Product ID:3000-W
MSDS Date:01/03/1989
FSC:1615
NIIN:00-895-5408
Kit Part:Y
MSDS Number: BJMFH

ARDROX INC

16961 KNOTT AVE
LA MIRADA, CA 90638
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 714-739-2821

Preparer: SHEREE L KINZEL

Cage: 23373

SIKORSKY AIRCRAFT

LA MIRADA, CA 90638-6015 US

Telephone: 714-739-2821

Cage: 3G066

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 54%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: 21%

OSHA PEL 5 PPM (SKIN)

ACGIH TLV: 5 PPM (SKIN)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

& LIQ OF

RTECS: 9999999ZZ

CNTCT OVER LG BODY AREA MAY BE FATAL.EFTS MAY BE

RTECS: 9999999ZZ

DESTRUCTION.COMPONENTS ARE READILY ABSORBED THRU SKIN

RTECS: 9999999ZZ

THOSE DESCRIBED IN OTHER CATEGORIES IN THIS SECTION.

RTECS: 9999999ZZ

VOMIT. IF CONSCIOUS, GIVE LG AMTS OF WATER. DO NOT

RTECS: 9999999ZZ

ABSORBENT TO A DOT-APPRVD CNTR.USE APPRO PROT &

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POTNTL SOURCE OF IGNIT.THORO VENT AREA BEFORE

RTECS: 9999999ZZ

CONTACT).MASSIVE OVEREXPO LEAD TO CARCINOGENIC

RTECS: 9999999ZZ

NOT IN USE.PROTECT CNTR FROM PHYS DMG. USE/STORE

RTECS: 9999999ZZ

GROUND ALL EQUIP.TRAIN ALL EMPLOYEES ON ALL SPECIAL

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CARE&CAUTION. PERSONNEL SHLD AVOID BRTHG VAPS/MISTS

RTECS: 9999999ZZ

USE TOBACCO IN AREA THAT MAY BECOME CONTAMINATED

RTECS: 9999999ZZ

RESPONSE TO REACTION OF PATIENT.EXPO MAY INCREASE

RTECS: 9999999ZZ

ABSOLUTELY NEC.MASSIVE OVEREXPO TO SOLUTION OF PROD

RTECS: 9999999ZZ

IN SEVERAL CASES THROUGH USE OF EARLY RENAL

RTECS: 9999999ZZ

VENOUSLY IS EFFECTIVE ANTIDOTE IN PVNTG RENAL

RTECS: 9999999ZZ

CLEANSING & DEBRIDEMENT & APPLICATION OF ANTIBIOTIC

RTECS: 9999999ZZ

RPTD/PRLNGD OVEREXP TO SOLV MAY CAUSE BRAIN & NERV

RTECS: 9999999ZZ

AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON/CHLOROFLUOROCARBON (CFC)
MATLS HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN
LAB ANIMALS & COULD HAVE A SIMILAR EFFECT IN HIUMANS.
ADRENOMIMETICS (I.E., EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO
CHLOROCARBONS OR CFC'S
Explanation of Carcinogenicity:METHYLENE CHLORIDE:CLASS 2B (IARC) CLASS
2 (NTP).
Effects of Overexposure:INHAL:CORROSIVE TO BODY TISSUE/NOSE/THROAT. MAY
CAUSE SYSTEMIC POISONING & LIVER DMG. NARC EFTS OF DICHLOROMETHANE
OCCUR IN RANGE 500-1000PPM; DIZZ/DRUNKENESS OCCUR OVER 1000PPM;
UNCON, IRREG HEARTBEA T, DEATH AT LEVEL AS LOW AS 10,000PPM. MAY
CAUSE SEVERE IRRIT & POSS SEPTAL PERFORATION. SKIN:VAPS, MISTS (SEE
INGRED 6)
Medical Cond Aggravated by Exposure:SINCE DICHLOROMETHANE MAY ELEVATE
CARBOXYHEMOGLOBIN LEVELS, THIS EFFECT MAY BE SIGNIFICANT IN SMOKERS
OR WORKERS W/ANEMIA OR HEART DISEASE.

