Product ID:MID-GRADE UNLEADED GASOLINE
MSDS Date:01/29/1991
FSC:9130
NIIN:01-272-0983
MSDS Number: BKLRY

TOTAL PETROLEUM INC

EAST SUPERIOR STREET
ALMA, MI 48801
US

Emergency Phone: 517-463-1164

Info Phone: 517-463-1164

Preparer: M.N. MARTIN

Cage: 6G102

TOTAL PETROLEUM INC

ALMA, MI 48801 US

Telephone: 517-463-1164

Cage: 6G102

GASOLINE (INCLUDING INGREDIENTS LISTED BELOW)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <2.5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1.6%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <1.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III)

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <4.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/15OSTEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III)

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <1.5%

OSHA PEL 100PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <2.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <7.0%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PENTANE

CAS: 109-66-0

RTECS: RZ9450000

Fraction By Weight: <3%

OSHA PEL 1000 PPM/750 STEL

ACGIH TLV: 600 PPM/750STEL;9293

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

OTHER HEXANE ISOMERS

Fraction By Weight: <10%

OSHA PEL 500 PPM

ACGIH TLV: 500 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
BENZENE IS A CONFIRMED CARCINOGEN AND MAY PRODUCE BLOOD CHANGES.
PROLONGED EXPOSURE TO HIGH CONCENTRATIONS HAS CAUSED KIDNEY AND
LIVER CANCER IN RAT/MICE
Explanation of Carcinogenicity:BENZENE IS A CONFIRMED CARCINOGEN BY
NTP, IARC AND OSHA.
Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: HEADACHE,
NAUSEA, WEAKNESS, NARCOSIS, UNCONSCIOUSNESS, ASPHYXIAITION.
INGESTION: IRRITATION OF GASTROINTESTINAL SYSTEM.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN,
RESPIRATORY OR CENTRAL NERVOUS SYSTEM DISORDERS MAY BE AT INCREASED
RISK FROM EXPOSURE.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. SEE DOCTOR.
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER. SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR. GIVE
OXYGEN/CPR IF NEEDED. SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING. SEE DOCTOR IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:<-40F,<-40C
Lower Limits:1.3
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS CAN TRAVEL
ALONG GROUND AND FLASHBACK EXPLOSIVELY. CONTAINERS MAY BURST WITH
HEAT OF FIRE. COMBUSTION MAY PRODUCE TOXIC GASES.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
USE NON-SPARKING TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT. STOP LEAK
AND CONTAIN SPILL. ABSORB IN INERT ABSORBENT AND PLACE INTO
APPROPIATE DISPOSAL CONTAINE R AND SEAL. WASH AREA WITH PLENTY OF
WATER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
PLACE, AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
GROUND CONTAINERS DURING TRANSFER. PROTECT CONTAINERS FROM PHYSICAL
DAMAGE.

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS
EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:VITON, NITRILE, PVA.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST. RCRA
CLASSIFICATION IGNITABLE (D001). EP TOXIC (U019).

HCC:F2
Boiling Pt:B.P. Text:<100-437F
Vapor Pres:400-900
Vapor Density:3-4
Spec Gravity:0.65-0.75
Evaporation Rate & Reference:<1 (ETHER = 1)
Solubility in Water:INSOLUBLE.
Appearance and Odor:A SILVER, GREY OR CLEAR LIQUID WITH CHARACTERISTIC
GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HALOGENS, STRONG ACIDS AND ALKALIES.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS
WHEN BURNED.

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.