Product ID:STAFOAM MF 102, COMPONENT T
MSDS Date:05/19/1987
FSC:9330
NIIN:00-106-8657
Kit Part:Y
MSDS Number: BJLZZ

EXPANDED RUBBER AND PLASTIC CORP

14000 S WESTERN AVE
GARDENA, CA 90249-3008
US

Emergency Phone: 213-324-6692

Info Phone: 213-321-4260

Cage: 25598

EXPANDED RUBBER AND PLASTIC CORP

GARDENA, CA 90249-3008 US

Telephone: 310-321-4260

Cage: 25598

TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)

CAS: 584-84-9

RTECS: CZ6300000

Fraction By Weight: <6.5%

OSHA PEL C,0.02 PPM/0.02 STEL

ACGIH TLV: 0.005PPM/0.02STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TOLUENE-2,6-DIISOCYANATE (SARA III)

CAS: 91-08-7

RTECS: CZ6310000

Fraction By Weight: <3.5%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

POLYESTER POLYOL

Fraction By Weight: >90%

LD50 LC50 Mixture:LC50 (RAT-4 HR TDI)=16-50 PPM (SEE SUPP)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:LIQUID IS SEVERELY IRRITATING TO BODY
TISSUES. TOLUENE DIISOCYANATE MAY SENSITIZE SEVERE ALLERGIC
REACTIONS SUCH AS A CHEMICAL ASTHMA. PEL FOR TDI IS BELOW THE ODOR
THRESHOLD. SOLVENTS ARE ABSORBED BY THE SKIN AND WITH CHRONIC
OVEREXPOSUREMAY CAUSE PERMANENT CENTRAL NERVOUS SYSTEM DAMAGE KNOWN
AS PAINTERS SYNDROME.
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE IS LISTED BY NTP
AND IARC. SEE INDIVIDUAL REPORTS FOR DETAILS.
Effects of Overexposure:EYE: SEVERE IRRITATION. SKIN:IRRITATION,
DERMATITIS, SENSITIZED DERMATITIS. INHALED:RESPIRATORY IRRITATION,
FLU-LIKE SYMPTOMS, ASTHMA, SENSITIZING, NARCOSIS, LOSS OF APPETITE.
INGESTED:G/I IRRITATION, HEADACHE,NAUSEA,VOMITING,DIARRHEA.
Medical Cond Aggravated by Exposure:SINCE TDI SENSITIZES DERMAL AND
RESPIRATORY ALLERGYS, PEOPLE WITH ISOCYANATE SENSITIZATION, OR
DERMATITIS, ASTHMA, AND OTHER SIMILAR DISORDERS SUCH AS EMPHYSEMA,
ECZEMA, ETC. MAY BE AT INCREASED RISK.

First Aid:EYE:FLUSH W/WATER 15 MIN HOLD LIDS OPEN. SEE A DOCTOR.
SKIN:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH
WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING
IF NECESSARY. GET MEDICAL CARE AS ASTHMATIC SYMPTOMS MAY DEVELOP
EITHER IMMEDIATELY OR BE DELAYED SEVERAL HOURS. INGESTED:DO NOT
INDUCE VOMITING. GIVE MILK OR WATER TO DRINK IF CONSCIOUS. GET
IMMEDIATE MEDICAL CARE

Flash Point Method:PMCC
Flash Point:260F,127C
Lower Limits:0.9
Upper Limits:9.5
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:WATER REACTS WITH TOLUENE DIISOCYANATE
GENERATING CARBON DIOXIDE. REACTION MAY BE VIGOROUS IF TDI IS
VAPORIZED. HEATED CONTAINERS MAY RUPTURE FROM OVER PRESSURE

Spill Release Procedures:ALWAYS USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. COVER SPILL WITH SAWDUST,VERMICULITE,ETC. ADD LIQUID
DECONTAMINANT AND ALLOW TO SET FOR AT LEAST 10 MIN. COLLECT
MATERIAL IN OPEN CONTAINERS AND ADD MORE DECONTAMINANT.
Neutralizing Agent:WATER WITH 2-5% DETERGENT AND 0-10% AMMONIA. SEE
SUPP DATA FOR ALTERNATE.

Handling and Storage Precautions:STORE TIGHTLY CLOSED IN A DRY AREA.
STORE BETWEEN 70-90F. PROTECT FROM MOISTURE. PRODUCT WILL
POLYMERIZE SLOWLY AT HIGHER TEMPERATURE
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. REACTION WITH WATER RELEASES CO*2 WHICH MAY RUPTURE
CONTAINERS. DO NOT RESEAL IF CONTAMINATION IS SUSPECTED.

Respiratory Protection:USE POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR
ANY TIME THE EXPOSURE IS ABOVE THE CEILING, SHORT TERM EXPOSURE
LEVEL,OR PEL, AND AT ALL TIMES DURING SPRAYING OPERATIONS. OTHER
RESPIRATORS MAY BE USED F OR SHORT (1 HOUR) EXPOSURES ONLY!!
Ventilation:GENERAL VENTILATION SUPPLEMENTED WITH LOCAL EXHAUST, AS
NEEDED TO MAINTAIN EXPOSURES BELOW PEL/TLV.
Protective Gloves:RUBBER,VINYL OR OTHER IMPERVIOUS
Eye Protection:GOGGLES OR FACE SHIELD **NO CONTACTS!!*
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. COVER AS
MUCH SKIN AS POSSIBLE DURING OPERATIONS.
Work Hygienic Practices:USE STRICT CHEMICAL HYGIENE PRACTICES. AVOID
ALL CONTACT POSSIBLE. WASH THOROUGHLY AFTER USING.
Supplemental Safety and Health
KEY1:T3-F5 LD50 = 5800 MG/KG (TDI). INHALATION AND SKIN CONTACT ARE
MOST DAMAGING EXPOSURES. ALTERNATE DECONTAMINANT: 20% TERGITOL
TMN-10 IN WATER. THIS IS PART A OF A TWO PART KIT. SEE P/N IND B F
OR THE OTHER PART.

HCC:F5
Boiling Pt:B.P. Text:480F,249C
Vapor Pres:0.025 MM
Vapor Density:6.0
Spec Gravity:1.20
Solubility in Water:REACTS WITH WATER
Appearance and Odor:YELLOW HIGH VISCOSITY LIQUID, STRONG PUNGENT ODOR

Stability Indicator/Materials to Avoid:YES
WATER, BASES, TERTIARY AMINES.
Stability Condition to Avoid:TEMPERATURES OVER 40C FOR EXTENDED
PERIODS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
TRACES ON HYDROGEN CYANIDE, OXIDES OF NITROGEN, TOLUENE
DIISOCYANATE VAPOR.
Conditions to Avoid Polymerization:WATER AND OTHER PRODUCTS THAT REACT
WITH TOLUENE DIISOCYANATE (TDI).

Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.