BBPPY - PAPI (R) 135 POLYMERIC MDI, #03035

  • MSDS: BBPPY
  • Manufacturer: DOW CHEMICAL U S A
  • Product Name: PAPI (R) 135 POLYMERIC MDI, #03035
  • National Stock Number: 6810-00F004154
Product Identification

Product ID:PAPI (R) 135 POLYMERIC MDI, #03035
MSDS Date:01/01/1987
FSC:6810
NIIN:00F004154
MSDS Number: BBPPY

Responsible Party
DOW CHEMICAL U.S.A./MIDLAND, MI 48674

Emergency Phone: (517) 636-4400

Cage: 96717

Contractor
DOW CHEMICAL CO
MIDLAND, MI 48674 US

Telephone: 800-258-2436

Cage: 96717

Ingredients

METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA III)

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 50%

OSHA PEL C, 0.02 PPM

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


POLYMETHYLENE POLYPHENYL ISOCYANATE

RTECS: TR0320000

Fraction By Weight: 60%

Hazards

Effects of Overexposure:EYE: IRRITATION. SKIN CONTACT:
PROLONGED/REPEATED EXPOSURE MAY CAUSE SKIN IRRITATION.

First Aid

First Aid:EYES: IRRIGATE WATER FOR 15 MINUTES. SKIN: WASH OFF IN
FLOWING WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE
TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN.

Fire Fighting

Flash Point:>400F (PMCC)
Extinguishing Media:CO2, DRY CHEMICAL, FOAM , HALON 1211.
Fire Fighting Procedures:DON'T RESEAL CONTAMINATED CONTAINERS AS
PRESSURE MAY RUPTURE
Unusual Fire/Explosion Hazard:WEAR POSITIVE PRESSURE SCBA AND FULL
PROTECTIVE CLOTHING.

Accidental Release

Spill Release Procedures:EVACUATE/VENTILATE SPILL AREA, DIKE SPILL TO
PREVENT ENTRY INTO WEAR SYSTEM, WEAR FU PROTECTIVE EQUIPMENT
INCLUDING POSITIVE PRESSURE SCBA. ABSORB THE ISOCYATE
W/SAWDUST/OTHER ABSORBENT, SHOVEL INTO S UITABLE UNSEALED
CONTAINERS.

Handling

Handling and Storage Precautions:STORE W/ADEQUATE EXHAUST VENTILATION.
AVOID BREATHING VAPOR/CONTACT WITH EYES/SKIN. STORE IN THTLY CLOSED
CONTAINERS FROM ATMOSPHERIC MOISTURE
Other Precautions:PROVIDE DRY NITROGEN PAD IF STORED IN BULK. STORE AT
A TEMPERATURE OF 50-95F. PROTECT FROM FREEZING. WASH SKIN AREA WITH
SOAWATER/LAUNDER CLOTHING BEFORE REUSE.

Exposure Controls

Respiratory Protection:USE AN APPROVED POSITIVE PRESSURE SCBA
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP BELOW TLV/LEL.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES/GOGGLES
Other Protective Equipment:BOOTS/APRON/FULL-BODY SUIT WILL DEPEND ON
OPERATION.
Supplemental Safety and Health
MSDS DATE: 08 AUG 1986.

Chemical Properties

Boiling Pt:B.P. Text:392F
Vapor Pres:<1
Vapor Density:8.6
Spec Gravity:1.2
Solubility in Water:REACTS
Appearance and Odor:BROWN LIQUID

Stability

Stability Indicator/Materials to Avoid:YES
AVOID WATER AS IT REACTS TO FORM HEAT/CO2/INSOLUBLE UREA.
Stability Condition to Avoid:WATER/ACID/BASE/METAL COMPOUNDS/SURFACE
ACTIVE MATERIALS.
Hazardous Decomposition Products:ISOCYANATE VAPOR/MIST/CO2/CO/NOX/TR OF
HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:STRONG
BASES/ALKALIES/TERTIARYAMINES/METAL SALTS/WATER >175C

Disposal

Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS.
LIQUIDS ARE USUALLY INCINERATED IN A PROPER FACILITY. SOLIDS ARE
USUALLY ALSO INCINERATED OR LANDFILLED. DISPOSE OF DRAIN/RINSE
FLUID ACCORDING TO FEDE RAL, STATE, AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.