Product ID:DUOSAN
MSDS Date:01/01/1987
FSC:6840
NIIN:00F009016
MSDS Number: BGZFB

MALLINCKRODT, INC.

MALLINCKRODT & 2ND STS.
ST. LOUIS, MO 63147

Emergency Phone: (314) 982-2243

Info Phone: (314) 982-2922

Cage: DO886

MALLINCKRODT, INC.

M PARIS, KY 40361 US

Telephone: 314-982-5000

Cage: DO886

THIOPHANATE-METHYL

CAS: 23564-06-9

RTECS: BA3650000

Fraction By Weight: 15%

MANCOZEB

CAS: 8018-01-7

RTECS: ZB3200000

Fraction By Weight: 60%

INERT INGREDIENTS (TYPE NOT SPECIFIED)

Fraction By Weight: 25%

LD50 LC50 Mixture:ORAL LD50 (RAT) 10,000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SLIGHT CORNEAL OPACITY, MOD.
ERYTHEMA.
Explanation of Carcinogenicity:NONE

First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MIN. GET MED
ATT. SKIN: WASH W/PLENTY OF SOAP & WATER. INHALATION: MOVE TO CLEAR
ATMOSPHERE. IF SYMPTOMS APPEAR, GET MED ATT.

Extinguishing Media:DRY CHEMICAL, CO2.
Fire Fighting Procedures:TREAT THE SAME AS A CHEMICAL FIRE WHERE VAPORS
& DISCHARGES TO THE ENVIRONMENT ARE TO BE CONFINED & REMOVED AS
QUICKLY AS POSSIBLE.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:SOAK UP W/ABSORBENT MATERIAL. SWEEP INTO A
DISPOSABLE CONTAINER.

Handling and Storage Precautions:DON'T STORE AT TEMPERATURE EXCEEDING
122F. STORE IN DRY/WELL CLOSED CONTAINER. KEEP AWAY FROM HEAT OR
SPARKS. DON'T ALLOW TO BECOME WET/OVERHEATED.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:USE RESPIRATORS WHEN MIXING & HANDLING.
Ventilation:WORK IN WELL VENTILATED AREAS.
Protective Gloves:RUBBER
Eye Protection:GOGGLES
Work Hygienic Practices:USE CLOTHING, EQUIPMENT & PERSONAL HYGIENE
PROCEDURES CONSISTENT W/GOOD PESTICIDE HANDLING PRACTICE.
Supplemental Safety and Health

Solubility in Water:SLIGHT
Appearance and Odor:LIGHT GREEN POWDER. REDUCED SULFUR ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/OTHER PESTICIDES & FERTILIZERS.
Stability Condition to Avoid:AVOID STORAGE AT HIGH TEMPERATURES FOR
PROLONGED PERIODS. AVOID CONTAMINATION W/WATER.

Waste Disposal Methods:FOLLOW STATE & FEDERAL GUIDELINES FOR PESTICIDE
DISPOSAL. DON'T ALLOW TO CONTAMINATE WATER SUPPLIES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.