURES HAVING NO ADVERSE EFFECTS ON THE
MOTHER HAD OTHER HARMFUL EFFECTS ON THE FETUS. HIGH DIETARY LEVELS
OF 2,F-D CAUSED TOXIC EFFECT IN RATS ON A REPRODUCTIVE TEST. HAS BE
EN SHOWN TO BE NEGATIV IN SOME IN VITRO(TEST TUBE) MUTAGENICITY
TESTS & POSITIVE IN OTHERS.

Boiling Pt:B.P. Text:>300F
Vapor Pres:0.4
Vapor Density:4.7
Spec Gravity:1.03
Solubility in Water:EMULSIFIABLE
Appearance and Odor:AMBER LIQUID W/HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
ACID, BASE, OXIDIZING MATERIAL.
Stability Condition to Avoid:AVOID TEMPERATURES NEAR OR ABOVE FLASH
POINT.
Hazardous Decomposition Products:NOXIOUS FUMES (AS HYDROCHLORIC ACID)
UNDER FIRE CONDITIONS.

Waste Disposal Methods:IF WASTES CANNOT BE DISPOSED OF BY USE ACCORDING
TO LABEL INSTRUCTIONS, CONTACT YOUR STATE PESTICIDE, ENVIRONMENTAL
CONTROL AGENCY OR THE HAZARDOUS WASTE REPRESENTATIVE AT THE NEAREST
EPA REGIONAL OFF ICE FOR GUIDANCE.

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particular situation.