First Aid:INHAL:REMOVE TO FRESH AIR IMMED.IF NOT BRTHG,GIVE ART RESP.
IF BRTHG DFCLT,GIVE O*2.KEEP WARM AND AT REST. GET MD IMMED.
SKIN:WASH IMMED W/LOTS OF SOAP & WATER.IF CLOTHES,SHOES ARE
CONTAM,REMOVE & WAS H BEFORE REUSE. GET MD IF ILL EFFECT/IRIT
DEVELOPS. EYES:WASH IMMED W/RUNNING WATER FOR 15 MIN. USE FINGERS
TO ASSURE THAT LIDS ARE SEPARATED & EYE IS BEING WASHED. LIFT
LOWER/UPPER LID (SEE INGREDS

Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, CO*2
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
USE WATER TO KEEP FIRE-EXPOSED CNTRS COOL/TO FLUSH SPILLS AWAY FROM
FIRE. IN CASE OF LG FIRES,ALSO (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCLD
HCL,PHOSGENE. REACTS VIGOROUSLY W/STRONG OXIDIZING/REDUCING
AGENTS.CLOSED CNTRS EXPOSED TO HEAT MAY EXPLODE.(SEE SUPP DATA)

Spill Release Procedures:SMALL:MOP UP/SOAK UP W/NON-COMBUSTIBLE
ABSORBENT INORGANIC MATL.TRANSFER TO DOT-APPRVD CNTR. LGE:CONTAIN
BY DIKING W/NON-COMBUSTIBLE ABSORBENT INORGANIC MATL. PVNT RUNOFF
FROM ENTERING SEWERS,STORM DR AINS,SURFACE WATER & SOIL. TRANSFER
(SEE INGREDS)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTRS COOL,DRY & AWAY FROM
SOURCES OF IGNIT. DO NOT STORE PROD IN DIRECT SUNLIGHT,HIGH TEMP OR
BELOW FREEZING AREAS. KEEP CNTR (SEE INGREDS)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:USE NIOSH/MSHA APPROVED CANNISTER-TYPE
RESPIRATOR. IN CONFINED/POORLY VENT AREAS, FOR EMERGENCY/OTHER
CONDITIONS WHERE EXPOSURE GUIDELINES MAY BE GREATLY EXCEEDED, USE
NIOSH/MSHA APPROVED POSITIVE-PRE SSURE SCBA.
Ventilation:CONTROL AIRBORN CONC W/MECHANICAL VENT. LOCAL EXPLO-PROOF
EXHAUST VENT FOR SOME OPERATIONS.
Protective Gloves:IMPERMEABLE GLOVES ARE RECOMMENDED.
Eye Protection:CHEMICAL WORKERS GOGGLES/FACESHLD
Other Protective Equipment:PROTECTIVE CLTHG FOR PRLNGD/FREQUENTLY RPTD
CNTCT. BOOTS, APRON, FULL-BODY SUIT. SAFETY SHOWER/EYEWASH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING CHEMICALS &
BEFORE USING SANITARY FACILITIES. DO NO WEAR CONTACT LENSES.
Supplemental Safety and Health
THIS PART IS ONE OF 3 WHICH REPLACES PART E FOR PRODUCTS PURCHASED
AFTER 1989. FIRE FIGHT PROC:SURROUNDING EQUIP & STRUCTURES W/WATER.
EXPLO HAZ:STRONG OXIDIZER. CONTACT W/COMBUSTIBLE MATLS MAY CAUSE
FIRE;FIRES ARE DIFFICULT TO EXTING. MTLS TO
AVOID:W/(ALCL3+NITROBENZENE), BUTADIENE, PEROXYDISULFURIC ACID,(SEE
INGREDS)

Boiling Pt:B.P. Text:105F, 41C
Vapor Pres: 340
Vapor Density: 3
Spec Gravity:1.188
pH:10
Evaporation Rate & Reference: 14
Solubility in Water:NEGLIGIBLE
Appearance and Odor:THICK MUSTARD BROWN LIQUID, PUNGENT PHENOLIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES (SODIUM HYDROXIDE),ALKALI METALS.REACTIVE
METALS.COMBUST MATLS.REACTS VIOLENTLY (SEE SUPP DATA)
Stability Condition to Avoid:HEAT,FLAMES,SPARKS,IGNIT SOURCES. DO NOT
HEAT ABOVE 60C IN PRESENCE OF AL AS FLAM H*2 GAS MAY BE
RELEASED.ELECTRIC ARCS.
Hazardous Decomposition Products:PHOSGENE AND HCL .

Waste Disposal Methods:DISPOSE OF CONTAM PROD & MATLS USED IN CLEANING
UP SPILLS,LEAKS IN A MANNER APPRVD FOR MATL. DUMPING INTO SEWERS,ON
GROUND,INTO ANY BODY OF WATER IS STRONGLY DISCOURAGED AND ILLEGAL.
DISPOSE I/A/W FED ERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.