Product ID:CHLOROBENZENE
MSDS Date:01/01/1987
FSC:6810
NIIN:00-982-0724
MSDS Number: BGBKD

MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION

PARIS BYPASS
PARIS, KY 40361
US

Emergency Phone: 314-982-5000

Info Phone: 314-982-5000

Cage: 62910

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

CHLOROBENZENE (SARA III)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: >98%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM; 9192

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Effects of Overexposure:INH:NARCOTIC.MAY IRRIT RESP TRACT;ING:MAY CAUSE
HEAD,NAUSEA,COMA;SKIN/EYE:MAY IRRIT,REDNESS,PAIN ETC

First Aid:INHAL:RMV TO FRESH AIR.IF NEEDED,GIVE CPR/OXYGEN.GET
MD;INGEST:GIVE SEVRL GL OF WATER.DO NOT INDUCE VOMITG.IMMED GET
MD;SKIN:FLUSH W/LG QTY OF H*2O FOR 15 MIN.RMV CONTMNTD CLOTHES.GET
MD;EYES:IMMED FL USH W/PLENTY OF H*2O FOR AT LEAST 15 MIN.GET MD.

Flash Point:28.9C(84F)-C.C
Autoignition Temp:Autoignition Temp Text:638C
Lower Limits:1.3
Upper Limits:7.1
Extinguishing Media:DRY CHEM,FOAM OR CARBON DIOXIDE.WATER SPRAY TO COOL
CONTNR.
Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL
CONTR.
Unusual Fire/Explosion Hazard:ABOVE FLASH TP,VAP-AIR MIXTURE ARE
EXPLOSIVE.VAP CNA FLOW ALONG SURFCS TO DISTNT IGN SOURCE & FL BAK

Spill Release Procedures:VENTILATE & EVAC AREA.USE PROTCTV CLOTHG &
RESP PROTCTION FM VAP.CONTAIN & RECOVR LIQ WHEN POSS.SPILLS MAY BE
ABSORBD W/INERT MATL,VERMICULITE,DRY SAND & PLACE IN A CONTNR
PENDING DISPOSAL.DO NOT FLUS H TO SEWER.HAVE DRY POWDR EXINGUISHR
ONHAND.

Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTNRS AT
COOL,DRY,VENTILATED PLACE.PROTECT AGAINST PHY DAMAGE;SEPARATE FROM
OXIDIZERS.BOND/GRD CNTNRS FOR TRANSFER OF LIQUID.
Other Precautions:AVOID BREATHING VAPS.USE W/ADEQUATE VENTILATION.KEEP
CONTAINRS CLOSED.WASH THOROUGHLY AFTER HANDLING.AVOID SKIN,EYES &
CLOTHING CONTACT;OUTSIDE OR DETACHED STORAGE IS PREFERRED;NO SMKG
IN AREA

Respiratory Protection:SUPPLIED AIR RESPIR/SCBA; ESCAPE: GAS MASK
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Protective Gloves:IMPERVIOUS
Eye Protection:GOGGLES/FACE SHIELD
Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE
WASH STATION
Supplemental Safety and Health
MSDS FM MFR DATED:27 AUG 85,CONFORMS TO OSHA HAZ COMM STD.

HCC:F3
Boiling Pt:=132.2C, 270.F
Vapor Pres:12
Vapor Density:3.9
Spec Gravity:1.10
Evaporation Rate & Reference:1.0(BU-AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID.FAINT ALMOND LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZERS,DIMETHYL SULFOXIDE, & SILVER PERCHLORATE
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:HCL GAS,PHOSGENE GAS,CO,CO*2 UPON
THERMAL DECOMPOSITION.

Waste Disposal Methods:COLLECTED SPILLS MAY BE ATOMIZED IN A
RCRA-APPROVED COMBUSTION CHAMBER OR SHIPPED TO RCRA APPROVED
FACILITY FOR DISPOSAL;RQ(CWA/CERCLA):100LBS;ENSURE COMPLIANCE
W/LOCAL,STATE, & FEDERAL REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.