Product ID:FORMULA 289 KURE FUNGICIDE
MSDS Date:04/01/1987
FSC:6840
NIIN:00N010003
MSDS Number: BHYPP

STATE CHEMICAL MANUFACTURING CO

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

ZINC,ION & MANGANESE ETHYLENE-BIS-DITHIOCARBAMATE

CAS: 8018-01-7

RTECS: ZB3200000

Fraction By Weight: 80%

OSHA PEL N/K

ACGIH TLV: N/K

ETHYLENE THIOUREA (SARA III)

CAS: 96-45-7

RTECS: NI9625000

Fraction By Weight: TRACE

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HIGH LEVELS (300 TIMES TLV) HAVE
CAUSED BIRTH DEFECTS IN TEST ANIMALS.ETHYLENETHIOUREA (ETU) IS A
TRACE CONTAMINANT;HAS CAUSED THYROID EFFECTS,TUMORS & BIRTH DEFECTS
IN LAB ANIMALS.
Explanation of Carcinogenicity:ETHYLENETHIOUREA:INAD EVID FOR CARC IN
HUM;SUFF EVID FOR CARC IN ANIM (IARC,1987).SUSP HUM/KNOWN ANIM CARC
(NTP,1985).
Effects of Overexposure:EYES:EXPOSURE TO DUST WILL CAUSE
IRRITATION,REPEATED/PROLONGED CONTACT W/ DUST WILL CAUSE
INFLAMMATION OF RETINA.SKIN:REPEATED/PROLONGED CONTACT W/ DUST WILL
CAUSE IRRITATION.INGESTION:N/K .INHALATION:EXPOSURE TO DUST WILL
CAUSEIRRITATION OF NOSE AND THROAT.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMEDIATELY W/ PLENTY OF COOL WATER FOR AT LEAST
15 MIN.IF IRRITATION PERSISTS,SEEK MEDICAL ATTENTION.DO NOT WEAR
CONTACT LENSES.SKIN:WASH THOROUGHLY W/ PLENTY OF SOAP & WATER.IF
IRRITATION DEVELOPS,CONTACT A PHYSICIAN.INGESTION:DILUTE BY GIVING
2 GLASSES OF WATER TO DRINK.CALL MD IMMED.NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERSON.INHAL:REMOVE TO FRESH AIR.IF IRRIT PERSISTS
CONTACT MD.

Flash Point Method:TOC
Flash Point:295F,146.11C
Lower Limits:N/K
Upper Limits:0.16 OZ/FT3
Extinguishing Media:CARBON DIOXIDE,WATER FOG,FOAM & DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:AUTOIGNIT:270F (LAYER),590F
(DUST).TOX,FLAM GASES EVOLVE >176F,80C:HYDROGEN SULFIDE,CARBON
DISULFIDE,OXIDES OF SULFUR,NITROGEN,CARBON.DUST CAN EXPLODE.

Spill Release Procedures:SWEEP/SHOVEL INTO CONTR FOR
DISP/REWORKING.KEEP DUST TO MINIMUM.FLUSH CONTAM AREA W/ LARGE AMTS
OF WATER TO CHEM/SANITARY SEWER W/ SETTLING PIT.KEEP SPILLS,RUNOFF
OUT OF MUNICIPAL SEWERS,OPEN BODIES O F WATER.TOXIC TO FISH.DO NOT
CONTAM NATURAL WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:WEAR PROT CLTHG.STORE IN COOL,DRY
PLACE.DO NOT GET WET,OVERHEAT-MAY IMPAIR EFTIVE,GENERATE FLAM
VAP.KEEP TIGHTLY CLSD.STORE <120F.INDUST USE ONLY.
Other Precautions:DISCHARGE HAZ TO FISH IN NEARBY AREAS.DO NOT CONTAM
WATER BY TREAT,CLEAN,DISP.KEEP OUT OF LAKES,STREAMS,PONDS.DO NOT
APPLY WHERE RUNOFF LIKELY,DRIFTS FAVORED.APPLY ONLY AS SPECIFIED.DO
NOT GRAZE OR FE ED CLIPPINGS TO LIVESTOCK.(SEE SUPP)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW EXPOSURE OF CONCERN .USE OUTDOORS.
Protective Gloves:REQUIRED
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:LONG PANTS,LONG SLEEVED SHIRT,HATS,BOOTS
SHOULD BE WORN WHEN MIXING,LOADING EQUIP.
Work Hygienic Practices:SHOWER AFTER USE.LAUNDER CLOTHES SEPARATELY
FROM OTHER LAUNDRY.DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
VOLATILE BY WT:1-3%.OTHER PREC:KEEP OUT OF REACH OF CHILDREN.NOT FOR
HOUSEHOLD USE/RESALE.READ/FOLLOW ALL LABEL DIRECTIONS/PREC.KEEP
FROM FIRE,SPARKS.FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY.ROUTES O
F ENTRY:INHALATION/SKIN/INGESTION .

Boiling Pt:B.P. Text:192-204C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:192-204C
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:0.35-0.5,H*2O=1
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:A BLUE GREEN POWDER WITH A SLIGHT SULFUR-LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR OXIDIZING MATERIALS.
Stability Condition to Avoid:EXPOSURE TO MOISTURE,HEAT,SPARKS OR OPEN
FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD SUCH
GASES AS OXIDES OF CARBON,NITROGEN & SULFUR;HYDROGEN SULFIDE/CARBON
DISULFIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISP MUST BE IN ACCORDANCE W/ FEDERAL,STATE &
LOCAL REGS .RECOVER LARGE AMTS FOR REUSE.DISP OF UNUSED MATL AS HAZ
WASTE.RQ 5000 POUNDS.INCIN AT HAZ WASTE TREATMENT FACILITY REC.DO
NOT REUSE EMPT Y CONTR.TRIPLE RINSE,CRUSH,DISCARD OR RECONDITION.

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