BDSXX - CHLORINE

Product Identification

Product ID:CHLORINE
MSDS Date:11/01/1985
FSC:6830
NIIN:00-281-3464
MSDS Number: BDSXX

Responsible Party
UNION CARBIDE CORP;LINDE DIV
39 OLD RIDGEBURY ROAD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357

Info Phone: 800-822-4357

Cage: 36346

Contractor
UNION CARBIDE CORP LINDE DIV
DANBURY, CT 06817-0001 US

Telephone: 800-822-4357; 304-744-3487

Cage: 36346

Ingredients

CHLORINE (SARA III)

CAS: 7782-50-5

RTECS: FO2100000

Fraction By Weight: 100.0%

OSHA PEL (C) 1 PPM

ACGIH TLV: 0.5 PPM/1 STEL; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Hazards

Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Health Hazards Acute and Chronic:ACUTE:EYES SEVERE INFLAMMATION OF THE
CONJUNCTIVA,LENS INJURY.SKIN:SEVERE IRRITATION,CHEMICAL
BURNS,SCARRING,DERMATITIS.INHALATION:IRRITATING TO EYES,RESPIRATORY
TRACT,ASPHYXIANT AT HIGH CONCENTRATION S,CHOKING,MAY BE
DEATH,PULMONARY EDEMA.CHRONIC:LUNG DYSFUNCTION;CORROSION OF TEETH.
Effects of Overexposure:SEE HEALTH HAZARDS DATA.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE
WORSEN.

First Aid

First Aid:SKIN:FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.CALL A
PHYSICIAN. INHALATION:REMOVE TO FRESH AIR,CALL A PHYSICIAN AT ONCE.
EYES:FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,CALL A
PHYSICIAN IMMEDIATELY.

Fire Fighting

Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:EVACUATE ALL PERSONNEL FROM DANGER AREA.USE
NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED AREA WITH FULL PROTECTION.
Unusual Fire/Explosion Hazard:OXIDIZING AGENT;MAY ACCELERATE
COMBUSTION.CONTACT WITH FLAMMABLE MATERIAL MAY CAUSE FIRE OR
EXPLOSION.

Accidental Release

Spill Release Procedures:USE PROPER PERSONAL PROTECTION (NIOSH/MSHA
APPROVED SCBA)IMMEDIATELY EVACUATE ALL PERSONNEL FROM DANGER AREA.

Handling

Handling and Storage Precautions:NEVER WORK ON PRESSURIZED SYSTEM.IF
THERE IS A LEAK,CLOSE THE CYLINDER VALVE,BLOW DOWN THE SYSTEM BY
VENTING TO A SAFE PLACE,THEN REPAIR THE LEAK.

Exposure Controls

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR CHLORINE
OR SCBA IF ABOVE TLV/PEL.
Ventilation:USE ONLY IN CLOSED SYSTEM.CORROSION RESISTANT FORCED DRAFT
FUME HOOD IS PREFERRED.
Protective Gloves:NEOPRENE RUBBER.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:FULL SKIN,EYES AND RESPIRATORY PROTECTION.
Work Hygienic Practices:AVOID CONTACT WITH SKIN AND EYES;DO NOT BREATHE
VAPORS/MIST.
Supplemental Safety and Health
MSDS RECEIVED BY DGSC-SLM:APRIL 15,1988.

Chemical Properties

HCC:G7
Boiling Pt:B.P. Text:-29.3F/-34C
Vapor Pres:85.3 PSIG
Vapor Density:2.49
Spec Gravity:1.41
Evaporation Rate & Reference:HIGH (BUTYL ACETATE=1)
Solubility in Water:SLIGHT
Appearance and Odor:GREENISH-YELLOW GAS;PUNGENT IRRITATING CHOKING
ODOR.
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
METALS,AL,CU & BRASS,REDUCING AGENTS.
Stability Condition to Avoid:OIL,GREASE FLAMMABLE MATERIALS.EXTREME
HEAT.
Hazardous Decomposition Products:BURNING MAY PRODUCE TOXIC FUMES OF
CHLORIDES.

Disposal

Waste Disposal Methods:KEEP PERSONNEL AWAY:DISPOSAL MUST BE IN
COMPLIANCE WITH LOCAL,STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.