Product ID:LIME-SOLVENT
MSDS Date:11/01/1985
FSC:6850
NIIN:00N010075
MSDS Number: BHYPS

STATE CHEMICAL MANUFACTURING COMPANY

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: <5%

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTAINS ACID.HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN:DIRECT CONTACT CAN CAUSE
IRRITATION.INGEST:CONTAINS ACID.HARMFUL IF SWALLOWED.INHAL:N/K .
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ PLENTY OF COOL H*2O FOR AT LEAST 15
MIN.IF IRRIT PERSISTS,CONTACT MD.SKIN:WASH W/ PLENTY OF SOAP &
WATER.IF IRRIT DEVELOPS,CONTACT MD.INGEST:DO NOT INDUCE
VOMITING;CONTACT MD IMMED .DRINK LG AMTS OF WATER OR MILK TO
DILUTE.OBSERVE THE PATIENT.IF THERE ARE PROBLEMS SWALLOWING,OR IF
THERE IS EXCESSIVE DROOLING,AN ENDOSCOPY IS INDICATED.A NEUTRALIZER
SHOULD NOT BE USED (SEE SUPP)

Flash Point Method:TCC
Flash Point:NONE TO 200F,93C
Lower Limits:N/K
Upper Limits:N/K
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION OF THE DRIED
RESIDUE OF THIS PRODUCT MAY RESULT IN THE FORMATION OF CARBON
MONOXIDE OR CARBON DIOXIDE GASES OR OXIDES OF PHOSPHORUS.

Spill Release Procedures:DIKE AREA.NEUTRALIZE WITH SODA ASH OR
LIME.ABSORB ON STATE OIL ABSORBENT,SAND OR VERMICULITE.FLUSH ANY
RESIDUES WITH PLENTY OF WATER TO THE DRAIN.
Neutralizing Agent:SODA ASH OR LIME.

Handling and Storage Precautions:CONTACT WITH SKIN OR EYES MAY CAUSE
IRRITATION.HARMFUL IF SWALLOWED.USE RUBBER GLOVES WHEN
HANDLING.KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:STORE ONLY IN COOL,DRY PLACE.NOT FOR USE ON
NICKLE-PLATED OR GALVANIZED SURFACES.READ AND FOLLOW ALL LABEL
DIRECTIONS/PRECAUTIONS BEFORE USE.FOR INDUSTRIAL AND INSTITUTIONAL
USE ONLY.KEEP OUT OF THE R EACH OF CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .DO NOT INTENTIONALLY INHALE VAPORS OF ANY
PRODUCT NOT SPECIFICALLY DESIGNED TO BE INHALED.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:REQUIRED,RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:HAVE A SOURCE OF COOL,CLEAN WATER NEARBY IN
CASE OF ACCIDENTAL EYE OR SKIN CONTACT.
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health
%VOLAT BY WT:>85.PH:2.2 (3% SOLUTION).FIRST AID PROC:TO AVOID THE RISK
FROM A THERMAL REACTION .INDUCE VOMITING BY PLACING FINGER IN BACK
OF THROAT OR FOLLOWING THE DIRECTIONS ON THE LABEL OF SY RUP OF
IPECAC BOTTLE.CONTACT MD IMMED (MFR).INHAL:REMOVE TO FRESH
AIR.SUPPORT BREATHING (GIVE O*2/ARTF RESP) .

Boiling Pt:B.P. Text:220F,104C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:1.048 (WATER=1)
pH:SUP DA
Evaporation Rate & Reference:N/K
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH LOW ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG CAUSTICS.
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:UPON THERMAL DECOMPOSITION OF DRIED
PRODUCT RESIDUE,CARBON MONOXIDE,CARBON DIOXIDE AND OXIDES OF
PHOSPHORUS MAY FORM.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT REUSE ANY EMPTY
CONTAINERS FOR ANY PURPOSE.FLUSH THOROUGHLY WITH WATER.CRUSH AND
DISCARD,OR GIVE RINSED DRUMS TO A DRUM RECONDITIONER FOR
RECYCLING.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.