BJMCW - NITROGEN

Product Identification

Product ID:NITROGEN
MSDS Date:08/01/1985
FSC:6830
NIIN:00-327-2929
MSDS Number: BJMCW

Responsible Party
UNION CARBIDE CORP INDUSTRIAL CHEMICALS DIV
39 OLD RIDGEBURY ROAD
DANBURY, CT 06917-0001
US

Emergency Phone: 304-744-3487

Info Phone: 800-822-4357

Cage: 61637

Contractor
UNION CARBIDE CORP
DANBURY, CT 06817-0001 US

Telephone: 800-822-4357/732-563-5522 (MSDS)

Cage: 61637

Ingredients

NITROGEN

CAS: 7727-37-9

RTECS: QW9700000

Fraction By Weight: 100%

ACGIH TLV: ASPHYXIANT; 9192

Hazards

LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT APPLICABLE.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EVAPORATION OF THE LIQUID FROM
THE SKIN CAN PRODUCE FROSTBITE-AVOID N2 LIQUID. IN HIGH
CONCENTRATIONS THIS IS A SIMPLE ASPHYXIANT - DIZZINESS,SHORTNESS OF
BREATH,UNCONSCIOUSNESS, OR SUFFOCATIO N CAN OCCUR.ANY COMPRESSED
GAS CAN BE AT MECHANICAL HAZARDS. CAN CAUSE COMPRESSED AIR ILLNESS
WITH CHRONIC OVEREXPOSURE
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:FROSTBITE OR CHILLING OF SKIN FROM CRYOGENIC
LIQUID. GAS CANDISPLACE OXYGEN FOR BREATHING AND RESULT IN
DIZZINESS, SHORTNESS OF BREATH.
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid

First Aid:TREAT FOR FROSTBITE IF NEEDED. IF BURNING OR ITCHING
SENSATION OF EYES/SKIN OCCUR, FLUSH WITH WATER FOR 15 MINUTES AND
SEEK MEDICAL ATTENTION. REMOVE VICTIM TO FRESH AIR IN CASE OF
OVERDOSE. GIVE MO UTH-TO-MOUTH ARTIFICAIAL RESPIRATION IFNEEDED.
GIVE OXYGEN IF BREATHING IS DIFFICULT.

Fire Fighting

Fire Fighting Procedures:GAS CYLINDRES ARE EQUIPPED WITH PRESSURE AND
TEMPERATURE RELIEF DEVICES - REMOVE CYLINDERS FROM FIRE OR HIGH
TEMPERATURE TO AVOID DANGER OF RUPTURE.
Unusual Fire/Explosion Hazard:NONE REPORTED BY MANUFACTURER.

Accidental Release

Spill Release Procedures:EVACUATE ALL PERSONNEL FROM RELEASE AREA.
VENTILATE TO OUTSIDE.
Neutralizing Agent:NOT APPLICABLE.

Handling

Handling and Storage Precautions:PROTECT CYLINDERS FROM PHYSICAL
DAMAGE. STORE AWAY FROM EXTREME HEAT. KEEP CYLINDER VALVES CLOSED
WHEN NOT IN USE AND WHEN EMPTY.
Other Precautions:DO NOT DEFACE CYLINDERS OR LABELS. HANDLE CYLINDERS
WITH PROPER CAUTION. STORE CYLINDERS IN A CLEAN, DRY, WELL
VENTILATED AREA AWAY FROM HEAT ABOVE 125F. KEEP CYLINDER CAPPED AND
SECURED AGAINST MOVEM ENT WHEN NOT IN USE.

Exposure Controls

Respiratory Protection:SCBA MAY BE NEEDED FOR PROLONGED EXPOSURE.
Ventilation:LOCAL EXHAUST MAY BE NEEDED FOR CONFINED SPACE USE. GENERAL
MECHANICAL VENTILATION IS ALWAYS RECOMMENDED.
Protective Gloves:WORK GLOVES FOR HANDLING CYLINDERS.
Eye Protection:APPROVED SAFETY GLASSES OR FACE SHIELD.
Other Protective Equipment:SAFETY SHOES AND HEARING PROTECTION.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. USE PROPER CARE WHEN HANDLING AND STORING
CYLINDERS.
Supplemental Safety and Health
SPECIAL GLOVES, FACE SHIELD, AND OTHER PROTECTIVE CLOTHING MAY BE
NEEDED IF HANDLING LIQUID.

Chemical Properties

HCC:G3
Boiling Pt:B.P. Text:-320F,-196C
Melt/Freeze Pt:M.P/F.P Text:-346F,-210C
Vapor Density:0.97 AIR=1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS,ODORLESS GAS
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
CAN REACT VIOLENTLY WITH LITHIUM (LI), NEODYMIUM (ND) AND TITANIUM (TI)
UNDER CERTAIN CONDITIONS.
Stability Condition to Avoid:NONE REPORTED BY MANUFACTURER
Hazardous Decomposition Products:NONE

Disposal

Waste Disposal Methods:MOVE LEAKY CYLINDER TO OUTDOORS OR VENTILATED
HOOD. ALLOW GAS TO DISCHARGE AT MODERATE RATE. DISPOSAL SHOULD BE
MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.