Product ID:1,1,1-TRICHLOROETHANE
MSDS Date:05/29/1991
FSC:6810
NIIN:01-322-5197
MSDS Number: BKJWW

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 716-722-5151

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 96%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OTHER COMPONENTS (TYPE NOT SPECIFIED)

Fraction By Weight: 3%

SEC-BUTYL ALCOHOL (SARA III)

CAS: 78-92-2

RTECS: EO1750000

Fraction By Weight: 0.3%

OSHA PEL 150 PPM

ACGIH TLV: 100 PPM; 9293

LD50 LC50 Mixture:ORAL LD50 (RAT) = 11.2-12.3 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE EYE & SKIN
IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CENTRAL NERVOUS
SYSTEM DEPRESSANT. LOSS OF CONSCIOUSNESS AND EVEN DEATH CAN OCCUR
AT HIGH LEVELS OF EXPOSURE. EXCESS EX POSURE CAN LEAD TO BLOOD
PRESSURE DEPRESSION, CARDIAC SENSITIZATION, AND VENTRICULAR
ARRHYTHMIA. POSSIBLE LIVER EFFECTS.
Explanation of Carcinogenicity:NOT LISTED AS A CARCINOGEN BY NTP, IARC
OR OSHA
Effects of Overexposure:INCOORDINATION AND IMPAIRED JUDGMENT MAY OCCUR
AT VAPOR EXPOSURES FROM 500-1000 PPM. DIZZINESS, DROWSINESS, AND
GENERAL ANESTETHIC EFFECTS MAY OCCUR IN RANGES OF 1000 PPM AND
HIGHER. MAY CAUSE EYE CON JUNCTIVITIS.
Medical Cond Aggravated by Exposure:INCREASED SENSITIVITY TO ADRENALINE
MAY BE CAUSED BY OVER EXPOSURE.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE:
FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET
MEDICAL AT TENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH
SOAP AND WATER PROMPTLY. INGESTION: DO NOT INDUCE VOMITING. GIVE
VICTIM A GLASS OF WATER. GET IMMEDIATE MEDICAL ATTENTION. AVOID
ASPIRATION.

Flash Point:NONE
Lower Limits:6.7
Upper Limits:17.2
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL AS APPROPRIATE FOR SURROUNDINGS. (FLAMM. LIMITS AT 212F)
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:SMALL SPILL: WIPE UP WITH RAGS OR TOWELS.
LARGE SPILLS: WEAR NIOSH APPROVED RESPIRATOR. VENTILATE AREA. DIKE
TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE WILL EVAPORATE
QUICKLY. DO NOT FLUSH TO SEWER OR WATERWAY.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT USE WITH ALUMINUM. BE SURE THAT NO ALUMINUM
CONTAINERS, AEROSOLS, FITTINGS, ETC. ARE USED WITH THIS MATERIAL.
AVOID BREATHING VAPOR. PRACTICE GOOD PERSONAL HYGIENE. READ AND
FOLLOW DIRECTIONS ON LABEL. DO NOT REUSE CONTAINERS.

Respiratory Protection:IN HIGH VAPOR AREA, USE NIOSH/MSHA APPROVED
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. USE SELF-CONTAINED
BREATHING APPARATUS IF VAPOR LEVELS EXCEED 1000 PPM.
Ventilation:LOCAL EXHAUST RECOMMENDED TO CONTROL VAPORS BELOW 50% OF
TLV.
Protective Gloves:NEOPRENE, PVA GLOVES RECOMMENDED.
Eye Protection:USE CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED. WEAR
LONG-SLEEVED SHIRTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
TARGET ORGANS ARE SKIN, CNS, CVS, AND EYES. CONSIDER RUBBER BOOTS AS
ADDITIONAL PROTECTION FOR LONG TERM WORK WITH THIS MATERIAL. DO NOT
CUT, GRIND, WELD, OR DRILL ON OR NEAR THIS MATERIAL. **NOTE TO
PHYSICIAN: DO NOT ADMINISTER EPINEPHRINE OR SIMILAR DRUGS TO AN
OVEREXPOSED PERSON (PRODUCES ARRHYTHMIAS)**

HCC:T4
Boiling Pt:B.P. Text:160F,71C
Vapor Pres:100MM @20C
Spec Gravity:1.34
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID; CHARACTERISTIC ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ALUMINUM, OTHER REACTIVE METALS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:WHEN INVOLVED IN FIRE,
1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN
CHLORIDE AND PHOSGENE FUMES.

Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS. UNUSED MATERIAL WILL BE A LAND-BANNED HAZARDOUS WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.