Product ID:MIL-C-46168 D PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-144-9884
Kit Part:Y
MSDS Number: BHNFS

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALE:IRR MUCOUS MEMB IN
NOSE,THRT/LUNGS.RUNNY NOSE,SORE THRT,COUGH,CHEST DIS- COMFORT,SHORT
BREATH,REDUCED LUNG FUNC.ISOCYANATE SENSITIZATION.SKIN:IRR,RED,
SWELL,RASH,SCALE,BLISTER.SKIN SENSITIZAT
ION,DRY,DEFATTED,CRACKED.SIM EFFECT
ASIHALE.EYE:IRR,TEAR,RED,SWELL.FEEL OF FINE DUST IN
EYE.INGEST:IRR,CORR ACTION.
Effects of Overexposure:INHALE:BRONCHITIS,ASTHMA ATTACK,BRONCHIAL
SPASM,PULMONARY EDEMA,HYPERSENSITIVE
PNEUMONITIS.HEADACHE,NAUSEA,NARCOSIS,FATIGUE,LOSS APPET.DELIB
INHALE:PERMANENT NERV SYS/BRAIN DAMAGE,LOSS MEMORY,DEATH. LUNG
DAMAGE,LOSS COORD.SKIN:DRY,DEFATTEDCRACKED,DERMITITIS.EYES:FEELING
OF DUST.INGEST:IRR/POSS CORROSIVE,MOUTH,GI TRACT
Medical Cond Aggravated by Exposure:ASTHMA,RESPIRATORY DISORDERS
RE:BRONCHITIS,EMPHY- SEMA,HYPERREACTIVITY;SKIN ALLERGIES,ECZEMA.

First Aid:INHALE:MOVE FROM EXPOSURE.ADMIN OXYGEN/CPR IF NEEDED.GET MED
ATTN.ASTHMATIC TYPESYMPTOMS MAY DEVELOP.MAY BE IMMED OR
DELAYED.TREAT SYMPTOMATICALLY.SKIN:REMOVE CONTAMINATED CLOTH
IMMED.WASH W/SOAP&WAT ER.WASH CONTAMINATED CLOTH.GET MED ATTNIF IRR
PERSISTS.EYE:FLUSH W/CLEAN,LUKEWARM WATER FOR 15 MIN,OCC LIFT
EYELIDS.GETMED ATTN.INGEST:DO NOT INDUCE VOMIT.GET MED ATTN.NOTHING
BY MOUTH TO UNCONCIOUS.

Flash Point Method:PMCC
Flash Point:91 F/ 33 C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, "ALCOHOL" FOAM, C02, DRY CHEMICAL.
Fire Fighting Procedures:FULL EMERGENCY EQUIP W/SELF-CONT BREATH
APPARATUS,FULL PROTECT CLOTHING.ISOLATE FROM HEAT,ELECT
EQUIP,SPARKS,OPEN FLAME.CLSD CONT MAY EXPLD IF EXPS'D EXTR HEAT.
Unusual Fire/Explosion Hazard:MAY BURST WHEN CONTAIM W/WATER,CREATE
C02.SOLVENT VAPORS MAY BE >AIR.STAGNANT AIR MAY CAUSE VAPORS TO
BUILD/TRAVEL ALONG GRND TO IGN SOURCE,POSS FLASHBACK.

Spill Release Procedures:EVACUATE.REMOVE SOURCE IGNITION,VENT
AREA.DIKE/IMPSPILLED MAT,CONTROL.NOTIFY AUTHORITIES.COVER WITH
SAWDUST,VERMICULITE,ETC.POUR DECONT MAT OVER LET REACT 10
MIN.COLLECT OPEN CONT,COVER LOOSE,LET STAND 24-48HRS.WASH DOWN
AREA W/DECONT SOLUTIONS.
Neutralizing Agent:UNION CARBIDE TERGITOL TMN-10(20%)WTR(80%);CONC
AMMON(3-8%)DETERG(2%)WTR (90-95%

Handling and Storage Precautions:STORE IN TIGHTLY CLSD CONTNR TO
PREVENT MOISTURE CONTAM.IDEAL STORAGE TEMP IS 50-81F/10-27C.KEEP
AWAY FROM HEAT,SPARKS, AND OPEN FLAME.
Other Precautions:GROUND CONTAINERS DURING STORAGE AND TRANSFER
OPERATIONS. DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. AVOID
CONTACT WITH SKIN AND EYES. AT MAXIMUM STORAGE TEMPERATURES NOTED,
MATERIAL MAY SLOWLY POLY MERIZE WITHOUT HAZARD.

Respiratory Protection:RESPIRATOR THAT IS RECOM'D FOR ISOCYANATE
ENVIRO.MANDATORY IF USING IN CONFINED AREA/LIMITED VENT.SHOULD BE
USED IN NON-SPRAYING OPERATIONS.(POS PRESS SUPPLIED AIR).IF
AIRBORNE CONCENT NK,RESP IS NEED ED.SOLV CONCENT SHOULD BE CONSID
FOR USE
Ventilation:EXHAUST VENT SUFF TO KEEP AIRBORNE CONCENT OF SOLV BELOW
TLVEXHAUST AIR NEEDS TO BE CLEANED BY SCRUBBERS/FILTERS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACESHIELD
Other Protective Equipment:SKIN CREAM,APPROPRIATE CLOTHING.SAFETY
SHOWERS,EYEWASH STA- TIONS.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND BEFORE
USING REST- ROOMS.SMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
IF CORNEA IS BURNED INSTILL ANTIBIOTIC/STEROID PREPARATION
FREQUENTLY.WORKPLACE VAPORS COULD PRODUCE REVERS CORNEAL EPITHELIAL
EDEMA IMPAIRING VISION.TREAT FOR DERMATITIS OR THERMAL
BURN.INDUCING VOMI TING IS CONTRAINDICATED BECAUSE OF THEIRRITATING
NATURE OF THE COMPOUND.STAIN FOR EVIDENCE OF CORNEAL INJURY.

Boiling Pt:B.P. Text:NE
Vapor Density:>AIR
Viscosity:183MPAS @ 20C
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR.
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER,AMINES,STRONG BASES,ALCOHOLS,METAL COMPOUNDS,SURFACE ACTIVE
MATERIALS.
Stability Condition to Avoid:MOISTURE,HIGH TEMPERATURES,SHOCK FROM
DROPPING.
Hazardous Decomposition Products:BY HIGH HEAT & FIRE:CARBON
DIOXIDE,CARBON MONOXIDE,OXIDES OFNITROGEN,TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT W/ISOCYANATES.MAY OCCUR
AT TEMP OVER 400F(204C).

Waste Disposal Methods:IN ACCORD W/FED,STATE,LOCAL ENVIRO REGS.INCINER-
ATION IS PREF.EMPTY CONT MUST BE HAND W/CARE DUE TO PRODUCT
RESIDUE/FLAM SOLV VAPOR.DECONTAMINATE PRIOR TO DISPOSAL.DO NOT
HEAT OR CUT ON OR NEAR EMPTY CONTAINER W/ELECTRICAL OR GAS
TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.