Product ID:PEN
MSDS Date:02/01/1987
FSC:9135
NIIN:00N010466
MSDS Number: BHNSG

STATE CHEMICAL MANUFACTURING COMPANY

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: <5%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SARA III)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: <40%

OSHA PEL 100 PPM

ACGIH TLV: 25PPM/100,A3 STEL;94

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: <40%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: <5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED.LONG
TERM EXPOSURE TO VAPORS MAY CAUSE LUNG,LIVER OR KIDNEY DAMAGE.NIOSH
STUDIES INDICATE 2-BUTOXY ETHANOL HAS CAUSED REPRODUCTIVE DISORDERS
IN LABORATORY ANIMALS (RATS/M ICE) AND MAY HAVE THE POTENTIAL FOR
CAUSING SIMILAR DISORDERS IN HUMANS .
Explanation of Carcinogenicity:PERCHLOROETHYLENE:INADEQ EVID FOR CARCIN
IN HUMANS/SUFF EVID FOR CARCIN IN ANIMALS (IARC 1987).
Effects of Overexposure:EYES:IRRITATION.SKIN:IRRITATION.PROLONGED
CONTACT MAY RESULT IN DRYING OR CRACKING.INGEST:HARMFUL OR FATAL IF
SWALLOWED. INHAL:PROLONGED BREATHING OF VAPORS MAY RESULT IN
HEADACHE,DIZZINESS,DROWSINESS OR NAUSEA.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH EYES IMMEDIATELY WITH PLENTY OF COOL WATER FOR AT
LEAST 15 MINUTES.IF IRRITATION PERSISTS,CONTACT PHYSICIAN.SKIN:WASH
WITH SOAP AND WATER.IF IRRITATION PERSISTS,CONTACT
PHYSICIAN.INGEST:CON TAINS SOLVENTS.DO NOT INDUCE VOMITING.SEEK
MEDICAL ATTENTION IMMEDIATELY.INHAL:REMOVE PERSON TO FRESH AIR.IF
SYMPTOMS PERSIST.SEEK MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:350F,176.67C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER FOG,CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .KEEP CONTRS COOL.PROTECT PERSONNEL FROM
VENTING,RUPTURING OR BURSTING CONTR BY EQUIP/SHIELDING.
Unusual Fire/Explosion Hazard:AT TEMPERATURE >120F,48.89C CONTRS MAY
VENT,RUPTURE OR BURST.THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
HCL AND PHOSGENE.CARBON MONOXIDE.

Spill Release Procedures:REMOVE SOURCES OF FLAME,SPARKS OR
HEAT.VENTILATE AREA.WIPE UP EXCESS.FLUSH AREA WITH PLENTY OF WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT OR AT
TEMP >120F,48.89C.CONTENTS UNDER PRESSURE.DO NOT PUNCTURE OR
INCINERATE.VAPORS MAY BE HARMFUL,AVOID BRTHG THEM.
Other Precautions:DO NOT TAKE INTERNALLY.NO SMOKING IN AREA OF USE.DO
NOT USE IN THE GENERAL VICINITY OF ARC WELDING,OPEN FLAMES OR HOT
SURFACES.HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL
AND/OR PHOSGENE ( ).READ & FOLLOW LABEL (SEE SUPP)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .AVOID BREATHING THE CONCENTRATED VAPORS OF
THIS PRODUCT.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE
Work Hygienic Practices:N/K
Supplemental Safety and Health
% VOLAT BY WT:>80.OTHER PREC:DIRECTIONS/PRECAUTIONS BEFORE USE.KEEP OUT
OF THE REACH OF CHILDREN.FOR INDUSTRIAL USE ONLY.

Boiling Pt:B.P. Text:165-254F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:1.2 (H*2O=1)
Evaporation Rate & Reference:N/K
Solubility in Water:<1%
Appearance and Odor:AMBER PRESSURIZED SPRAY WITH PETROLEUM ODOR
CONTAINING CHERRY SCENT.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT,SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:HCL,PHOSGENE .CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT PUNCTURE OR INCINERATE
CONTAINERS.GIVE TO DISPOSAL SERVICE EQUIPPED TO SAFELY HANDLE AND
DISPOSE OF PRESSURIZED CO NTAINERS.

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This information is formulated for use by elements of the Department
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.