Product ID:11110057 POLYMIDE PRECURSOR SOL. (K TYPE)
MSDS Date:01/01/1988
FSC:8010
NIIN:00F012789
MSDS Number: BJGMM

E.I. DU PONT DE NEMOURS CO

1007 MARKET STREET
WILMINGTON, DE 19898

Emergency Phone: (800) 441-3637

Info Phone: (800) 441-3637

Cage: 18773

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

N-METHYL-2-PYRROLIDONE

CAS: 872-50-4

RTECS: UY5790000

DIETHYL PYROMELLITATE (PMDE)

CAS: 50853-29-7

2-PHENYL APB-144, (1,4-BIS

CAS: 94148-67-1

PHTHALIC ANHYDRIDE (SARA III)

CAS: 85-44-9

RTECS: TI3150000

Fraction By Weight: 0-2.0%

OSHA PEL 2 PPM

ACGIH TLV: 1 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 0-2.0%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

LD50 LC50 Mixture:ORAL RAT LD50 = 11,500 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: PERMANENT DAMAGE, VISUAL
IMPAIRMENT, BLINDNESS. SKIN: DISCOMFORT, RASH, ALLERGIC.
INHALATION: IRRITATION OF THE NOSE/THROAT, LUNG, COUGH, SHORTNESS
OF BREATH, ASTHMA-LIKE REACTIONS, DIZZINESS, H EADACHE, CONFUSION,
LOSS OF CONSCIOUSNESS. INGESTION: GASTROINTESTINAL TRACT
IRRITATION/VOMITING/NAUSEA/ABDOMINAL PAIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: PERMANENT DAMAGE TO THE RETINA, VISUAL
IMPAIRMENT, BLINDNESS. SKIN: SENSITIZATION. INHALATION: RESPIRATORY
TRACT IRRITATION, ANEMIA/MICROSCOPIC LESIONS IN THE RETINAL
PHOTORECEPTOR DEGENERATION/ DISORGANIZATION, LIVER, ADRENAL
CORTEX/SPLEEN.
Medical Cond Aggravated by Exposure:SENSITIZATION, ALLERGIC, RASH

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. CALL
PHYSICIAN. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH
AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT , GIVE OXYGEN. CALL PHYSICIAN. INGESTION: INDUCE
VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL PHYSICIAN.

Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL, CO2 OR WATER SPRAY.
AS APPROPRIATE FOR SURROUNDING MATERIAL/CONDITIONS.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS/FULL
PROTECTIVE GEAR.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AREA. ABSORB W/ABSORBENT MATERIAL/TRANSFER TO A METAL DRUM FOR
DISPOSAL. PREVENT LIQUID OF ENTERING SEWERS, WATERWAYS OR LOW
AREAS.

Handling and Storage Precautions:AVOID BREATHING VAPOR/MIST. DON'T GET
IN EYES, ON SKIN OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINER IN A COOL, DRY PLACE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. IF SHIPPED IN DRY
ICE, REMOVE DRY ICE PRIOR TO STORAGE IN A FREEZER. STORE AT 0F IN
ORIGINAL CONTAINER IS RECOMMENDED TO AVOID SLOW POLYMERIZATION
WHICH WOULD DEGRADE P RODUCT UTILITY.

Respiratory Protection:WEAR NIOSH/MSHA AIR PURIFYING RESPIRATOR W/A
DUST FILTER/ORGANIC VAPOR CARTRIDGE IF THERE IS POTENTIAL FOR
AIRBORNE EXPOSURE IN EXCESS OF APPLICABLE LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP Protective Gloves:IMPERVIOUS
Eye Protection:GOGGLES/FULL FACEHSIELD/SAFETY GLASSES
Other Protective Equipment:APRON, PANTS, HOOD/JACKET.
Work Hygienic Practices:ANY NONDISPOSABLE CLOTHING CONTAMINATED W/THE
SOLUTION SHOULD BE LAUNDERED SEPARATELY FROM OTHER CLOTHING BEFORE
REUSE.
Supplemental Safety and Health

Boiling Pt:B.P. Text:395.6F
Melt/Freeze Pt:M.P/F.P Text:-11F
Vapor Pres:0.29
Vapor Density:3.40
Spec Gravity:1.19
Evaporation Rate & Reference:(BU AC = 1.0): 0.06
Solubility in Water:APPRECIABLE
Appearance and Odor:SLIGHT TAN TO BROWN; AMINE-LIKE ODOR.
Percent Volatiles by Volume:33-40%

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:USE METHYL ETHYL KETONE OR ACETONE FOR
DECONTAMINATION, AVOIDING ALL PROXIMITY OF SPARKS, OPEN FLAMES,
HEAT.
Conditions to Avoid Polymerization:TEMP >0F CAUSES SLOW POLYMERIZATION
WHICH WOULD DEGRADE PRODUCT UTILITY.

Waste Disposal Methods:FOLLOW APPLICABLE FEDERAL, STATE/LOCAL LAWS &
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.