Product ID:MIL-C-46168D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-130-3347
Kit Part:Y
MSDS Number: BHNDQ

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL LESS WATER & NPRS* (NK) G/L

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: IRRI MUCOUS MEMBRANE, PERMANENT
BRAIN & NER SYS DAM OR DEATH, LOSS OF MEMORY, INTELLECTUAL ABILITY,
COORDINATION. SKIN: SENSITIZATION/SUSECPTIBLE INFECT-ION. EYES:
IRRITATING. INGES: IRRI, POSS CORROSIVE ACTION TO MOUTH, STOMACH
TIS-SUE, DIGESTIVE TRACT. VOMIT MAY CAUSE ASPIRATION, RESULTING IN
CHEM PNEUMONITIS
Explanation of Carcinogenicity:NOT LISTED
Effects of Overexposure:INHAL: IRRI NOSE, THROAT, LUNGS, RUN NOSE,
COUGH, CHEST DISCOMFORT, RESPIRATORY TRACT, POSS ASTHMATIC ATTACK,
ISOCYANATE SENSITIZ. SKIN: RED, SWELL, RASH, SCAL,DRY, DEFATT,
CRACKED SKIN. EYE: RED, TEA R, SWELL, STING SENSATION, FEELING
LIKEDUST IN EYE. INGES: IRRI, POSS CORROSIVE ACTION OF MOUTH,
STOMACH TISSUE, DIGEST
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA, & HYPERREACTIVITY; SKIN ALLERGIES AND
ECZEMA

First Aid:INHAL: REMOVE TO FRESH AIR. ADMIN OXYGEN/CPR AS NEEDED.
OBTAIN MED ATTN. TREAT SYMPTOMATICALLY. SKIN: REMOVE CONTAM
CLOTHES IMMED. WASH AREA THORO W/SOAP & WTRLAUNDER CLOTHES THORO
BEFORE REUSE. SEEK MED ATTN, IF IRRI PERSISTS/DEVELOPS.EYE: FLUSH
W/CLEAN, LUKEWARM WTR 15 MIN, LIFTING LIDS. OBTAIN MED ATTN. INGES:
DO NOT INDUCE VOMIT. DO NOT GIVE ANYTHING BY MOUTH IF UNCONSC.
CONSULT PHYSICIAN

Flash Point Method:PMCC
Flash Point:91 F/ 33 C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:SELF CONTAINED BREATH APPARATUS/FULL
PROTECTIVE CLOTHES. HIGH TOXIC GAS MAY BE GENERATED BY THERM
DECOMP/COMBUST. ISOLATE FROM HEAT, ETC. CLOSED CONT MAY EXPLO
Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR, STAGNANT AIR
CAUSE VAP TO BUILD/TRAVEL ALONG GROUND TO IGNITION SOURCE DISTANT,
CAUSING FLASH BACK/EXPLOSION. AVOID EXTREME HEAT, ETC.

Spill Release Procedures:EVACUATE NON-ESSENT PERSONS. REMOVE ALL
SOURCES OFIGNITION. VENT AREA. DIKE/IMPOUND SPILL MATERIAL, POUR
DECONTAM SOLUTION OVER SPILL AREA/ALLOW TO REACT 10 MIN. COLLECT
OPEN CONT/SAFE PLACE, COVER LOOSELY, LET TO STAND 24-48 HRS.
WASH DOWN W/DECON

Handling and Storage Precautions:32 F MIN/122F MAX. SHELF LIFE: 12 MO @
77 F. HDI REACTS SLOWLY W/WATER TO FORM CO2 GAS. GAS CAN CAUSE
SEALED CONT TO EXPAND/POSS RUPTURE EXPLOSIVELY
Other Precautions:SINCE THIS PRODUCT MEETS THE CRITERION OF
IGNITIBILITY, IT IS HAZARDOUS WHEN DISCARDED. GROUND CONT DURING
STORAGE/TRANFER OPERATIONS. STORE TIGHTLY CLOSED CONTTO PREV MOIST
CONTAM. DO NOT RESEAL IF C ONTAM IS SUSPECTED. 50-81F TEMP STORAGE

Respiratory Protection:OBSERVE OSHA REG FOR RESPIRATOR USE. PROPERLY
FITTED AIR-PURIFYING RESPIRATOR. LIMITED VENT, USE POSITIVE
PRESSURE SUPPLIED AIR RESPIRATOR IS MANDATORY. NON- SPRAY
OPERATIONS AT LEAST AN AIR PURIFYI NG RESPIRATOR IF REQUIRED.
Ventilation:EXHAUST VENT SUFFICIENT TO KEEP THE AIRBORNE CONCEN OF
SOLVENT BELOW RESPEC TLV. EXHAUST AIR-CLEANED BY SCRUBBERS/FILTER
Protective Gloves:CHEM RESISTANT GLOVES
Eye Protection:SAFETY GLASSES/SPLASH GOGGLE/FACE SHIELD
Other Protective Equipment:CONTACT LENSES SHOULD NOT BE WORN. COVER AS
MUCH OF THE SKINAREA AS POSSIBLE. PROTECT SKIN W/CREAM ONLY TO
MINIMUM
Work Hygienic Practices:WASH HANDS THORO BEFORE EATING & BEFORE USING
RESTROOMS. SMOKE ONLY IN SMOKING AREAS. SAFETY SHOWERS & EYEWASH
STATIONS.
Supplemental Safety and Health
EMPLOYEES SHOULD BE EDUCATED & TRAINED IN THE SAFE USE OF THIS PRODUCT.
NOTE TO PHYSICIAN: EYE: CORNEAL INJURY; IF BURNED, INSTILL
ANTIBIOTIC/STEROID PREP FREQ.REVERS CORNEAL EPITH EDEMA IMPAIR
VISION . SKIN: SENSITIZER. TREAT DERM/THER BURNINGES: NO SPEC
ANTIDOTE. VOMIT IS CONTRAINDICATED, IRRI COMP. INHAL: SENSITIZER

HCC:F3
Boiling Pt:B.P. Text:NE
Decomp Temp:Decomp Text:NE
Vapor Density:> AIR
Viscosity:MPAS@ 20C 183
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE
ACTIVE MATERIALS
Stability Condition to Avoid:STABLE UNDER REASONABLE CONDITIONS OF
STORAGE AND USE
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON
DIOXIDE/MONOXIDE, OXIDES OF NIT-ROGEN, TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF CONTACT WITH MOISTURE
OR OTHER MATERIALS WHICH REACT WITH ISOCYANATES. MAY OCCUR AT TEMP
OVER 400 F(204 C)

Waste Disposal Methods:ACCORD W/FED, STATE & LOCAL ENVIRON CONTROL REG.
INCINERATEION PREFERRED. EMPTY CONT HANDLE W/CARE FLAMM
RESIDUE/SOLVENT VAPOR. DECONTAM CONTAINER. DO NOT HEAT, CUT ON/OR
NEAR EMPTY CONT W/ELEC OR GAS TORCH. DISPOSE DECONTAMINATED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.