Product ID:GLID-GUARD GLID-THANE ONE - GRANARY,6101
MSDS Date:12/08/1988
FSC:8010
NIIN:00N010593
MSDS Number: BHVFC

GLIDDEN COMPANY

925 EUCLID AVENUE
CLEVELAND, OH 44115

Emergency Phone: 216-826-5566

Info Phone: 216-826-5566

Cage: 01PD6

GLIDDEN PAINT, ICI PAINTS NORTH AMERICA

CLEVELAND, OH 44115 US

Telephone: 800-545-2643/216-344-8207

Cage: 01PD6

ACGIH A1=CONFIRMED HUM CARC (1989).INORG

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

INORGANIC LEAD COMPOUNDS (AS PB).OSHA & ACGIH LIMITS ARE AS

Fraction By Weight: 1.5%

OSHA PEL 0.05 MG (PB)/M3

ACGIH TLV: 0.15 MG (PB)/M3

CHROMATES (AS CRO*3)

Fraction By Weight: 0.5%

OSHA PEL 0.1 MG CRO*3/10 M3 C

ACGIH TLV: 0.05 MG (CRO*3)/M3

ORGANIC TIN COMPOUNDS

Fraction By Weight: 0.5%

OSHA PEL 0.1 MG/M3 SKIN

ACGIH TLV: 0.1 MG/M3 SKIN

2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)

CAS: 111-15-9

RTECS: KK8225000

Fraction By Weight: 7%

OSHA PEL S,100 PPM

ACGIH TLV: S, 5 PPM; 9192

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 16%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 4%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 7%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 26%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SOLVENT NAPHTHA (PETROLEUM),LIGHT AROMATIC.AROMATIC

CAS: 64742-95-6

Fraction By Weight: 6%

OSHA PEL N/K

ACGIH TLV: N/K

FREE ALIPHATIC DIISOCYANATE

RTECS: 9999999ZZ

Fraction By Weight: 3%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NIOSH STUDIES INDICATE 2-ETHOXYETHYL
ACETATE CAUSED REPROUCTIVE DISORDERS IN LAB ANIMALS (RATS/MICE) &
MAY HAVE POTNTL FOR CAUSING SIMILAR DISORDERS IN HUMANS .MAY CAUSE
LIVER & KIDNEY DMG,RESP FAILURE,ASPHYXIATION,DEATH,CORNEAL
INJURY.RPTD/PRLNG OVEREXPOS TO SOLVS ASSOCD W/ PERM BRAIN & NERVOUS
SYS DMG.(SEE SUP)
Explanation of Carcinogenicity:CR(VI) CMPD:SUFF EVID FOR CARC IN
HUMANS/ANIM (IARC,1987).CR/CERTAIN CR CMPD:KNOWN HUM CARC
(NTP,1985).(SEE ING 11 & 12)
Effects of Overexposure:EYES:SEVERE
IRRIT,TEARING,REDNESS.SKIN:IRRIT,DERM,DEFAT,ALLERGIC
RXN.INGEST:NAUS,VOMIT,DIARR,DIGEST SYS PROBLEMS.LEAD-FATG,SLEEP
DISTURB,CONSTIP,APPETITE LOSS,METAL
TASTE,ANXIETY,NAUS,PALLOR,HDCH,IRRI TABILITY,MUSC/JOINT
PAIN,TREMORS,NUMB,DIZZ,HYPERTENSION.INHAL:IRRIT,DROW,FATG,DIZZ,LT
HEAD,HDCH,INCOORD,NAUS,(SEE SUPP)
Medical Cond Aggravated by Exposure:EYE,SKIN,RESPIRATORY
SYSTEM,LUNG,KIDNEY,LIVER,NERVOUS SYSTEM DISORDERS.ASTHMA-LIKE
CONDITIONS.CARDIAC ABNORMALITIES.

First Aid:EYES:FLUSH IMMED W/ LARGE AMTS OF WATER,ESPECIALLY UNDER LIDS
FOR AT LEAST 15 MIN.GET EMERGENCY MED TREATMENT.SKIN:WASH OFF
QUICKLY W/ PLENTY OF WATER,THEN SOAP & WATER;REMOVE CONTAM CLOTHES
& WASH.DI SPOSE OF CONTAM LEATHER ITEMS.INGEST:GET MED ATTN
IMMED.INHAL:REMOVE TO FRESH AIR.RESTORE & SUPPORT BREATHING.GET
EMERGENCY MED ATTN.GIVE OXYGEN IF NECESSARY.GET MED HELP FOR
BREATHING DIFFICULTY.

Flash Point Method:SCC
Flash Point:79F,26C
Lower Limits:N/K
Upper Limits:1.0%
Extinguishing Media:DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTR MAY EXPLODE IN EXTREME HEAT
OR FIRE.VAPORS MAY EXPLODE AT AMBIENT TEMP.VAPORS HEAVIER THAN AIR
& MAY TRAVEL LONG DIST TO IGNIT SOURCE & (SEE SUPP)

Spill Release Procedures:ELIM ALL IGNIT SOURCES.VENT W/ EXPLOS-PROOF
EQUIP.COLLECT W/ ABSORB MATL.USE NON-SPK TOOLS.EVACUATE UNNEC
PERSONNEL.LRG SPILL-SHUT OFF LEAK IF SAFE.DIKE & CONTAIN.PUMP TO
STOR OR SALVAGE VESSEL.EXCESS -USE ABSORB.KEEP FROM SEWERS OR WATER
COURSES.
Neutralizing Agent:N/K

Handling and Storage Precautions:STORE BELOW 80F,27C.KEEP AWAY FROM
HEAT,SPARKS,OPEN FLAME.KEEP CONTNR TIGHTLY CLOSED & UPRIGHT.EMPTY
CONTNRS MAY CONTAIN HAZ RESIDUE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.DO NOT USE ON SURFACES
OR ARTICLES TO WHICH CHILDREN MAY BE EXPOSED.USE ONLY W/ ADEQ
VENT.DO NOT INGEST.AVOID SKIN & EYE CONT,& BRTHING VAPORS.AVOID
BRTHING OF SANDING DU ST.DRIED FILM HARMFUL IF EATEN/CHEWED.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .USE EXPLOS-PROOF,NON-SPK EQUIP.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH,SAFETY SHOWER,IMPERVIOUS CLOTHING.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING,ESPECIALLY
BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:FLASH BACK.MAY DECOMP IN FIRE TO IRRITANT/TOXIC
GASES,CO,CO*2.HLTH HAZ:INHAL CONC CONTENT
HARMFUL/FATAL.LEAD-COLIC,ANEMIA,NEURITIS;RED BLOOD CELL
FORM,KIDNEYS,NERVOUS & REPRO SYS DMG.EFTS OF
OVEREXP:VOMIT,COUGH,CNS DEPRESS,RESP PROBLEMS,CONFUSN,ANESTH
EFT,BRTHG DIFFICULTY,UNCON,BLURRED VISION,(SEE ING 11)

Boiling Pt:B.P. Text:228-355F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Density:1.09,AIR=1
Spec Gravity:1.09 (WATER=1)
Evaporation Rate & Reference:N/K
Appearance and Odor:TAN LIQUID
Percent Volatiles by Volume:63.00

Stability Indicator/Materials to Avoid:YES
OXIDIZERS,ACIDS,REDUCING AGENTS,BASES,A MINES.
Stability Condition to Avoid:ELEVATED TEMPERATURES,CONTACT WITH
OXIDIZING AGENT.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .TOXIC TO FISH.AVOID DISCHARGE
TO NATURAL WATERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.