Product ID:GRS
MSDS Date:06/01/1986
FSC:9150
NIIN:00N019994
MSDS Number: BHHDV

STATE CHEMICAL MANUFACTURING CO.

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <30%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: <10%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED.EXPOSURE
TO NEAR ANESTHETIC LEVELS CAN CAUSE CARDIAC SENSITIZATION.CHRONIC
OVEREXPOSURE MAY RESULT IN LIVER DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:POSS SLIGHT,TEMPORARY CORNEAL
INJURY.SKIN:POSSIBLE IRRITATION.INGESTION:HARMFUL OR FATAL IF
SWALLOWED.INHALATION:PROLONGED BRTHG OF VAPORS MAY RESULT IN
DROW,DIZZ,HDCH,NAUS OR IRRIT OF EYES OR NO SE.EXPOS TO NEAR
ANESTHETIC LEVELS CAN RESULT IN BLOOD PRESS DEPRESSION,CARDIAC
SENSITIZATION & VENTRICULAR ARRHYTHMIA.
Medical Cond Aggravated by Exposure:LIVER DISEASE AND RHYTHM DISORDERS
OF THE HEART.

First Aid:EYES:FLUSH IMMED WITH PLENTY OF COOL WATER FOR AT LEAST 15
MIN.IF IRRIT PERSISTS,SEEK MED ATTN.SKIN:N/A.INGEST:DO NOT INDUCE
VOMITING.CALL MD IMMED (NOTE TO MD:NEVER GIVE ADRENALIN TO PERSON
OVEREXPOS ED TO 1,1,1-TRICHLOROETHANE).INHAL:REMOVE TO FRESH AIR.IF
IRRITATION PERSISTS,CONTACT MD.

Flash Point Method:TOC
Flash Point:PROPELLANT:<20F
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER FOG,FOAM,CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .KEEP CANS COOL.USE SHIELDING TO PROTECT PERSONNEL
AGAINST VENTING,RUPTURING OR BURSTING CANS.
Unusual Fire/Explosion Hazard:EXPOSURE TO TEMPERATURES >120F,49C MAY
CAUSE CANS TO VENT,RUPTURE OR BURST.UPON BURNING CO,CO*2,HYDROGEN
CHLORIDE OR PHOSGENE GASES MAY BE EVOLVED.

Spill Release Procedures:ABSORB EXCESS ON SAND,VERMICULITE,ETC.FLUSH
RESIDUE WITH SOAP AND WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:FLAM.DO NOT USE OR STORE NEAR
FLAME,HEAT OR SPARKS.DO NOT STORE IN DIRECT SUN OR TEMP
>120F,49C.DO NOT PUNCTURE OR INCINERATE.CONTENTS UNDER PRESSURE.
Other Precautions:NO SMKG IN AREA.DO NOT USE IN GEN VICIN OF ARC
WELDING,OPEN FLAME OR HOT SURFACES.HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE .READ & FOLLOW ALL LABEL DIRECTIONS &
PREC BEFORE USE.FOR INDUS USE ONLY.KEEP AWAY FROM CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:OPTIONAL
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE
Work Hygienic Practices:N/K
Supplemental Safety and Health
N/K

Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Evaporation Rate & Reference:N/K
Solubility in Water:<1%
Appearance and Odor:A RED GREASE WITH A SOLVENT ODOR.
Percent Volatiles by Volume:50

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,STRONG CAUSTICS AND SOME PLASTICS.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:UPON BURNING CARBON MONOXIDE,CARBON
DIOXIDE,HYDROGEN CHLORIDE OR PHOSGENE MAY BE EVOLVED.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .GIVE CANS TO A DISPOSAL
SERVICE EQUIPPED TO SAFELY DISPOSE OF PRESSURIZED CONTAINERS.DO NOT
INCINERATE,PUNCTURE OR DISPOS E OF IN FIRE.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.