BBJPK - CLEANING SOLUTION (CHROMIC ACID - SULF)

  • MSDS: BBJPK
  • Manufacturer: FISHER SCIENTIFIC CHEMICAL DIV
  • Product Name: CLEANING SOLUTION (CHROMIC ACID - SULF)
  • National Stock Number: 6850-00F001628
Product Identification

Product ID:CLEANING SOLUTION (CHROMIC ACID - SULF)
MSDS Date:11/14/1985
FSC:6850
NIIN:00F001628
MSDS Number: BBJPK

Responsible Party
FISHER SCIENTIFIC CHEMICAL DIV
1 REAGENT LN
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100/201-796-7523

Info Phone: 201-796-7100/201-796-7523

Cage: 1B464

Contractor
ROSE AND CO INC
FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 9Z317

Ingredients

SULFURIC ACID

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 97.3%

OSHA PEL 1 MG/CUM

ACGIH TLV: 1 MG/CUM=IC

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


CHROMIC ACID (SOLID OR SOLUTION), CRO3, CHROMIUM (VI)

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: 1%

OSHA PEL 0.1 MG/CUM (CRO3)

ACGIH TLV: 0.05 MG/CUM (CR)


WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 1.7%

Hazards

LD50 LC50 Mixture:ORAL LDLO (MAN) 2135 MG/KG SULFURIC ACID
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALE: CORROSIVE/SEVERE RESPIRATORY
IRRITATION/DAMAGE/DYSPNEA/TRACHROBRONCHITIS/BRONCHIAL PNEUMONIA/GI
DISTURBANCES/LIVER/KIDNEY DAMAGE. SKIN: CORROSIVE/SEVERE
IRRITATION/DERMATITIS/SENSITIZER. EYES: CORROSIVE/SEVERE
DAMAGE/IRRITATION/CONJUNCTIVITIS. INGEST: CORROSIVE/SERIOUS BURNS
OF THE MOUTH/ESOPHAGUS/ASPHYXIA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALE: PULMONARY
EDEMA/CYANOSIS/HYPOTENSION/COUGH/DISCOLORATION/NOSE BLEEDS, FOUL
SMELLING NASAL DISCHARGE/EROSION & DISCOLORATION OF TEETH. SKIN:
PAIN/BURNS/VESICULATION/ULCERS. EYES: BLINDNESS/LACR IMATION.
INGESTION: VOMITING/DIARRHEA OF DARK PRECIPITATED BLOOD/PERFORATION
OF ESOPHAGUS & STOMACH.

First Aid

First Aid:SKIN: REMOVE CONTAMINATED CLOTHING/SHOES IMMEDIATELY. WASH
AFFECTED AREA W/SOAP/MILD DETERGENT & WATER. CHEMICAL BURNS, COVER
W/STERILE, DRY DRESSING. EYES: WASH IMMEDIATELY W/PLENTY OF WATER
FOR 15 M INUTES. CHEMICAL BURNS APPLY STERILE BANDAGES LOOSELY
W/OUT MEDICATION. INGEST: DON'T USE GASTRIC LAVAGE/INDUCE VOMITING.
DILUTE ACID IMMEDIATELY W/PLENTY OF WATER/MILK. OBTAIN MED. ATTN.
IN ALL CASES

Fire Fighting

Flash Point:NONFLAMMABLE
Extinguishing Media:DRY CHEMICAL, CO2, LARGE FLOOD AREA W/WATER FROM A
DISTANCE.
Fire Fighting Procedures:DON'T GET SOLID STREAM OF WATER ON SPILLED
MATERIAL. MOVE CONTAINERS FROM FIRE AREA. COOL CONTAINERS EXPOSED
TO FLAMES W/WATER FROM SIDE UNTIL OUT.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE, EXPLOSION HAZARD WHEN
EXPOSED TO HEAT/FLAME. USE FLOODING AMOUNTS OF WATER AS FAR, APPLY
FROM A SAFE DISTANCE. KEEP UPWIND. USE SCBA.

Accidental Release

Spill Release Procedures:KEEP COMBUSTIBLES AWAY. DON'T TOUCH MATERIAL.
DON'T GET WATER INSIDE CONTAINER. STOP LEAK W/OUT RISK. USE WATER
SPRAY TO REDUCE VAPORS. CON'T PUT WATER ON LEAK. DIKE FOR LATER
DISPOSAL. VENTILATE AREA . (SEE SUPP)

Exposure Controls

Respiratory Protection:SUPPLIED AIR RESPIRATOR W/FULL FACEPIECE, HELMET
OR HOOD. SELF CONTAINED BREATHING APPARATUS W/FULL FACEPIECE.
FIREFIGHTER: SCBA W/FULL FACEPIECE OPERATED IN PRESSURE
DEMAND/OTHER POSITION PRESSURE MO DE.
Ventilation:LOCAL EXHAUST
Protective Gloves:REQUIRED
Eye Protection:SPLASH PROOF/DUST RESISTANT GOGGLES
Other Protective Equipment:FACESHIELD, EYE-WASH FOUNTAIN.
Supplemental Safety and Health
CON'T ON MATERIAL TO AVOID: FOR MORE INFORMATION SEE ORIGINAL MSDS.
SOIL SPILL: DIG HOLDING AREA, DIKE, USING SOIL/SAND BAGS/FOAMED
BARRIERS USE CURRENT POWDER, FLY ASH TO ABSORB. NEUTRALIZE W/SLAKED
LIME, SODIUM BICARBONATE/CRUSHED LIMESTONE. AIR SPILL: KNOCK DOWN
VAPOR W/WATER SPRAY.

Chemical Properties

Boiling Pt:B.P. Text:554F
Melt/Freeze Pt:M.P/F.P Text:23F
Vapor Pres:.001
Spec Gravity:1.9
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN VISCOUS LIQUID.

Stability

Stability Indicator/Materials to Avoid:YES
WATER, ORGANIC MATERIALS, COMBUSTIBLE MATERIALS, ALCOHOLS, ACIDS,
METALS, SALTS (SEE SUPP.)
Stability Condition to Avoid:HEAT, FLAME
Hazardous Decomposition Products:SULFURE OXIDES & CHROMIUM OXIDE

Disposal

Waste Disposal Methods:DISOPSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS. RUNOFF TO SEWER MAY CREATE FIRE/EXPLOSION
HAZARD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.