Product ID:"KROVAR" I DF HERBICIDE
MSDS Date:10/11/1996
FSC:6840
NIIN:00-001-7710
MSDS Number: BCTXC

DU PONT E I DE NEMOURS & CO INC

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637,800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Preparer: MSDS NO. DU005711

Cage: 18873

TIMBERLAND ENTERPRISES INC

557 MONTICELLO, AR 71655 US

Telephone: 501-367-8561

Cage: 1HB45

BROMACIL, (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL)

CAS: 314-40-9

RTECS: YQ9100000

Fraction By Weight: 40%

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3; 9394

DIURON, [3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA] (SARA

CAS: 330-54-1

RTECS: YS8925000

Fraction By Weight: 40%

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3; 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

INERT INGREDIENTS (TYPE NOT SPECIFIED)

Fraction By Weight: 20%

LD50 LC50 Mixture:ORAL LD50 (RAT) IS >2,500 MG/KG.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. SKIN: MAY
BE DERMALLY ABSORBED IN HARMFUL AMOUNTS.MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF RESPIRATORY TRACT, LIVER ENLARGEMENT,
SPLEEN AND THYROID EFFECTS, RED BLOO D CELL DESTRUCTION. INGESTION:
HARMFUL TO BLOOD FORMING ORGANS.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES: IRRITATION, TEARING, BLURRED VISION.
SKIN: IRRITATION, RASH. INHALATION: RESPIRATORY TRACT IRRITATION,
LIVER ENLARGEMENT, SPLEEN AND THYROID EFFECTS, RED BLOOD CELL
DESTRUCTION, CYANOSIS, WEAKNE SS, AND SHORTNESS OF BREATH.
INGESTION:NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING AILMENTS
OF THE LIVER,SPLEEN AND BLOOD FORMING ORGANS MAY BE AT INCREASED
RISK FROM EXPOSURE.

First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP
AND WATER. IF ADVERSE SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF
BREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION:
IF CONSCIOUS,GIVE 2 GLASSES OF WATER AND INDUCE VOMITING. GET
MEDICAL ATTENTION.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:788F
Lower Limits:0.135 GM/L
Upper Limits:NOT GIVEN
Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL, CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. USE
WATER SPRAY. IF CONDITIONS PERMIT, LET FIRE BURN ITSELF OUT SINCE
WATER MAY INCREASE CONTAMINATION HAZARD.
Unusual Fire/Explosion Hazard:THE FINELY DISPURSED DUST FROM THIS
PRODUCT IS A FIRE OR EXPLOSION HAZARD IN THE PRESENCE OF SOURCES OF
IGNITION.RUNOFF FROM FIRE MAY BE A POLLUTION HAZARD.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN UP. SHOVEL OR SWEEP UP. NEVER RETURN TO CONTAINER FOR
REUSE. SCOOP INTO BAGS OR BOXES WITH PLASTIC OR ALUMINUM SHOVEL. IF
SPILL IS ON GROUND NEAR PLANTS/TREES,REMOVE TOP 2 INCHES OF TOP
SOIL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN WELL VENTILATED AREA. KEEP
CONTAINER TIGHTLY CLOSED. DO NOT STORE/CONSUME FOOD, DRINK, TOBACCO
IN AREAS WHERE THEY MAY BECOME CONTAMINATED.
Other Precautions:READ AND FOLLOW ALL LABEL DIRECTIONS.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL GOGGLES.
Other Protective Equipment:INDUSTRIAL-TYPE WORK CLOTHING, BOOTS,
COVERALLS, AND APRON AS REQUIRED TO AVOID SKIN EXPOSURE.PROVIDE EYE
WASH STATION.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
THOROUGHLY CLEAN ALL TRACES OF PRODUCT FROM APPLICATION EQUIPMENT
IMMEDIATELY AFTER USE. FLUSH TANK, PUMP, HOSES AND "BOOM" WITH
SEVERAL CHANGES OF WATER AFTER REMOVING NOZZLE TIPS AND SCREENS.
MIX ON LY ENOUGH PRODUCT FOR THE JOB AT HAND. AVOID OVER-FILLING OF
SPRAY TANK. AVOID STORAGE OF PESTICIDE NEAR WELL SITES.

HCC:T5
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:DISPERSIBLE
Appearance and Odor:SOLID;BROWN;NO ODOR.

Stability Indicator/Materials to Avoid:YES
MANUFACTURER STATES NONE KNOWN.
Stability Condition to Avoid:MANUFACTURER STATES NONE KNOWN.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL FOR DISPOSAL IN AN APPROVED AND PERMITTED
LANDFILL. DO NOT FLUSH TO S URFACE WATER OR SANITARY SEWER SYSTEM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.