BDQSH - CHLOROFORM

Product Identification

Product ID:CHLOROFORM
MSDS Date:01/01/1987
FSC:6810
NIIN:00-264-6609
MSDS Number: BDQSH

Responsible Party
E.I. DUPONT DE NEMOURS & COMPANY, INC
1007 MARKET STREET
WILMINGTON, DE 19899
US

Emergency Phone: 800-441-3637 OR 800-345-9999

Info Phone: 302-999-2161 OR 800-441-7575

Cage: 19898

Contractor
MMM SUPPLY INC
LONG BEACH, CA 90813-1145 US

Telephone: 213-590-8633

Cage: 7X274

Ingredients

CHLOROFORM (SARA III)

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 100%

OSHA PEL (C) 50 PPM

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Hazards

Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Explanation of Carcinogenicity:CHLOROFORM IS SUSPECTED BY NTP AND IARC
TO BE CARCINOGENIC.
Effects of Overexposure:SKIN:IRRITATS BY DEFAT.INHALED,INGESTED:
DIZINESS,UNCONS,EQUILIBRIUM LOSS,IRRITATS,LIVER DAMAGE.

First Aid

First Aid:SKIN:WASH W.SOAP & H2O EYES:FLUSH W. H2O. INGESTED:GIVE 2
GLASSES H2O; INDUCE VOMITING.CALL A PHYSICIAN. INHALE: REMOVE TO
FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE
CONTAMINATED CL OTHING. IF UNCONS DO NOT TAKE ANYTHING BY MOUTH.

Fire Fighting

Extinguishing Media:NONFLAMMABLE AND NONEXPLOSIVE IN AIR.
Fire Fighting Procedures:FIREMAN SHOUL WEAR RESPIR PROTECTION(SCBA)
Unusual Fire/Explosion Hazard:NONFLAMMABLE.IN PRESENCE OF STRONG ALKALI
AND WATER,CHLOROFORM MAY BECOME VIOLENTLY EXPLOSIVE.

Accidental Release

Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION
SOURCES. STOP LEAK. H2O SPRAY COOL CONT/DIVERT SPILL FROM
FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL
ABSORBENT,SHOVEL INTO METAL DRUMS: LG SPILL:DI KE W COMMERCIAL
ABSORBENT,PUMP INTO COVERED DRUMS

Handling

Handling and Storage Precautions:DO NOT STORE IN ALUMINUM CANS.KEEP
BUNG TIGHTLY CLOSED.STORE IN COOL,DRY PLACE.KEEP CONTAINER CLOSED.
Other Precautions:REMOVE CONTAMINATED CLOTHING PROMPTLY.FLUSH AFFECTED
AREA WITH WATER.DRY OR WASH CLOTHING BEFORE REUSE.

Exposure Controls

Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY CONDITIONS/
ADEQUATE VENT.
Ventilation:LOCAL EXHAUST FOR ADEQUAT VENT.MECH(TO OUTSIDE VIA
SCRUBBER)
Protective Gloves:NEOPRENE
Eye Protection:CHEM SPLASH GOGGLES
Other Protective Equipment:NEOPRENE CLOTHING,SAFETY SHOES TO AVOID
CHLOROFORM SPLASHES.
Supplemental Safety and Health
STORAGE CODE T4 RATHER THAN T1 BECAUSE ITEM IS NOT A KNOWN
CARCINAGEN,BUT IS SUSPECTED(ACGIH-1983-84).

Chemical Properties

HCC:T3
Boiling Pt:B.P. Text:142F,61C
Vapor Pres:160
Vapor Density:4.13
Spec Gravity:1.5
Evaporation Rate & Reference:< 1 (ETHER = 1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID WITH PLEASANT, SWEET ODOR.

Stability

Stability Indicator/Materials to Avoid:YES
WATER,AIR,SUNLIGHT CAN CAUSE SLOW OXIDATION TO PHOSGENE.
Stability Condition to Avoid:EXCESS WATER,FLAME,HOT SURFACES MAY
PRODUCE TOXIC GASES.
Hazardous Decomposition Products:PHOSGENE,HYDROGEN CHLORIDE.

Disposal

Waste Disposal Methods:ABSORB WITH VERMICULITE,OTHER COMMERCIAL
ABSORBENT.KEEP IN COVERED DRUMS PENDING DISPOSAL.HANDLE AND DISPOSE
IAW LOCAL,STATE AND FEDERAL REQULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.