Product ID:RAPIDRAW INK 3084
MSDS Date:05/27/1988
FSC:7510
NIIN:00N010209
MSDS Number: BJJQH

KOH-I-NOOR RAPIDOGRAPH INC

100 NORTH STREET
BLOOMSBURG, NJ 08804-0068

Emergency Phone: 201-479-4124

Info Phone: 201-479-4124

Preparer: BEN APONAIRCIUS

Cage: 75364

KOH-I-NOOR RAPIDOGRAPH INC

BLOOMSBURY, NJ 08804-9501 US

Telephone: 908-479-4124

Cage: 75364

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 15%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9192

MORPHOLINE

CAS: 110-91-8

RTECS: QD6475000

Fraction By Weight: <3%

OSHA PEL S,20 PPM/30 STEL

ACGIH TLV: S, 20 PPM; 9192

N-BUTYL ALCOHOL (SARA III)

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: <2%

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: <2%

OSHA PEL C 50 PPM

ACGIH TLV: C 50 PPM,VAPOR; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: <2%

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: <3%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 60-70%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 RATS ORAL >5 G/KG.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MORPHOLINE HAS PRODUCED KIDNEY DAMAGE
IN ANIMALS.IT IS VERY UNLIKELY THAT THE TLV'S FOR THE COMPONENTS
WOULD BE EXCEEDED DURING USAGE,HOWEVER,ABUSE MAY RESULT IN EYE
IRRITATION,HEADACHE,DIZZINESS,DERM ATITIS ABOUT FINGERNAILS.
Explanation of Carcinogenicity:CARBON BLACK:INADEQUATE EVIDENCE FOR
CARCINOGENICITY IN HUMANS/ANIMALS (IARC,1987).
Effects of Overexposure:EYES:IRRITATING.BUTANOL AND ISOPROPANOL HAVE
CAUSED CORNEAL INFLAMMATION AND BURNS.SKIN:IRRITATING.INGESTION.N/K
.INHALATION:IRRITATING TO RESPIRATORY SYSTEM.
Medical Cond Aggravated by Exposure:NONE EXPECTED

First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN.SEEK MED
ATTN.SKIN:WASH WITH PLENTY OF WATER.INGESTION:DRINK 1 TO 2 GLASSES
OF WATER TO DILUTE.GET MED ATTN.INHALATION:REMOVE TO FRESH AIR.

Flash Point:120F,48.89C
Extinguishing Media:THIS INK WILL NOT BURN OR SUPPORT COMBUSTION.USE
WATER TO EXTINGUISH BURNING RESIDUE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .HIGH TEMPS WILL EVAPORATE THE LIQ & RESIDUE
WILL BURN.WATER IS AN ADEQ EXTINGUISHING MEDIUM.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:WASH WITH SOAP AND WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP FROM FREEZING.STORE AT ROOM
TEMPERATURE.
Other Precautions:N/K

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:NOT REQUIRED
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT REQUIRED.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
SOL IN H*20:MISCIBLE IN ALL PROPORTIONS.FL PT METH:ASTM D56.DISTRIBUTOR
RENAMES PRODUCT:LEROY SUPER BLACK INK,580007 (SEE PART B).

Boiling Pt:B.P. Text:100C,212F
Melt/Freeze Pt:M.P/F.P Text:19-24F
Decomp Temp:Decomp Text:N/K
Spec Gravity:1.095 (WATER=1)
Evaporation Rate & Reference:LIKE WATER (BU AC=1)
Solubility in Water:MISC,IN ALL PROPOR
Appearance and Odor:BLACK LIQUID.SLIGHT FUEL OIL ODOR.

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.