Product ID:PGR
MSDS Date:05/01/1987
FSC:8010
NIIN:00N010570
MSDS Number: BHVDX

STATE CHEMICAL MANUFACTURING CO

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: >60%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: <20%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHRONIC:POSSIBLE LIVER DISEASE.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:ACGIH A2=SUSP HUM
CARCIN (1988-89).INSUFF EVID FOR CARCIN IN HUM,SUFF IN ANIM (IARC
1987).
Effects of Overexposure:EYES:IRRIT.SKIN:DIRECT CONTACT IS
IRRIT.INGEST:HARMFUL.INHAL:VAP HARMFUL.CONTAINS METHYLENE
CHLORIDE.OVEREXPOS MAY RESULT IN HDCH,NAUS,DROW,DIZZ,NASAL & RESP
IRRIT.DELIB INHAL CAN BE HARMFUL OR FATAL. CHRONIC:MENTAL
CONFUSN,DEPRESS,FATIGUE,APPETITE LOSS,NAUS,VOMIT,COUGH,LOST SENSE
OF BALANCE & VISUAL DISTURBANCES.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ PLENTY OF COOL WATER FOR AT LEAST 15
MIN.CONTACT MD IMMED.DO NOT WEAR CONTACT LENSES.SKIN:WASH IMMED W/
PLENTY OF SOAP & WATER.IF IRRIT PERSISTS,CONTACT MD.INGEST:DRINK
LRG QTY OF WATER,THEN INDUCE VOMIT (PLACE FINGER AGAINST BACK OF
THROAT OR FOLLOW DIRECTIONS ON LABEL OF SYRUP OF IPECAC).CALL MD
IMMED.INHAL:REMOVE TO FRESH AIR.IF DFCLT BRTHG OR OTHER SYMPTOMS
PERSIST,CALL MD.

Flash Point:N/K
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM.WATER MAY BE
INEFFECTIVE,BUT MAY BE USED TO KEEP CANS COOL.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .SHIELD PERSONNEL FROM VENTING,RUPTURING OR BURSTING
CANS.
Unusual Fire/Explosion Hazard:FLAMM.EXPOS TO TEMP >120F,49C MAY CAUSE
CANS TO VENT,RUPTURE OR BURST.POSITIVE FLAME EXTENTION.HAZ DECOMP
PROD:CO,CO*2,HYDROGEN CHLORIDE OR TRACES OF PHOSGENE.

Spill Release Procedures:REMOVE ALL SOURCES OF HEAT,SPARKS OR OPEN
FLAMES.VENTILATE AREA OF SPILL.ABSORB SPILL ON STATE OIL
ABSORBENT,SAND,VERMICULITE ETC.
Neutralizing Agent:N/K

Handling and Storage Precautions:DANGER:INGEST HARMFUL/FATAL.VAP
HARMFUL..DIRECT CONTACT:EYE/SKIN IRRIT.FLAM.DO NOT STORE IN DIRECT
SUN,>120F,49C OR NEAR SPARKS,OPEN FLAME. (SEE SUPP)
Other Precautions:NO SMKNG IN USE AREA.DO NOT USE IN GENL VICIN OF ARC
WELDING,OPEN FLAMES,HOT SURFACES.HEAT &/OR UV RADIA MAY CAUSE FORM
OF HCL &/OR PHOSGENE .FOLLOW ALL LABEL DIRECTIONS & PREC BEFORE
USE.FOR IN DUS USE ONLY.KEEP AWAY FROM CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:VITON
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SOURCE OF COOL,CLEAN WATER NEARBY IN CASE OF
ACCIDENTAL EYE/SKIN CONTACT.WEAR SCBA IF IT MUST BE USED IN
CONFINED AREA.
Work Hygienic Practices:WASH PROMPTLY WITH PLENTY OF SOAP & WATER.DO
NOT WEAR CONTACT LENSES WHILE WORKING WITH THIS PRODUCT.
Supplemental Safety and Health
% VOLAT BY WEIGHT:>90.MATLS TO AVOID:RUBBER,PLASTIC,LINOLEUM OR ANY
ORGANIC MATERIAL.HNDLG/STOR PREC:CONTENT UNDER PRESS.DO NOT
PUNCTURE OR INCIN CANS.DO NOT USE ON RUBBER,PLASTIC,LINOLEUM OR
OTHER OR GANIC MATLS.TO PVNT CLOGGING,TURN CAN UPSIDE DOWN & SPRAY
SHORT JET OF GAS AFTER EACH JOB.

Boiling Pt:B.P. Text:N/A,AEROSOL
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:A CLEAR AEROSOL GEL WITH A STRONG ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,CAUSTICS OR CHEMICALLY ACTIVE LIGHT METALS.MAY
ADVERSELY AFFECT SOME PLASTICS.DO NOT USE ON (SEE SUPP)
Stability Condition to Avoid:FLAMMABLE.DO NOT EXPOSE TO TEMP
>120F,49C,SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING MAY RESULT IN FORMATION OF
CARBON MONOXIDE,CARBON DIOXIDE,HYDROGEN CHLORIDE OR TRACES OF
PHOSGENE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT INCINERATE
CANS.CONTENTS UNDER PRESSURE.EMPTY COMPLETELY THEN WRAP CANS AND
PLACE IN TRASH.

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particular situation.