Product ID:1,10-PHENANTHROLINE IN ETHANOL
MSDS Date:09/15/1988
FSC:6810
NIIN:00F016183
MSDS Number: BKFXR

E-C APPARATUS CORPORATION

3831 TYRONE BOULEVARD N.
ST. PETERSBURG, FL 33709

Emergency Phone: (813) 344-1644

Info Phone: (813) 344-1644

Preparer: WILLIAM W. GORMAN, JR.

Cage: 7Y829

E-C APPARATUS CORP.

SAINT PETERSBURG, FL 33709 US

Telephone: 800-356-0783

Cage: 7Y829

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

1,10-PHENATHROLINE, MONOHYDRATE, 4,5-PHENANTHROLINE

CAS: 5144-89-8

RTECS: SF8437000

Fraction By Weight: 70%

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT): 20 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN:
IRRITANT/NARCOSIS/DEFAT/DERMATITIS/ECZEMA/REDNESS/ABSORPTION/PALENE
SS. EYES: CORROSIVE/IRRITATION/CORNEAL
INJURY/BURNS/LACRIMATION/CONJUCTIVIA HYPEREMIA. INGESTION:
POISONING/NAUSEA/VOMITING/DEF ECATION/URINATION/CNS
DEPRESSION/DIZZINESS/DROWSINESS/NARCOSIS/COMA/LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: BLURRED/DOUBLE VISION/PERMANENT
BLINDNESS/ATROPHY. INHALATION: PHOTOPHOBIA/HEADACHE/COLD
SYMPTOMS/GASTRITIS/ACIDOSIS/PSYCHOSES/INTOXICATION/INSOMNIA/TREMORS
/RESTLESSNESS/HALLUCINATIONS/FLUSHED F ACE/RAPID PULSE/SWEATING.
INGESTION: DEATH/RESPIRATORY/CIRCULATORY/CEREBRAL FAILURE.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. SKIN:
WASH W/SOAP & MILD DETERGENT/LARGE AMOUNTS OF WATER. EYE: WASH
W/WATER. IN CASE OF BURNS, APPLY STERILE BANDAGE LOOSELY W/OUT
MEDICATION. ING ESTION: IF CONSCIOUS, GIVE 2-4 GLASSES OF WATER OR
1 OUNCE OF MILK OF MAGNESIA. INDUCE VOMITING BY TOUCHING FINGER TO
BACK OF THROAT. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:57F
Lower Limits:4.3%
Upper Limits:19%
Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL FOAM, OR WATER SPRAY
Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA. SOLID STREAMS
MAY BE INEFFECTIVE, USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
WEAR SCBA IN PRESSURE MODE. (SEE SUPP).
Unusual Fire/Explosion Hazard:DANGEROUS FIRE/NEGLIGIBLE EXPLOSION
HAZARD WHEN EXPOSED TO HEAT/FLAME. VAPORS ARE >AIR & MAY TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION/FLASHBACK.

Spill Release Procedures:SHUT OFF IGNITION SOURCES. DON'T TOUCH SPILLED
MATERIAL. STOP LEAK SAFELY. USE WATER SPRAY TO REDUCE VAPORS. TAKE
UP W/SAND OR OTHER ABSORBENT MATERIAL/PLACE INTO CONTAINERS FOR
LATER DISPOSAL. EVACUA TE AREA.

Handling and Storage Precautions:DON'T SMOKE OR WEAR CONTACT LENSES
WHEN WORKING W/CHEMICALS.
Other Precautions:KEEP FROM HEAT, SPARKS OR FLAMES. AVOID INHALATION OF
VAPORS. KEEP UPWIND. AVOID CONTACT W/SKIN & EYES.

Respiratory Protection:33,000 PPM (LOWER EXPLOSIVE LIMIT)-SUPPLIED-AIR
RESPIRATOR W/SEPARATE AIR SUPPLY
Ventilation:PROVIDE LOCAL EXHAUST/GENERAL DILUTION TO KEEP Protective Gloves:RECOMMENDED
Eye Protection:SPLASH-PROOF/DUST-PROOF SAFETY GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING
Work Hygienic Practices:REMOVE/LAUDNER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE.
Supplemental Safety and Health
FIRE PROCEDURES (CON'T): FOR MASSIVE FIRE, USE UNMANNED HOSE HOLDER OR
MONITOR NOZZLES, OR LET FIRE BURN/WITHDRAW FROM AREA IN CASE OF
RISING SOUND FROM VENTING SAFETY DEVICE/ANY DISCOLORATION OF STOR
AGE TANK. TTE = TETRAETHYLENE.

Boiling Pt:B.P. Text:172F
Melt/Freeze Pt:M.P/F.P Text:-172F
Vapor Pres:40
Vapor Density:1.6
Spec Gravity:0.8
Evaporation Rate & Reference:(TTE = 1): 1.14 (SEE SUP)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID, 5-10 PPM ODOR THRESHOLD

Stability Indicator/Materials to Avoid:NO
STRONG OXIDIZERS, ALKALI METALS, & ACIDS
Stability Condition to Avoid:SOURCES OF IGNITION, HEAT, FLAME, SPARKS &
FLARES
Hazardous Decomposition Products:FLAMMABLE HYDROGEN GAS, CO & CO2

Waste Disposal Methods:PREVENT RUNOFF INTO SEWERS. DISPOSE IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.