Product ID:FORMULA 190
MSDS Date:01/01/1988
FSC:6840
NIIN:00N010002
MSDS Number: BHNMD

STATE CHEMICAL MANUFACTURING CO.

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

PETROLEUM DISTILLATE

Fraction By Weight: 95.83%

OSHA PEL N/K

ACGIH TLV: N/K

BROMACIL

CAS: 314-40-9

RTECS: YQ9100000

Fraction By Weight: 0.98%

OSHA PEL 1 PPM

ACGIH TLV: 10 MG/M3; 9192

2,4-D ESTERS (SARA III)

CAS: 25168-26-7

RTECS: AG8575000

Fraction By Weight: 1.09%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHRONIC OVEREXPOSURE:CENTRAL NERVOUS
SYSTEM DEPRESSION AND INTERNAL ORGAN DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRITANT.SKIN:IRRITANT.POSSIBLE CAUSE OF
DERMATITIS.INHALATION:VAPORS ARE IRRITATING TO THE NOSE AND
THROAT.INGESTION:HARMFUL OR FATAL IF SWALLOWED.OVEREXPOSURE MAY
CAUSE NAUSEA,VOMITING.ASPIRATI ON INTO LUNGS CAUSES CHEMICAL
PNEUMONIA.
Medical Cond Aggravated by Exposure:BRONCHIAL CONDITIONS.SKIN
IRRITATION AND DERMATITIS.EYE IRRITATION.

First Aid:EYES:FLUSH EYES IMMEDIATELY WITH WATER FOR AT LEAST 15
MIN.GET MED ATTN.SKIN:WASH WELL WITH SOAP AND WATER.REMOVE
CONTAMINATED SHOES AND CLOTHING.INHALATION:REMOVE TO FRESH AIR.USE
ARTIFICIAL RESPIRAT ION IF NEEDED.GET MED ATTN.INGESTION:DONOT
INDUCE VOMITING.ASPIRATION HAZARD DUE TO PETROLEUM DISTILLATES
PRESENT.CONTACT MD IMMED.

Flash Point Method:TCC
Flash Point:150F,65.56C
Lower Limits:7.0%
Upper Limits:1.0%
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM AND WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .A STRAIGHT STREAM OF WATER MAY SPREAD THE
FIRE,HOWEVER,WATER SPREAD FROM AS FAR A (SEE SUPP)
Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR & MAY TRAVEL TO
A DISTANT IGNITION SOURCE AND FLASHBACK.CNTRS INVOLVED IN FIRE MAY
RUPTURE OR EXPLODE.AVOID ACCUMULATION (SEE SUPP)

Spill Release Procedures:REMOVE SOURCES OF HEAT,SPARKS,OR
FLAME.VENTILATE AREA.DIKE AREA TO CONTAIN SPILL.USE ABSORBANT OR
VACUUMING TO COLLECT SPILL.DISPOSE OF PROPERLY.REPORTABLE QUANTITY
OF 2,4-DICHLOROPHENOXYACETIC ACID,I SOOCTYL ESTER IS 100 LBS.TOXIC
TO FISH & WILDLIFE.
Neutralizing Agent:N/K

Handling and Storage Precautions:READ COMPLETE LABEL PRECAUTIONS BEFORE
USING.DO NOT STORE NEAR POSSIBLE IGNIT SOURCES.STORE AWAY FROM
FOOD,FEED,OR FERTILIZERS.STORE ONLY (SEE SUPP)
Other Precautions:DO NOT EAT,SMOKE OR DRINK WHILE WORKING WITH THIS
PRODUCT.WASH HANDS & OTHER EXPOSED AREAS W/ SOAP/WATER BEFORE
EATING,DRINKING,OR SMOKING TO AVOID ACCIDENTAL INGESTION.WASH
CONTAM CLTHG SEPARATE FROM OTHER LAUNDRY.FOR INDUSTRIAL (SEE SUP)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:RUBBER BOOTS IF NEEDED TO AVOID GETTING SKIN
WET.
Work Hygienic Practices:WASH W/ SOAP & WATER AFTER ALL CONTACT WITH
THIS PRODUCT.
Supplemental Safety and Health
FIRE FIGHT PROC:DISTANCE AS POSSIBLE MAY BE USED TO COOL CNTRS INVOLVED
IN FIRE.EXPLO HAZ:OF VAPORS.HAZ DECOMP PRODS MAY INCLUDE
CO,CO*2,HCL & NITROGEN CONTAINING GASES.HNDLG/STOR PREC:IN ORIGINAL
CNT R.STORE ABOVE 40F,4.4C.OTHER PRECS:AND INSTITUTIONAL USE
ONLY.KEEP OUT OF REACH OF CHILDREN.VOLATILE BY WT >95%.

Boiling Pt:B.P. Text:350-500F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:0.85-0.9,H*2O=1
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TAN TO BROWN LIQUID WITH A PETROLEUM ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ACIDS OR BASES,SELECTED AMINES.
Stability Condition to Avoid:IGNITION SOURCES,ELECTRICAL
AREAS,HEAT,SPARKS AND OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON
DIOXIDE,HYDROGEN CHLORIDE,AND NITROGEN CONTAINING COMPOUNDS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .2,4-DICHLOROPHENOXYACETIC
ACID,ISOOCTYL ESTER IS AN ACUTE HAZ WASTE UNDER RCRA.FOLLOW LABEL
INSTRUCTIONS FOR DISPOSAL.DO NOT REUSE CNTR FOR ANY REASON.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.